Materials Literature
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Previous thermodynamic analyses of carbon formation in SOFCs assumed that graphite could be used to represent the properties of carbon formed in the anode. It is generally observed, however, that catalytically grown carbon nanofibers (CNF) are more likely to form in the SOFC anode with nickel catalysts. The energetic…
Complex [tBuOCO]WC(tBu)(THF)2 (1) {where tBuOCO = [2,6-(tBuC6H3O)2C6H3]3−, THF = tetrahydrofuran} polymerizes acetylenes (R-phenylacetylene (R = H, p-OMe, p-F, 3,5-diCF3), 1-decyne, 3,3-dimethyl-1-butyne, and trimethylsilylacetylene) to form π-conjugating polymers. Upon treating 1 with 2 equiv. of phenylacetylene in t…
The structure of intertidal benthic diatoms assemblages in the Tagus estuary was investigated during a 2-year survey, carried out in six stations with different sediment texture. Nonparametric multivariate analyses were used to characterize spatial and temporal patterns of the assemblages and to link them to the measu…
Metal oxides as a rule oxidize and oxygenate substrates via the Mars-van Krevelen mechanism. A well-defined α-Keggin polyoxometalate, H(5)PV(2)Mo(10)O(40), can be viewed as an analogue of discrete structure that reacts via the Mars-van Krevelen mechanism both in solution and in the gas phase. Guided by previous experi…
t-ZrO 2, synthesized under hydrothermal treatment conditions at 150 °C for 20 h using NaOH as the mineralizer, was phase stable up to 600 °C in air. The t-ZrO 2 calcined at 600 °C (denoted as Z600) were nonporous spherical nanocrystallites with an average size of ∼12 nm and a surface area of ∼55 m 2 /g, which exhibite…
Silver nanoparticles (NPs) have been widely explored as antibacterial and antifungal agents in households, cosmetics, food packaging, medical devices and even various wound care products. With the application of silver NPs in biomedicine expanding, the safety issue is attracting ever-growing attention. Although increa…
Superparamagnetic iron oxide nanoparticles (SPIONs) comprise a fundamental technology class within the emerging field of nanomedicine, and have been extensively researched for cancer imaging and therapy. This review article will discuss the chemistry and design considerations associated with the synthesis of SPIONs an…
In this contribution, we reported the synthesis of organic–inorganic polyurethanes with polyhedral oligomeric silsesquioxane (POSS) in the main chains. Toward this end, 3,13-dihydroxypropyloctaphenyl double-decker silsesquioxane (DDSQ) was synthesized; this POSS diol was used as a chain extender to obtain hybrid polyu…
We consider oxygen interactions with realistic silica surfaces, including both experimentally observed nondefective surface reconstructions and experimentally observed surface defects. Nondefective models include clusters representing the site above a fully coordinated surface Si atom and bridging O atoms, and the def…
Monodisperse carbon spheres with coefficient of variation less than 4% were successfully synthesized through polycondensation of resorcinol with formaldehyde in the presence of ammonia as a catalyst followed by carbonization in an inert atmosphere. The diameters of the carbon spheres can be tuned in the range of 220–1…
On account of their intrinsic chemical and spectroscopic properties, luminescent lanthanide molecular materials find potential applications in lighting, optical communications, photonics and biomedical devices. This perspective article summarizes some recent seminal research work on luminescent properties and structur…
A new design of luminescent materials by decorating a tetraphenylethene core with four aromatic chromophores is proposed. The generated luminogens exhibit aggregation-enhanced emission and excellent solid-state fluorescence efficiency (93-99%). Efficient non-doped OLEDs based on them afford remarkable efficiencies up…
ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTFundamental Studies of Well-Defined Surfaces of Mixed-Metal Oxides: Special Properties of MOx/TiO2(110) {M = V, Ru, Ce, or W}Darío J. Stacchiola, Sanjaya D. Senanayake, Ping Liu, and José A. Rodriguez*View Author Information Chemistry Department, Brookhaven National Laborator…
We describe a synthesis of Au wavy nanowires in an aqueous solution in the presence of cetyltrimethylammonium bromide (CTAB). The resultant Au nanowires automatically separated from the solution and floated at the air/water interface. We investigated the formation mechanism by characterizing the samples obtained at di…
Phenylethynyl terminated novel imide compound based on 1,3-bis(3-aminophenoxy)benzene (APB) and phenylethynyl trimellitic anhydride (PETA) were prepared. The curing behavior of phenylethynyl terminated imide compound was investigated by differential scanning calorimetry and Fourier transform infrared spectrometry. The…
Cyclic butylene terephthalate oligomers (CBT) were reacted in a ring-opening polymerization with three types of isocyanates: a bifunctional aromatic type, a bifunctional aliphatic type and a polymeric aromatic isocyanate. All reactions took place in a batch mixer. The use of 0.5 to 1 wt% isocyanate led to a dramatic i…
In this work, all-polypropylene composites (all-PP composites) were manufactured by injection moulding. Prior to injection moulding, pre-impregnated pellets were prepared by a three-step process (filament winding, compression moulding and pelletizing). A highly oriented polypropylene multifilament was used as the rein…
We have established a well-defined dome shape Tc curve in Ir0.94-xRhxSe2 superconductors. The maximum Tconset of 9.6K was obtained at x=0.36, at which the Se-Se separation in the dimer anion is the longest. Simultaneously, the destabilization of Se-Se dimers accompanied by partial elec-tron-transfer from the Ir/Rh to…
This paper focuses on the reinforcing of Poly(lactic acid) with chopped basalt fibres by using silane treated and untreated basalt fibres. Composite materials with 5-10-15-20-30-40 wt% basalt fibre contents were prepared from silane sized basalt fibres using extrusion, and injection moulding, while composites with 5-1…
This work aimed to study the effect of different ultraviolet (UV) weathering conditions (natural and accelerated) on the photodegradation of polyvinyl chloride (PVC) and wood/polyvinyl chloride (WPVC) composites by considering the structural and physical changes of PVC and WPVC samples as well as examining the photode…