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Electro‐Optical Study of Subphthalocyanine in a Bilayer Organic Solar Cell

Hans Gommans、David Cheyns、Tom Aernouts 等 6 位作者2007-08-23Advanced Functional Materials

Abstract Ultra‐thin films of subphthalocyanine (SubPc) were grown onto Si/SiO 2 substrates by organic molecular beam deposition and the complex refractive index has been characterized by spectroscopic ellipsometry. The peak maximum in the extinction coefficient is determined to be 1.6 at 590 nm and the dielectric cons…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesOrganic Electronics and Photovoltaics

Direct Spectroscopic Evidence for a High-Spin Fe(IV) Intermediate in Tyrosine Hydroxylase

Bekir Engin Eser、Eric W. Barr、Patrick A. Frantom 等 7 位作者2007-08-23Journal of the American Chemical Society

Tyrosine hydroxylase, a member of the aromatic amino acid hydroxylase family, uses a mononuclear Fe(II) and tetrahydropterin for hydroxylation of tyrosine to dihydroxyphenylalanine. Rapid-freeze quench Mössbauer spectroscopy has now provided direct evidence for the presence of an Fe(IV) intermediate in the reaction ca…

Metal-Catalyzed Oxygenation MechanismsEnzyme Structure and FunctionMetabolism and Genetic Disorders

Equation of state for shock-compressed porous molybdenum from first-principles mean-field potential calculations

Qili Zhang、Ping Zhang、Gongmu Zhang 等 4 位作者2007-08-23arXiv

The Hugoniot curves for shock-compressed molybdenum with initial porosities of 1.0, 1.26, 1.83, and 2.31 are theoretically investigated. The method of calculations combines the first-principles treatment for zero- and finite-temperature electronic contribution and the mean-field-potential approach for the ion-thermal…

Materials Sciencecond-mat.stat-mech

Soliton Solution for the Spin Current in Ferromagnetic Nanowire

Zai-Dong Li、Qiu-Yan Li、Lu Li 等 4 位作者2007-08-23arXiv

We investigate the interaction of a periodic solution and one-soliton solution for the spin-polarized current in a uniaxial ferromagnetic nanowire. The amplitude and wave number of the periodic solution for the spin current have the different contribution to the width, velocity, and the amplitude of soliton solution,…

Materials Sciencecond-mat.other

Charge Order Superstructure with Integer Iron Valence inFe2OBO3

Manuel Angst、Peter G. Khalifah、Raphaël P. Hermann 等 9 位作者2007-08-23Physical Review Letters

Solution-grown single crystals of Fe(2)OBO(3) were characterized by specific heat, Mössbauer spectroscopy, and x-ray diffraction. A peak in the specific heat at 340 K indicates the onset of charge order. Evidence for a doubling of the unit cell at low temperature is presented. Combining structural refinement of diffra…

Multiferroics and related materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Velocity Renormalization and Carrier Lifetime in Graphene from the Electron-Phonon Interaction

Cheol-Hwan Park、Feliciano Giustino、Marvin L. Cohen 等 4 位作者2007-08-23Physical Review Letters

We present a first-principles investigation of the phonon-induced electron self-energy in graphene. The energy dependence of the self-energy reflects the peculiar linear band structure of graphene and deviates substantially from the usual metallic behavior. The effective band velocity of the Dirac fermions is found to…

Graphene research and applicationsQuantum and electron transport phenomenaThermal properties of materials

Description and explanation of electromagnetic behaviors in artificial metamaterials based on effective medium theory

Ruopeng Liu、Tie Jun Cui、Da Huang 等 5 位作者2007-08-23Physical Review E

We present a general theory of effective media to set up the relationship between the particle responses and the macroscopic system behaviors for artificial metamaterials composed of periodic resonant structures. By treating the unit cell of the periodic structure as a particle, we define the average permittivity and…

Antenna Design and AnalysisAdvanced Antenna and Metasurface TechnologiesMetamaterials and Metasurfaces Applications

Electrode Grids for ITO Free Organic Photovoltaic Devices

Kristofer Tvingstedt、Olle Inganäs2007-08-23Advanced Materials

Silver grids are utilized to exclude the expensive use of indium tin oxide (ITO) in conjugated polymer photovoltaic devices. The grids are generated by electroless deposition from elastomeric microfluidic channels onto transparent substrates. The organic photovoltaic devices demonstrated here, with minimized series re…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAdvanced Sensor and Energy Harvesting Materials

Synthesis of NaYF4 Nanocrystals with Predictable Phase and Shape

Xiao Liang、Xiaohong Wang、Jiayuan Zhuang 等 5 位作者2007-08-23Advanced Functional Materials

Abstract In this Full Paper, a water/alcohol/oleic acid system was developed to prepare NaYF 4 nanocrystals with predictable size, shape and phase. The structural and kinetic factors that govern the phase and shape evolution of NaYF 4 nanocrystals have been carefully studied, and the influence of NaF to Y 3+ ratio, re…

Inorganic Fluorides and Related CompoundsLuminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics Synthesis

Origin of Magic Stability of Thiolated Gold Clusters: A Case Study on Au25(SC6H13)18

Yuichi Negishi、Nirmalya K. Chaki、Yukatsu Shichibu 等 5 位作者2007-08-23OpenAlex

The present work aims to test the validity of the electronic shell model for Au 25 (SC 6 H 13 ) 18 by monitoring the charge state of the Au:S core and thereby to elucidate the origin of magic stability. Electrospray ionization mass spectrometry revealed that the Schiffrin method yields [Au 25 (SC 6 H 13 ) 18 ] x with…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Frequency dependence of the thermal conductivity of semiconductor alloys

