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The influence of molecular structure and π-system extent on nano- and microstructure of Langmuir layers of copper azaporphyrins

Larissa A. Valkova、Victor Erokhin、Alexandr S. Glibin 等 4 位作者2011-09-01Journal of Porphyrins and Phthalocyanines

Comparative analysis of the structure of floating layers formed by copper tetra-tert-butylsubstituted phthalocyanine ( CuPctBu4 ) and tetrabenzotriazaporphyrin ( CuThptBu4 ) dissolved in a number of solvents is performed. The influence of the π-system extent (tetra-tert-butylsubstituted copper porphyrazine and phthalo…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSurface Chemistry and Catalysis

Fine structure of polymeric compositions based on latexes modified by water-soluble phthalocyanine

Т. Р. Асламазова、В. А. Котенев、В. И. Золотаревский 等 4 位作者2011-09-01Protection of Metals and Physical Chemistry of Surfaces

The data of the atomic force microscopy of films and coatings based on the water-soluble polymer binders modified with water-dispersion phthalocyanine (WDP) are considered. In the formation of films from a latex polymer with a low glass-transition point (−17°C) and both nonmodified and phthalocyanine-modified latex pa…

Surface Modification and SuperhydrophobicityAdvanced Polymer Synthesis and CharacterizationPolymer composites and self-healing

An instrument for the investigation of actinides with spin resolved photoelectron spectroscopy and bremsstrahlung isochromat spectroscopy

S.-W. Yu、James Tobin、B W Chung2011-09-01Review of Scientific Instruments

A new system for spin resolved photoelectron spectroscopy and bremsstrahlung isochromat spectroscopy has been built and commissioned at Lawrence Livermore National Laboratory for the investigation of the electronic structure of the actinides. Actinide materials are very toxic and radioactive and therefore cannot be br…

Rare-earth and actinide compoundsRadioactive element chemistry and processingNuclear Materials and Properties

Magnetic anisotropy and magnetic excitations in supported atoms

Tobias Schuh、Timofey Balashov、Toshio Miyamachi 等 8 位作者2011-09-01Physical Review B

We present a view on inelastic scanning tunneling spectroscopy of magnetic impurities relying on states of the total angular momentum $J=L+S$ in the presence of a crystal field. We show that the selection rules for spin-flip scattering within the $J$-multiplet agree with the simple selection rules for the effective sp…

Quantum and electron transport phenomenaMagnetism in coordination complexesQuantum optics and atomic interactions

Occurrence of airborne algae within the township of Bukit Jalil in Kuala Lumpur, Malaysia

Evelyn Hui-Ping Ng、Wan-Loy Chu、Stephen Ambu2011-09-01Grana

There have been relatively few studies on airborne algae although they are known to have health implications. The aim of this study was to conduct a survey on the distribution of airborne algae within Bukit Jalil in Kuala Lumpur, Malaysia. The sampling sites included a quiet residential area, a busy area with high hum…

Lichen and fungal ecologyDiatoms and Algae ResearchBiocrusts and Microbial Ecology

Dynamical phase of driven colloidal systems with short-range attraction and long-range repulsion

Jiang‐Xing Chen、Jun-Wen Mao、Snigdha Thakur 等 5 位作者2011-09-01The Journal of Chemical Physics

We study the nonequilibrium dynamics of colloidal system with short-range depletion attraction and screened electrostatic repulsion on a disordered substrate. We find a growth-melting process of the clusters as the temperature is increased. By strengthening the screened electrostatic repulsion, a depinning transition…

Material Dynamics and PropertiesTheoretical and Computational PhysicsPickering emulsions and particle stabilization

Space charge injection in LDPE by semi-conductive electrode with different carbon black filling rates

