Materials Literature
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A cyclic tetramer of pyrene, [4]cyclo-2,7-pyrenylene ([4]CPY), was synthesized from pyrene in six steps and 18% overall yield by the platinum-mediated assembly of pyrene units and subsequent reductive elimination of platinum. The structures of the two key intermediates were unambiguously determined by X-ray crystallog…
Effects of addition of Zn (up to 1 wt%) on microstructure, precipitate structure and intergranular corrosion (IGC) in an Al–Mg–Si alloys were investigated. During ageing at 185 °C, the alloys showed modest increases in hardness as function of Zn content, corresponding to increased number densities of needle-shaped pre…
Microalgal biomass harvested from wastewater treatment high rate algal ponds may be valorised through anaerobic digestion producing biogas. However, microalgae anaerobic biodegradability is limited by their complex cell wall structure. Thus, pretreatment techniques are being investigated to improve microalgae methane…
Ancient Jian wares are famous for their lustrous black glaze that exhibits unique colored patterns. Some striking examples include the brownish colored "Hare's Fur" (HF) strips and the silvery "Oil Spot" (OS) patterns. Herein, we investigated the glaze surface of HF and OS samples using a variety of characterization m…
This paper deals with the problem of controlling a hybrid energy storage system (HESS) for electric vehicles. The storage system consists of a fuel cell (FC), serving as the main power source, and a supercapacitor (SC), serving as an auxiliary power source. It also contains a power block for energy conversion consisti…
Hybrid nanostructures based on graphene and transition metal oxides hold great promise as high‐performance electrode materials for next‐generation lithium‐ion batteries. In this work, the rational design and fabrication of NiCo2O4 nanosheets supported on reduced graphene oxide (denoted as rGO/NiCo2O4) is presented as…
Carbonaceous materials have great potential for applications as anodes of alkali-metal ion batteries, such as Na-ion batteries and K-ion batteries (NIB and KIBs). We conduct an in situ study of the electrochemically driven sodiation and potassiation of individual carbon nanofibers (CNFs) by transmission electron micro…
The aim of this study was to determine the size-dependent penetration ability of gold nanoparticles and the potential application of ultrasmall gold nanoparticles for intranucleus delivery and therapy. We synthesized gold nanoparticles with diameters of 2, 6, 10, and 16 nm and compared their intracellular distribution…
The development of accurate molecular mechanics force fields is a significant challenge that must be addressed for the continued success of molecular simulation. We developed the ForceBalance method to automatically derive accurate force field parameters using flexible combinations of experimental and theoretical refe…
UNLABELLED: Prions are self-templating protein aggregates that stably perpetuate distinct biological states and are of keen interest to researchers in both evolutionary and biomedical science. The best understood prions are from yeast and have a prion-forming domain with strongly biased amino acid composition, most no…
We report a 2D layered metal-organic framework (MOF) with wide channels named NUS-1 and its activated analogue NUS-1a composed of Zn4O-like secondary building units and tetraphenylethene (TPE)-based ligand 4,4'-(2,2-diphenylethene-1,1-diyl)dibenzoic acid. Due to its special structure, NUS-1a exhibits unprecedented gas…
Perovskite-based solar cells have recently been catapulted to the cutting edge of thin-film photovoltaic research and development because of their promise for high-power conversion efficiencies and ease of fabrication. Two types of generic perovskites compounds have been used in cell fabrication: either Pb- or Sn-base…
We studied the electronic properties of graphene nanoribbons with several edge structures under a parallel electric field using density functional theory with the effective screening medium method. Our calculations showed that the edge atomic sites of the nanoribbons with zigzag-shaped edges anomalously screen the ele…
Abstract In order to overcome limitations in the processing parameters of powder compaction method, a novel processing technique based on sol-gel route has been developed to produce near-net-shaped prototype fine zirconia minispheres with required properties that could potentially be used as grinding media. Impact of…
ABSTRACT Tetracycline hydrochloride loaded poly(vinyl alcohol)/soybean protein isolate/zirconium (Tet–PVA/SPI/ZrO2) nanofibrous membranes were fabricated via an electrospinning technique. The average diameter of the PVA/soybean protein isolate (SPI)/ZrO2 nanofibers used as drug carriers increased with increasing ZrO2…
An experimental technique for visualizing in-plane distributions of polarization states for an electromagnetic wave has been proposed and demonstrated successfully; distributions of rotating electric near-field vectors E xy as well as their elliptic traces have been imaged electrooptically at a series of distances fro…
The continuous increase of the operating frequency and density of integrated circuits leads to consider single-wall carbon nanotubes (SWCNTs) and multiwall carbon nanotubes (MWCNTs) as the most promising candidates for future interconnect technology because of their high current-carrying capacity and conductivity in t…
We apply well-characterized silver nanowire grating (Ag-NWG) plasmonic surfaces as a Raman surface spectroscopy tool, which is based on surface-enhanced Raman scattering (SERS), to study the surface conformation characteristics of amine terminated alkanethiol self-assembled monolayers (SAMs). The surface conformation…
Electron beam irradiation efffects on polymer cross-linking used for wire and cable insulations are still being researched. This study showed that upon irradiation, ethylene vinyl acetate (EVA) and maleic anhydride grafted polyethylene (LDPE-g-MAH) addition as coupling agent to the LDPE/fillers, improved processing an…
Isolating enantiomers by crystallization via diastereomer salt formation is widely used in the pharmaceutical industry. Unfortunately, we found that, when some diastereomer impurity exists, oiling-out will take place and significantly decrease the resolution efficiency. To identify the role of impurities in oiling-out…