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Large-Scale Reactive Molecular Dynamics Simulation and Kinetic Modeling of High-Temperature Pyrolysis of the Gloeocapsomorphaprisca Microfossils

Chenyu Zou、Sumathy Raman、Adri C. T. van Duin2014-05-12The Journal of Physical Chemistry B

The ability to predict accurately the thermal conversion of complex carbonaceous materials is of value in both petroleum exploration and refining operations. Modeling the thermal cracking of kerogen under basinal heating conditions improves the predrill prediction of oil and gas yields and quality, thereby ultimately…

Thermochemical Biomass Conversion ProcessesPetroleum Processing and AnalysisThermal and Kinetic Analysis

Chemical Processes During Energy‐Saving Preparation of Lightweight Ceramics

Lidia K. Kazantseva、Sergey V. Rashchenko2014-05-12Journal of the American Ceramic Society

Lightweight glass‐ceramic material similar to foam glass was obtained at 700°C–800°C directly from alkali‐activated silica clay and zeolitized tuff without preliminary glass preparation. It was characterized by low bulk density of 100–250 kg/m 3 and high pore size homogeneity. Chemical processes occurring in alkali‐ac…

Concrete and Cement Materials ResearchGlass properties and applicationsRecycling and utilization of industrial and municipal waste in materials production

Thermodynamics of the Quasi-Epitaxial Flavin Assembly around Various-Chirality Carbon Nanotubes

Sina Sharifi、Milinda Samaraweera、José A. Gascón 等 4 位作者2014-05-12Journal of the American Chemical Society

Establishing methods to accurately assess and model the binding strength of surfactants around a given-chirality single-walled carbon nanotube (SWNT) are crucial for selective enrichment, targeted functionalization, and spectrally sharp nanodevices. Unlike surfactant exchange, which is subject to interferences from th…

DNA and Nucleic Acid ChemistryPorphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic Compounds

Adsorption of HCN onto sodium montmorillonite dependent on the pH as a component to chemical evolution

Marìa Colín-García、A. Heredia、A. Negrón-Mendoza 等 6 位作者2014-05-12International Journal of Astrobiology

Abstract The aim of this work is to study the behaviour of hydrogen cyanide (HCN) adsorbed onto mineral surfaces (sodium montmorillonite, a clay mineral) in different pH environments as a possible prebiotic process for complexation of organics. Our experimental results show that specific sites on the surface of the cl…

Origins and Evolution of LifeClay minerals and soil interactionsChemical Analysis and Environmental Impact

Influence of Temperature and Material Deposit on Material Removal Uniformity during Optical Pad Polishing

Tayyab I. Suratwala、Michael D. Feit、William A. Steele 等 4 位作者2014-05-12Journal of the American Ceramic Society

The effects of temperature and material deposit on workpiece material removal spatial uniformity during optical pad polishing are described. Round and square‐fused silica workpieces (25–265 mm in size) were polished on a polyurethane pad using ceria slurry under various conditions. Using a nonrotated workpiece on a ro…

Advanced machining processes and optimizationDiamond and Carbon-based Materials ResearchAdvanced Surface Polishing Techniques

Hydrogen ion-selective electrolyte-gated organic field-effect transistor for pH sensing

Johannes Kofler、Kerstin Schmoltner、Andreas Klug 等 4 位作者2014-05-12Applied Physics Letters

A H+ ion-selective electrolyte-gated organic field-effect transistor (IS-EGOFET) with a broad detection range between pH 3 and pH 12, is presented. This pH sensor relies on an integrated EGOFET used as a transducer in combination with an ionophore-doped polymeric ion-selective membrane serving as a sensing element. Th…

Conducting polymers and applicationsAcoustic Wave Resonator TechnologiesAnalytical Chemistry and Sensors

Angular tunable zero-field ferromagnetic resonance frequency in oblique sputtered CoFeBSm thin films

