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Effects of polymer polydispersity on the phase behaviour of colloid-polymer mixtures

Moreno Fasolo、Peter Sollich2005-02-08arXiv

We study the equilibrium behaviour of a mixture of monodisperse hard sphere colloids and polydisperse non-adsorbing polymers at their $θ$-point, using the Asakura-Oosawa model treated within the free-volume approximation. Our focus is the experimentally relevant scenario where the distribution of polymer chain lengths…

Materials ScienceSoft Condensed Matter

Fabrication of Superhydrophobic Surfaces by Self-Assembly and Their Water-Adhesion Properties

Xiaoyan Song、Jin Zhai、Yilin Wang 等 4 位作者2005-02-08The Journal of Physical Chemistry B

The self-assembled films of methyloctyldimethoxysilane (MODMS) and fluorooctylmethyldimethoxysilane (FODMS) were prepared on silicon surfaces and evaluated with AFM, water contact angle measurement, and X-ray photoelectron spectroscopy. Superhydrophobic surfaces were obtained by cooperation of MODMS and FODMS self-ass…

Adhesion, Friction, and Surface InteractionsSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Growth of Single-Crystalline Ni and Co Nanowires via Electrochemical Deposition and Their Magnetic Properties

Hui Pan、Binghai Liu、Jiabao Yi 等 9 位作者2005-02-08The Journal of Physical Chemistry B

Single-crystalline Ni nanowires have been successfully fabricated with anodic aluminum oxide as template by electrodeposition. Structural characterization (X-ray diffraction, XRD, and high-resolution transmission electron microscopy, HRTEM) shows that the single-crystalline Ni nanowire has a preferred orientation alon…

Nanoporous metals and alloysAnodic Oxide Films and NanostructuresElectrodeposition and Electroless Coatings

SAFA: Semi-automated footprinting analysis software for high-throughput quantification of nucleic acid footprinting experiments

Rhiju Das、Alain Laederach、Samuel M. Pearlman 等 5 位作者2005-02-08OpenAlex

Footprinting is a powerful and widely used tool for characterizing the structure, thermodynamics, and kinetics of nucleic acid folding and ligand binding reactions. However, quantitative analysis of the gel images produced by footprinting experiments is tedious and time-consuming, due to the absence of informatics too…

Protein Structure and DynamicsEnzyme Structure and FunctionRNA and protein synthesis mechanisms

Pickering Emulsions with Controllable Stability

Sonia Melle、Mauricio Lask、Gerald G. Fuller2005-02-08OpenAlex

We prepare solid-stabilized emulsions using paramagnetic particles at an oil/water interface that can undergo macroscopic phase separation upon application of an external magnetic field. A critical field strength is found for which emulsion droplets begin to translate into the continuous-phase fluid. At higher fields,…

Proteins in Food SystemsPickering emulsions and particle stabilizationMicro and Nano Robotics

Pseudocapacitive Lithium Storage in TiO2(B)

Markéta Zukalová、Martin Kalbáč、Ladislav Kavan 等 5 位作者2005-02-08OpenAlex

Phase-pure TiO 2 (B) with microfibrous morphology was prepared via a newly developed method from amorphous TiO 2 . Cyclic voltammetry evidences that Li-insertion into TiO 2 (B) is governed by a pseudocapacitive faradaic process, whose rate is not limited by solid-state diffusion of Li + in a broad interval of scan rat…

Advanced Battery Materials and TechnologiesAdvancements in Battery MaterialsSupercapacitor Materials and Fabrication

Gold Nanocages: Bioconjugation and Their Potential Use as Optical Imaging Contrast Agents

Jingyi Chen、Fusayo Saeki、Benjamin J. Wiley 等 11 位作者2005-02-08OpenAlex

Gold nanocages of <40 nm in dimension have been synthesized using the galvanic replacement reaction between Ag nanocubes and HAuCl4 in an aqueous solution. By controlling the molar ratio between Ag and HAuCl4, the gold nanocages could be tuned to display surface plasmon resonance peaks around 800 nm, a wavelength comm…

Advanced Biosensing Techniques and ApplicationsNanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and Applications

Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite

Claude Ederer、Nicola A. Spaldin2005-02-08arXiv

We analyze the coupling between the ferroelectric and magnetic order parameters in the magnetoelectric multiferroic $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}$ using density functional theory within the local spin density approximation (LSDA) and the $\mathrm{LSDA}+\mathrm{U}$ method. We show that weak ferromagnetism of…

Advanced Condensed Matter PhysicsMultiferroics and related materialsUnderwater Acoustics Research

Deposition of Well‐Defined Fluoropolymer Nanospheres on PET Substrate by Plasma Polymerization of Heptadecafluorodecyl Acrylate and Their Potential Application as a Protective Layer

Jiachun Feng、Wei Huang、Guodong Fu 等 5 位作者2005-02-07Plasma Processes and Polymers

Abstract Summary: Fluoropolymer films consisting of well‐defined nanospheres were deposited via pulsed plasma polymerization of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10‐heptadecafluorodecyl acrylate (HDFA) on flexible poly(ethylene terephthalate) (PET) substrates. The morphology of the nanostructured fluoropolymer films w…

Polymer Nanocomposite Synthesis and IrradiationDiamond and Carbon-based Materials ResearchSurface Modification and Superhydrophobicity

Temperature variation of film tension above the bulk smectic-A–isotropic transition in freestanding liquid-crystal films

M. Veum、Ellynne Kutschera、N. Voshell 等 7 位作者2005-02-07Physical Review E

We have measured the temperature variation of film tension above the bulk smectic-A-isotropic transition in freestanding films of two liquid-crystal compounds. Above the transition, the tension increases sharply with temperature, and the slope is proportional to the film's thickness regardless of whether or not the co…