Fenying Niu、Yewen Zhang、Zhenlian An 等 6 位作者2011-09-01OpenAlex

Electrode materials may play an important role in space charge accumulations. Semi-conductive electrodes, carbon black (CB) with ethylene vinyl acetate copolymer (EVA) in three different filling rates, 27vol%, 32vol% and 34vol%, were studied on their space charge injection. Results show that higher CB filling rate ind…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Hemispherical reflectance and emittance properties of carbon nanotubes coatings at infrared wavelengths

Manuel A. Quijada、John G. Hagopian、Stephanie Getty 等 5 位作者2011-09-01Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Recent visible wavelength observations of Multiwalled Carbon Nanotubes (MWCNT) coatings have revealed that they represent the blackest materials known in nature with a Total Hemispherical Reflectance (THR) of less than 0.25%. This makes them exceptionally good as absorbers, with the potential to provide order-ofmagnit…

Carbon Nanotubes in CompositesTransition Metal Oxide NanomaterialsCCD and CMOS Imaging Sensors

Fabrication and Dielectric Properties of (Ba0.7Sr0.3)TiO3–Glass Composites

Michihiro Tanaka、Kazutomo Abe、Hidenobu Itoh 等 4 位作者2011-09-01Japanese Journal of Applied Physics

Bulk and thick-film (Ba 0.7 Sr 0.3 )TiO 3 (BST)–glass composites with different dielectric properties were fabricated at 1000 °C from powder mixtures of a sol–gel-derived BST and a commercial glass (GP). Increasing the calcination temperature of the BST gel powder from 850 to 1000 °C resulted in an increase in the sin…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Tem analyses of the local crystal and domain structures in (na1-xkx)0.5bi0.5tio3perovskite ceramics

Mojca Otoničar、Srečo D. Škapin、Boštjan Jančar2011-09-01IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control

The local crystal and domain structures of the ((Na(1-x)K(x))(0.5)Bi(0.5)TiO(3) (NBT-KBT) solid solutions were studied because of their influence on the enhanced electromechanical properties of ceramics. Based on X-ray diffraction, the morphotropic phase boundary (MPB) was determined for the composition x = 0.20, in w…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

A NOVEL LEAD-FREE TRANSPARENT CERAMIC WITH HIGH ELECTRO-OPTIC COEFFICIENT

K. W. Kwok、Faliang Li、Dunmin Lin2011-09-01Functional Materials Letters

A novel lead-free transparent electro-optic ceramic (K 0.5 Na 0.5 ) 0.95 Li 0.05 Nb 0.95 Bi 0.0 5O 3 + 2 mol % excess Bi 2 O 3 has been fabricated by hot-press sintering. The ceramic possesses a dense, fine-grained and pure-perovskite structure. Owing to the decreases in optical anisotropy of the crystal structure and…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Piezoelectric properties and unipolar fatigue behavior of KNN-based Pb-free piezoceramics

Eric A. Patterson、David P. Cann2011-09-01IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control

Single-phase perovskite ceramics were synthesized using a Pb-free (K(0.44)Na(0.52)Li(0.04))(Nb(0.86)Ta(0.10)Sb(0.04))O(3) (LF4) piezoelectric material both with and without CuO as a dopant additive. Bipolar hysteresis measurements showed a relatively high remanent polarization (20 μC/cm(2), 16 μC/cm(2)) and maximum po…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Measurement of Mass Attenuation Coefficients of Blue Sapphire at Different Photon Energy by Compton Scattering Technique

J. Kaewkhao、P. Lofimkitjaroenporn、S. Tuscharoen 等 6 位作者2011-09-01Applied Mechanics and Materials

The mass attenuation coefficients of blue sapphire were measured at the different energy of γ-rays using the Compton scattering technique. There are in good agreement of scattered gamma rays energies between theoretical value and experimental value, reflecting the validation of Compton scattering system setup. The res…

Digital Radiography and Breast ImagingRadiation Shielding Materials AnalysisAdvanced X-ray and CT Imaging