Guozhi Chai、Nguyen N. Phuoc、Chong Kim Ong2014-05-12Applied Physics Express

We investigated the high-frequency magnetic properties of oblique-sputtered CoFeBSm thin films. We found that the zero-field ferromagnetic resonance frequency f r can be tuned from 3.8 to 6.4 GHz by rotating the samples within the plane. The angular tunable f r is tentatively explained with the competition of uniaxial…

Magnetic properties of thin filmsZnO doping and propertiesHeusler alloys: electronic and magnetic properties

Regenerative medicine in orthopedics using cells, scaffold, and microRNA

Mitsuo Ochi、Tomoyuki Nakasa、Goki Kamei 等 5 位作者2014-05-12Journal of Orthopaedic Science

Cells, scaffold, and growth factors are crucially important in regenerative medicine and tissue engineering. Progress in science and technology has enabled development of these three factors, with basic research being applied clinically. In the past decade, we have investigated tissue regeneration in animal models of…

Mesenchymal stem cell researchElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Bacterial Magnetosome Biomineralization - A Novel Platform to Study Molecular Mechanisms of Human CDF-Related Type-II Diabetes

Natalie Zeytuni、René Uebe、Michal Maes 等 10 位作者2014-05-12PLoS ONE

Cation diffusion facilitators (CDF) are part of a highly conserved protein family that maintains cellular divalent cation homeostasis in all organisms. CDFs were found to be involved in numerous human health conditions, such as Type-II diabetes and neurodegenerative diseases. In this work, we established the magnetite…

Enzyme Structure and FunctionGeomagnetism and Paleomagnetism StudiesMagnetic and Electromagnetic Effects

L1 FePt-ZrO2 (001) nanostructured films with high aspect ratio columnar grains

Kaifeng Dong、Huihui Li、Yingguo Peng 等 6 位作者2014-05-12Applied Physics Letters

In order to increase the signal-to-noise ratio of heat assisted magnetic recording, it is desirable to fabricate high magnetic anisotropy FePt media with small grain size and high aspect ratio (grain height to size ratio). In the present paper, we report that FePt media with small grain size and high aspect ratio were…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsCharacterization and Applications of Magnetic Nanoparticles

Advances in Modeling Sorption and Diffusion of Moisture in Porous Reactive Materials

Stephen J. Harley、Elizabeth A. Glascoe、James P. Lewicki 等 4 位作者2014-05-12ChemPhysChem

Water-vapor-uptake experiments were performed on a silica-filled poly(dimethylsiloxane) (PDMS) network and modeled by using two different approaches. The data was modeled by using established methods and the model parameters were used to predict moisture uptake in a sample. The predictions are reasonably good, but not…

Microfluidic and Capillary Electrophoresis ApplicationsEpoxy Resin Curing ProcessesPolymer Foaming and Composites

MicroRNA-203 inhibits malignant melanoma cell migration by targeting versican

Pingyuan Bu、Ping Yang2014-05-12Experimental and Therapeutic Medicine

MicroRNA (miR)-203 has been demonstrated to function as a suppressor in tumorigenesis. Recently, miR-203 was reported to play a role in malignant melanoma (MM); however, the detailed function of miR-203 in MM remains unclear. In the present study, the expression of miR-203 was shown to be significantly downregulated i…

MicroRNA in disease regulationProteoglycans and glycosaminoglycans researchSilk-based biomaterials and applications

Silencing of the CaCP Gene Delays Salt- and Osmotic-Induced Leaf Senescence in Capsicum annuum L.