Adhesion, Friction, and Surface InteractionsAdvanced Materials and MechanicsLiquid Crystal Research Advancements

Comparison about the structure and properties of PAN‐based activated carbon hollow fibers pretreated with different compounds containing phosphorus

Junfen Sun、Lishun Wu、Qingrui Wang2005-02-07Journal of Applied Polymer Science

Abstract Polyacrylonitrile (PAN) hollow fibers were pretreated with five different compounds containing phosphorus, including ammonium dibasic phosphate, ammonium dihydrogen phosphate, triammonium phosphate, phosphoric acid, and metaphosphoric acid, and then further oxidized in air, carbonized in nitrogen, and activat…

Flame retardant materials and propertiesGraphene research and applicationsSupercapacitor Materials and Fabrication

Magnetoresistivity in the clustered state ofLa0.7−xYxCa0.3MnO3manganites

J. A. Souza、R. F. Jardim2005-02-07Physical Review B

We have performed a detailed characterization of both magnetic and transport properties of ${\mathrm{La}}_{0.7\ensuremath{-}x}{\mathrm{Y}}_{x}{\mathrm{Ca}}_{0.3}\mathrm{Mn}{\mathrm{O}}_{3}$ ($x=0$, 0.05, 0.10, and 0.15) compounds. These measurements provide clear evidence for three temperature intervals in which the m…

Multiferroics and related materialsAdvanced Condensed Matter PhysicsMagnetic and transport properties of perovskites and related materials

Mechanical properties and failure surface morphology of amine‐cured epoxy/clay nanocomposites

Hiroaki Miyagawa、Kit H. Foo、Isaac M. Daniel 等 4 位作者2005-02-07Journal of Applied Polymer Science

Abstract The tensile and impact properties of amine‐cured diglycidyl ether of bisphenol A based nanocomposites reinforced by organomontmorillonite clay nanoplatelets are reported. The sonication processing scheme involved the sonication of the constituent materials in a solvent followed by solvent extraction to genera…

Epoxy Resin Curing ProcessesPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry

Polar Anchoring Strength of a Tilted Nematic: Confirmation of the Dual Easy Axis Model

Giovanni Carbone、Charles Rosenblatt2005-02-07Physical Review Letters

The polar anchoring strength coefficient $W$ and polar pretilt angle ${\ensuremath{\theta}}_{0}$ were measured simultaneously for the liquid crystal pentylcyanobiphenyl at a rubbed polyimide alignment layer that is ordinarily used for vertical alignment. It was found that $W\ensuremath{\propto}{\ensuremath{\theta}}_{0…

Advanced Materials and MechanicsPhotonic Crystals and ApplicationsLiquid Crystal Research Advancements

Optoelectronically automated system for carbon nanotubes synthesis via arc-discharge in solution

Debasis Bera、Erik Brinley、Suresh C. Kuiry 等 7 位作者2005-02-07Review of Scientific Instruments

The method of arc discharge in the solution is unique and inexpensive route for synthesis of the carbon nanotubes (CNTs), carbon onions, and other carbon nanostructures. Such a method can be used for in situ synthesis of CNTs decorated with nanoparticles. Herein, we report a simple and inexpensive optoelectronically a…

Nanotechnology research and applicationsCarbon Nanotubes in CompositesNanowire Synthesis and Applications

Effective Temperature in Athermal Systems Sheared at Fixed Normal Load

Ning Xu、Corey S. O’Hern2005-02-07Physical Review Letters

We perform molecular dynamics simulations of repulsive athermal systems sheared at fixed normal load to study the effective temperature TL defined from time-dependent fluctuation-dissipation relations for density. We show that these systems possess two distinct regimes as a function of the ratio TS/V of the granular t…

Material Dynamics and PropertiesGranular flow and fluidized bedsHigh-pressure geophysics and materials

Protection of Silver‐Based Alloys from Tarnishing by Means of Plasma‐Enhanced Chemical Vapor Deposition

Riccardo d’Agostino、Francesco Fracassi、Fabio Palumbo 等 6 位作者2005-02-07Plasma Processes and Polymers

Abstract Summary: SiO 2 ‐like coatings have been deposited onto silver‐based alloys by means of plasma‐enhanced chemical vapor deposition (PECVD) fed with a tetraethoxysilane/oxygen mixture in order to study their capability to protect the alloys from tarnishing. Chemical and morphological characterization of the coat…

ZnO doping and propertiesCopper Interconnects and ReliabilityHigh-Temperature Coating Behaviors

Thermal analysis characterization of the degradation of biodegradable starch blends in soil

A. Vallés Lluch、Alfonso Martı́nez-Felipe、A. Ribes‐Greus 等 7 位作者2005-02-07Journal of Applied Polymer Science

Abstract Dynamic mechanical thermal analysis, differential scanning calorimetry (DSC), and thermogravimetric analysis were used to monitor the degradation of biodegradable blends in soil from vegetal sources consisting of dispersed thermoplastic starch and cellulosic derivatives. First, the viscoelastic behavior of th…

Microplastics and Plastic Pollutionbiodegradable polymer synthesis and propertiesNanocomposite Films for Food Packaging

Temperature-dependent luminescent properties of Eu–Tb complexes synthesizedin situin gel glass

Yan Liu、Guodong Qian、Zhiyu Wang 等 4 位作者2005-02-07Applied Physics Letters

The chelates of europium and terbium with hexafluoroacetylacetone (HFA) and triphenylphoshine oxide (TPPO), Eu∕Tb(HFA)3(TPPO)2, have been synthesized in situ in gel glasses with various concentrations of Eu3+ and Tb3+ ions. The photoluminescence spectra have been measured and the characteristic transitions of Tb3+ and…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesLuminescence Properties of Advanced Materials