Materials Literature
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Silicon immersion grating have opened the new possibilities of building compact high-resolution cryogenic spectrometers for the near-infrared (NIR) region from 1.4 to 5.5μm. We are developing a silicon immersion grating for a next-generation NIR high-resolution spectrometer attached to the Subaru 8.2 m telescope. S…
The Visible Integral-field Replicable Unit Spectrograph Prototype (VIRUS-P) has been in operation on the Harlan J Smith 2.7m Telescope at McDonald Observatory since October of 2006. The prototype was created to test the design and science capabilities of the full VIRUS instrument, wherein 150 copies of the spectrograp…
We are developing a new NIR high-resolution (R<sub>max</sub> = 100, 000) and high-sensitive spectrograph WINERED, specifically customized for short NIR bands at 0.9-1.35 μm. WINERED employs the following novel approaches in the optical system: portable design with a ZnSe immersion grating and warm optics without an…
Abstract Monodisperse InP nanocrystals were prepared by a facile one-pot solvothermal route via the pyrolysis reaction between indium chloride and tris(dimethylamino)phosphine at relatively low temperatures (150–180 °C). The InP nanocrystals after size-selective precipitation had a well-crystallized zinc blende struct…
We have developed a new type of soft x-ray diffraction grating. This critical-angle transmission (CAT) grating combines the advantages of traditional transmission gratings (low mass, extremely relaxed alignment and flatness tolerances) with those of x-ray reflection gratings (high efficiency due to blazing in the dire…
The number of internal double bonds in poly(vinyl chloride) (PVC) samples was studied as a function of molecular weight at various monomer conversions. These defect structures were found to exhibit end-group-like characteristics: their concentration per chain was largely constant as a function of molecular weight. Thi…
We report the formation of a highly stable amino stationary phase on diamond and demonstrate its use in solid-phase extraction (SPE). This process consists of spontaneous and self-limiting adsorption of polyallylamine (PAAm) from aqueous solution onto oxidized diamond. Thermal curing under reduced pressure or chemical…
The lateral structure of an ABA-type triblock copolymer polyparamethylstyrene- block-polystyrene- block-polyparamethylstyrene at the buried silicon substrate interface is studied as a function of different substrate surface treatments. With grazing incidence small-angle neutron scattering (GISANS), high interface sens…
The unusual behavior of smectites, the ability to change volume when wetted (swelling) or dried (shrinking), makes soil rich in smectites very unstable and dangerous for the building industry because of the movement of building foundations and poor slope stability. These macroscopic properties are dominated by the str…
The effect of polyethylene oxide (PEO) or polypropylene oxide (PPO) oligomers of various molecular weight (Mw) as well as of triblock copolymers, based on PEO and PPO blocks, on aqueous laponite RD suspensions was studied with small-angle neutron scattering (SANS). The radius of gyration (RG) increases for low M w whe…
We present a general theoretical framework suitable for an economical, but rigorous, analysis of the relaxivity and EPR data of paramagnetic metal complexes. This framework is based on the so-called Grenoble method that properly accounts for the fluctuations of the "static" zero-field splitting Hamiltonian and avoids…
This paper describes a study of CO 2 diffusion and adsorption in layered double-hydroxide (LDH) adsorbents using a gravimetric method. Four different particle size fractions, namely, 53−75, 75−90, 90−180, and 180−300 μm, were used in the study. The LDH materials were calcined in situ prior to the experiments, which re…
A systematically varying series of monolayer-protected clusters (MPCs) was prepared by exposing small gold nanoparticles ( approximately 2 nm in diameter) to the following four adsorbates: n-octadecanethiol ( n - C18), 2-hexadecylpropane-1,3-dithiol ( C18C2), 2-hexadecyl-2-methylpropane-1,3-dithiol ( C18C3), and 1,1,1…
Abstract Li2CuO2 was used for the CO2 chemisorption process. Li2CuO2 was thermally treated under a flux of CO2, dynamically (from 25 to 1000 °C) and isothermically. The results clearly showed that Li2CuO2 is able to chemisorb CO2 in a wider range of temperatures than those presented by other lithium ceramics. Therefor…
Third-generation (G3) poly(amidoamine) (PAMAM) dendrimers are simulated approaching 1,2-dimyristoyl- sn-glycero-3-phosphocholine (DMPC) bilayers with fully atomistic molecular dynamics, which enables the calculation of a free energy profile along the approach coordinate. Three different dendrimer terminations are exam…
Resistivity and piezoelectric response of individual ZnO nanorods were measured using scanning force microscopy. We found a variation in resistivity of 3 orders of magnitude, from 0.1 to 155 Omegacm and in piezoelectric coefficient ranging from 0.4 to 9.5 pm/V in ZnO nanorods grown from solution at the same time on th…
We describe the preparation by electrodeposition of arrays of lead telluride (PbTe) nanowires using the lithographically patterned nanowire electrodeposition (LPNE) method. PbTe nanowires had a rectangular cross-section with adjustable width and height ranging between 60-400 nm (w) and 20-100 nm (h). The characterizat…
The molecular structures and enthalpy release of poly(amidoamine) (PAMAM) dendrimers binding to 1,2-dimyristoyl- sn-glycero-3-phosphocholine (DMPC) bilayers were explored through atomistic molecular dynamics. Three PAMAM dendrimer terminations were examined: protonated primary amine, neutral acetamide, and deprotonate…
Members of the adenylate-forming family of enzymes play a role in the metabolism of halogenated aromatics and of short, medium, and long chain fatty acids, as well as in the biosynthesis of menaquinone, peptide antibiotics, and peptide siderophores. This family includes a subfamily of acyl- and aryl-CoA ligases that c…
We present a conceptual design for an innovative infrared cross-dispersed spectrograph for the NASA Infrared Telescope Facility (IRTF) at Mauna Kea. This facility-class instrument will provide a resolving power of up to 80,000 at 1.2-2.5 μm and 67,000 at 3-5 μm with a minimum slit width of 0.25". The instrument…