Huaijuan Xiao、Yanxu Yin、Weiguo Chai 等 4 位作者2014-05-12International Journal of Molecular Sciences

Cysteine proteinases have been known to participate in developmental processes and in response to stress in plants. Our present research reported that a novel CP gene, CaCP, was involved in leaf senescence in pepper (Capsicum annuum L.). The full-length CaCP cDNA is comprised of 1316 bp, contains 1044 nucleotides in o…

Plant Stress Responses and ToleranceCarbon and Quantum Dots ApplicationsPlant Micronutrient Interactions and Effects

An assessment of the dynamic stability of microorganisms on patterned surfaces in relation to biofouling control

Partha Halder、Mahyar Nasabi、Niranjali Jayasuriya 等 8 位作者2014-05-12Biofouling

Microstructure-based patterned surfaces with antifouling capabilities against a wide range of organisms are yet to be optimised. Several studies have shown that microtopographic features affect the settlement and the early stages of biofilm formation of microorganisms. It is speculated that the fluctuating stress-stra…

Polymer Surface Interaction StudiesMicrofluidic and Bio-sensing TechnologiesMicro and Nano Robotics

Effect of Annealing on the First-Cycle Performance and Reversible Capabilities of Lithium-Rich Layered Oxide Cathodes

Yufang Chen、Zhongxue Chen、Kai Xie2014-05-12The Journal of Physical Chemistry C

The cathode materials of lithium-rich 0.4Li 2 MnO 3 ·0.6LiNi 1/3 Co 1/3 Mn 1/3 O 2 have been synthesized via coprecipitation method. To propose a better understanding of the effects of annealing on the cathode material, the bulk and surface structures of the pristine and cycled samples of 0.4Li 2 MnO 3 ·0.6LiNi 1/3 Co…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Austenite–martensite/bainite orientation relationship: Characterisation parameters and their application

Victoria A. Yardley、E. J. Payton2014-05-12Materials Science and Technology

Transformations from austenite to martensite or bainite in ferrous alloys have great technological importance, but some aspects remain elusive. The orientation relationship (OR), morphology and habit plane can vary considerably from one system to another. Much published work considers these OR in terms of their variat…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Microfluidic Thermally Activated Materials for Rapid Control of Macroscopic Compliance

Aditya Balasubramanian、Mike Standish、Christopher J. Bettinger2014-05-12Advanced Functional Materials

Macroscopic structures that can undergo rapid and reversible stiffness transitions can serve as functional polymeric materials for many applications in robotics and medical devices. Thermomechanical phase transitions can provide a suitable mechanism for transient control of mechanical properties. However, the characte…

Advanced Sensor and Energy Harvesting MaterialsPolymer composites and self-healingAdvanced Materials and Mechanics

A Fused‐Ring Acceptor Unit in D–A Copolymers Benefits Photovoltaic Performance

Chuantian Zuo、Jiamin Cao、Liming Ding2014-05-12Macromolecular Rapid Communications

Pentacyclic lactam acceptor unit TPTI invented by our group is proved to be a good building block for efficient D-A copolymers used in organic solar cells. Here, two D-A copolymers PBTTPTI and PTTTPTI are developed by copolymerizing TPTI with 2,2'-bithiophene (BT) or thieno[3,2-b]thiophene (TT). PBTTPTI and PTTTPTI ex…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Development of silicon electrode enhanced by carbon nanotube and gold nanoparticle composites on silicon neural probe fabricated with complementary metal-oxide-semiconductor process

Songsong Zhang、Wei Mong Tsang、Srinivas Merugu 等 7 位作者2014-05-12Applied Physics Letters

We present the fabrication of highly P-doped single crystal silicon electrodes on a silicon probe through complementary metal-oxide-semiconductor (CMOS)-compatible processes. The electrode with diameter of 50 μm and a separation of 200 μm is designed for recording/stimulating purposes. Electrochemical impedance spectr…

Advanced Memory and Neural ComputingConducting polymers and applicationsNeuroscience and Neural Engineering

Cost-Effective Systems for Atomic Layer Deposition

Michael Lubitz、Phillip A. Medina、Aleks Antic 等 5 位作者2014-05-12Journal of Chemical Education

Herein, we describe the design and testing of two different home-built atomic layer deposition (ALD) systems for the growth of thin films with sub-monolayer control over film thickness. The first reactor is a horizontally aligned hot-walled reactor with a vacuum purging system. The second reactor is a vertically align…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides