Materials Literature
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We show that two-dimensional phononic crystals exhibit Dirac cone dispersion at k=0 by exploiting dipole and quadrupole accidental degeneracy. While the equi-frequency surface of Dirac cone modes is isotropic, such systems exhibit "super-anisotropy", meaning that only transverse waves are allowed along certain directi…
Building on ideas introduced by Eshelby in 1953, and on recent dynamical extensions of the Peierls model for screw and edge dislocations, an approximate equation of motion (EoM) to govern non-uniform dislocation motion under time-varying stress is derived, allowing for time variations of the core width. Non-local in t…
We show, by way of tight-binding and first-principles calculations, that a one-to-one correspondence between electron's crystal momentum k and non-zero orbital angular momentum (OAM) is a generic feature of surface bands. The OAM forms a chiral structure in momentum space much as its spin counterpart in Rashba model d…
We present a detailed comparison of the S0, S1 (n → π∗) and S2 (π → π∗) potential energy surfaces (PESs) of the prototypical molecular switch azobenzene as obtained by Δ-self-consistent-field (ΔSCF) density-functional theory (DFT), time-dependent DFT (TD-DFT) and approximate coupled cluster singles and doubles (RI-CC2…
We present a first-principles scheme that allows the orbital magnetization of a magnetic crystal to be evaluated accurately and efficiently even in the presence of complex Fermi surfaces. Starting from an initial electronic-structure calculation with a coarse ab initio k-point mesh, maximally localized Wannier functio…
High frequency operation of tunneling real-space transfer transistor (TRSTT) in the negative differential resistance (NDR) regime is assessed by calculating the device common source unity current gain frequency (fT) range with a small signal equivalent circuit model including tunneling. Our circuit model is based on a…
As a continuation of work on metal and alloy "plants" synthesis on porous membranes by means of pulsed current electroplating volume metallic microstructures resembling such natural objects as shells, cabbage leaves, mushrooms are grown and presented in their modest elegance. Such structures are formed from PdNi and P…
An Ag4 diamond is encapsulated by silicotungstate ligands in TBA8[Ag4(DMSO)2(γ-H2SiW10O36)2]⋅2 DMSO⋅2 H2O (Ag4; DMSO=dimethyl sulfoxide, TBA=tetra-n-butylammonium), which was obtained by reaction of TBA4H4[γ-SiW10O36] with AgOAc in an organic medium. Polyoxometalate Ag4 (see picture) selectively catalyzes hydrolytic o…
This paper describes the fabrication and characterization of a hybrid nanostructure comprised of carbon nanotubes (CNTs) grown on graphene layers for supercapacitor applications. The entire nanostructure (CNTs and graphene) was fabricated via atmospheric pressure chemical vapor deposition (APCVD) and designed to minim…
Bacterial cellulose (BC), produced by Gluconacetobacter xylinum, consists of ribbon-shaped nano-fibers in web-like structures. Polyaniline (PAni) is a conductive polymer, the conductivity of which is related to the synthesis and doping process. In this paper, we report on the in situ nano-assembly of BC nanofibers and…
Transformation in a shell: Ion exchange is used for the fabrication of multishelled inorganic hollow materials. The transformation of solid Cu2O to Cu2S hollow spheres is investigated as a model reaction (see picture; PVP=poly(vinylpyrrolidone)).
We report new chemiluminescent properties of fluorescent carbon dots in the presence of classical oxidants, such as acidic potassium permanganate and cerium(IV). The radiative recombination of oxidant-injected holes and electrons in the carbon dots accounts for the CL emission, which sheds new light on characteristics…
Lighting the way: Biochemical cues have been reversibly patterned into hydrogels with full spatiotemporal control by using two photochemical reactions. The hydrogel is conjugated with a peptide by a thiol-ene photoaddition reaction that is initiated by visible light. Subsequent, selective photocleavage of an o-nitrobe…
Flexible graphene paper (GP) pillared by carbon black (CB) nanoparticles using a simple vacuum filtration method is developed as a high-performance electrode material for supercapacitors. Through the introduction of CB nanoparticles as spacers, the self-restacking of graphene sheets during the filtration process is mi…
We report a chemical route to colloidal silicon (Si) nanocrystals, or quantum dots, with widely tunable average diameter, from less than 3 nm up to 90 nm and peak photoluminescence (PL) from visible wavelengths to the bulk band gap of Si at 1100 nm. The synthesis relies on the high temperature (>1100 °C) decomposition…
Abstract The past decade has witnessed increasing attention in the synthesis, properties, and applications of one‐dimensional (1D) conducting polymer nanostructures. This overview first summarizes the synthetic strategies for various 1D nanostructures of conjugated polypyrrole (PPy), polyaniline (PANI), polythiophene…
This paper demonstrates that nanospace engineering of KOH activated carbon is possible by controlling the degree of carbon consumption and metallic potassium intercalation into the carbon lattice during the activation process. High specific surface areas, porosities, sub-nanometer (<1 nm) and supra-nanometer (1-5 nm)…
Abstract Capacitive energy storage offers several attractive properties compared to batteries, including higher power, faster charging, and a longer cycle life. A key limitation to this electrochemical energy‐storage approach is its low energy density and, for this reason, there is considerable interest in identifying…
Shape control of inorganic nanocrystals is important for understanding basic size- and shape-dependent scaling laws and is useful in a wide range of applications. With minor modifications in the chemical environment, it is possible to control the reaction and diffusion processes at room temperature, opening up a synth…
A series of well defined semitelechelic and mid-functionalized poly(poly(ethylene glycol) methyl ether methacrylate)s (poly(PEGMA)s) were synthesized through reversible addition-fragmentation chain transfer (RAFT) polymerization using thiazolidine-2-thione-functionalized chain transfer agents (CTAs). The thiazolidine-…