Yee Kan Koh、David G. Cahill2007-08-23OpenAlex

The distribution of phonons that carry heat in crystals has typically been studied through measurements of the thermal conductivity $\ensuremath{\Lambda}$ as a function of temperature or sample size. We find that $\ensuremath{\Lambda}$ of semiconductor alloys also depends on the frequency of the oscillating temperatur…

Advanced Thermoelectric Materials and DevicesThermal Radiation and Cooling TechnologiesThermal properties of materials

Surface Enhanced Raman Scattering Enhancement Factors: A Comprehensive Study

Eric C. Le Ru、E. Blackie、Matthias Meyer 等 4 位作者2007-08-23OpenAlex

This paper presents an in-depth study of Surface Enhanced Raman Scattering (SERS) enhancement factors (EFs) and cross-sections, including several issues often overlooked. In particular, various possible rigorous definitions of the SERS EFs are introduced and discussed in the context of SERS applications, such as analy…

Spectroscopy and Quantum Chemical StudiesGold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and Applications

Novel Sensor for Locating Partial Discharges in High-Voltage Rotating Machines

Dong-Sik Kang、Don-Ha Hwang、Taek‐Kun Nam 等 4 位作者2007-08-22IEEE Transactions on Energy Conversion

The online partial discharge (PD) diagnosis has been recently accepted as an effective technique for the evaluation of the insulation condition of stator windings in high-voltage rotating machines. There are several types of sensors used for detecting PD in rotating machines. The so-called capacitive coupler, which is…

Electrical Fault Detection and ProtectionPower Transformer Diagnostics and InsulationHigh voltage insulation and dielectric phenomena

Discotic Liquid Crystals: From Tailor‐Made Synthesis to Plastic Electronics

Sabine Laschat、et al. et al.2007-08-22ChemInform

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Nonlinear Dynamics and Pattern FormationPhotonic and Optical DevicesLiquid Crystal Research Advancements

Analysis of the Effects Caused by Structural Asymmetries in the Performance of Three-Limb Core Three-Phase Inductive Filters

José M. Cano、Gonzalo A. Orcajo、Carlos H. Rojas 等 6 位作者2007-08-22IEEE Transactions on Energy Conversion

A considerable number of nonlinear industrial loads employ three-phase inductive filters to reduce their peak currents and mitigate the conduction of harmonic currents into the supply system. In modeling and analysis of this kind of filter, the fact that-for reasons of economy-they consist of a single block where the…

Non-Destructive Testing TechniquesMagnetic Properties and ApplicationsPower Quality and Harmonics

Modeling Carbon Nanotube Sensors

Jie Deng、Kunal Ghosh、H.‐S. Philip Wong2007-08-22IEEE Sensors Journal

Carbon nanotube sensors are modeled and their design space analyzed. It is found that semiconducting nanotubes are almost always preferred over metallic nanotubes, intrinsic nanotubes maximize sensor performance, while minimizing static power consumption, and higher biasing points maximize dynamic range, while improvi…

Mechanical and Optical ResonatorsCarbon Nanotubes in CompositesAnalytical Chemistry and Sensors

Morphology investigation on high‐pressure crystallized bisphenol‐A polycarbonate/dioctyl phthalate blends

Jun Lü、Rui Huang、Il‐Kwon Oh2007-08-22Journal of Polymer Science Part B Polymer Physics

Abstract The high‐pressure crystallized bisphenol‐A polycarbonate/dioctyl phthalate (BAPC/DOP) blend samples were investigated using wide‐angle X‐ray diffraction (WAXD), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The specimens were prepared in a piston‐cylinder high‐pressure appara…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Magnetic interactions in the MnFe1−xCoxP series of solid solutions

R. Zach、J. Toboła、B. Średniawa 等 7 位作者2007-08-22Journal of Physics Condensed Matter

In this report the results of crystal structure investigations, high magnetic field measurements and electronic structure calculations carried out for the MnFe 1− x Co x P system are presented. The crystal structure parameters were determined using the x-ray powder diffraction method. On this basis the inter-atomic di…

Magnetic and transport properties of perovskites and related materialsZnO doping and propertiesHeusler alloys: electronic and magnetic properties

Vulcanization of polybutadiene rubber with dipentamethylene thiuram tetrasulfide

P. Posadas、A. Fernández、Justo Brasero 等 7 位作者2007-08-22Journal of Applied Polymer Science

Abstract The cure of polybutadiene rubber (BR) with sulfur donor dipentamethylene thiuram tetrasulfide (DPTT) does not show reversion reaction, in contrast with similar natural rubber compounds. No polysulfure links are formed; whereas a great amount of CC crosslinks are produced. The addition of tetramethyl thiura…

Tribology and Wear AnalysisEpoxy Resin Curing ProcessesPolymer Nanocomposites and Properties

Properties of CdSe quantum dots coated with silica fabricated in a facile way

Yufeng Liao、Wenjiang Li、Sailing He2007-08-22Nanotechnology

High quality quantum dots (QDs) CdSe were prepared using a novel and non-TOP method. Quantum dots of different sizes ranging from 2 to 4 nm could be obtained by removing aliquots of the reaction solution at different time intervals or by adjusting some reaction conditions. The CdSe quantum dots (core) were directly co…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films