Flame‐retardant polycarbonate/acrylonitrile‐butadiene‐styrene based on red phosphorus encapsulated by polysiloxane: Flame retardance, thermal stability, and water resistance

Rongkun Jian、Li Chen、Zhi Hu 等 4 位作者2011-09-01Journal of Applied Polymer Science

Abstract Red phosphorus encapsulated by polysiloxane (MRP) was prepared, and the chemical structure and morphology of MRP were characterized by FTIR and TEM, respectively. A series of flame retardant polycarbonate/acrylonitrile‐butadiene‐styrene containing MRP (PC/ABS/MRP) were prepared via melt‐blending. The flame re…

Flame retardant materials and propertiesSilicone and Siloxane Chemistry

Hepatotoxicity of silica nanoparticles with a diameter of 100 nm

T Hasezaki、Katsuhiro Isoda、Masuo Kondoh 等 5 位作者2011-09-01Die Pharmazie

Nanomaterials have potential toxicity that is not found in micromaterials, and it is therefore essential to understand their biological activity and potential toxicity. We focused on silica nanoparticles, since it was previously reported that the intravenous administration of silica nanoparticles with a diameter of 70…

Nanoparticles: synthesis and applications

Effect of natural aging on photoluminescence of porous silicon

A. S. Lenshin、В. М. Кашкаров、S. Yu. Turishchev 等 5 位作者2011-09-01Technical Physics Letters

The influence of natural aging on the intensity and position of the photoluminescence (PL) peak in n-type porous silicon (por-Si) has been studied. Changes in the phase composition and relative content of the amorphous and oxide phases in por-Si during aging were determined by simulating the spectra of Si L 2,3 ultras…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Determination of the effective coercive field of ferroelectrics by piezoresponse force microscopy

Martin Lilienblum、E. Soergel2011-09-01Journal of Applied Physics

The effective coercive field Ec for ferroelectric domain reversal is usually determined in a capacitor-like geometry by increasing an applied electric field until poling occurs. Here we present a different method based on local poling with the tip of a scanning force microscope and analyzing the dependence of the doma…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Orientational behaviour of ultraviolet-tailored 4-cyano-4'-pentylbiphenyl at the aqueous/liquid crystal interface

Qiongzheng Hu、Chang‐Hyun Jang2011-09-01Liquid Crystals

In this study, we examined the anchoring behaviour of the ultraviolet (UV)-tailored nematic liquid crystal (LC) 4-cyano-4'-pentylbiphenyl (5CB) at the aqueous/LC interface. A range of photochemical reaction products are generated when 5CB is exposed to UV light, including the main product 4-cyano-4’-biphenylcarboxylic…

Liquid Crystal Research AdvancementsLipid Membrane Structure and BehaviorSurfactants and Colloidal Systems

Barrier effects of polyaniline layer in surface modified MF-4SK/Polyaniline membranes

Н. П. Березина、S. A. Shkirskaya、M. V. Kolechko 等 6 位作者2011-09-01Russian Journal of Electrochemistry

An express method of synthesis of surface-modified membrane composites is suggested that allows obtaining heterogeneous materials featuring effects of the blocking of the transport of solvent ions and molecules. Studies using the methods of atomic force microscopy (AFM), differential scanning calorimetry (DSC), thermo…

Electrochemical sensors and biosensorsFuel Cells and Related MaterialsConducting polymers and applications

Mechanical Properties of Chemically Treated Sawdust-Reinforced Recycled Polyethylene Composites

Md. Nazrul Islam、Md. Sakinul Islam2011-09-01Industrial & Engineering Chemistry Research

In the present work, cetyltrimethylammonium bromide (CTAB)-treated sawdust-reinforced recycled polyethylene (RPE) composites were prepared by injection molding method. The mechanical properties of RPE composites reinforced with CTAB-treated sawdust were evaluated and the results were compared with those of untreated o…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesInnovative concrete reinforcement materials