Materials Literature
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Abstract A Haake torque rheometer equipped with an internal mixer is used to study the influence of the amount of sodium montmorillonite (Na + ‐MMT) and organically modified MMT (O‐MMT) on X‐ray diffraction (XRD), morphology, and mechanical characteristics of rigid poly (vinyl chloride) (PVC)/Na + ‐MMT and PVC/O‐MMT n…
Monoclonal antibody therapeutics is an important and fast expanding market. While production of these molecules has been a major area of research, much less is known regarding the stabilization of these proteins for delivery as drugs. Crystallization of antibodies is one such promising route for protein stabilization…
Abstract Polypropylene (PP) foam has been considered as a potential substitute for other thermoplastics foams in industrial applications. However, the key concern is the weak melt strength of PP, which leads to a high content of open‐cell structure in PP foams; and, thus, unsatisfactory for a number of applications. I…
The local and cooperative dynamics in atactic (a-PS) and syndiotactic (s-PS) polystyrene were studied by broadband dielectric spectroscopy. Besides the known α-relaxation, two additional relaxation processes β 1 and β 2 were revealed in various samples of a-PS and s-PS films cast from solvent solutions. These new dyna…
Abstract Eight new flame‐retardant poly(amide‐imide)s with high inherent viscosities containing phosphine oxide moieties in main chain were synthesized from the polycondensation reaction of N , N ′‐(3,3′‐diphenylphenylphosphine oxide) bistrimellitimide diacid chloride 7, with eight ;aromatic diamine 8a–h by two differ…
Facially amphiphilic biaryl dendrimers are compared with the more classical benzyl ether amphiphilic dendrimers for molecular recognition, using protein binding as the probe. The protein used for the proposed study is chymotrypsin (ChT). A generation-dependent binding affinity was observed with the benzyl ether dendri…
We have developed a series of azobenzene liquid crystals (azo LC) compounds, both multicomponent as well as single component, that possess room temperature nematic and smectic phases. Some of these materials have a wide mesophase temperature range which makes them useful for a variety of practical applications. Two ma…
The synthesis, crystal structure and preliminary magnetic studies are reported for a very highly reduced, VIV8VIII2, polyoxo(alkoxo)vanadate with a unique square prismatic topology.
Abstract The dry–jet–wet spinning process was employed to spin poly(lactic acid)(PLA) fiber by the phase inversion technique using chloroform and methanol as solvent and nonsolvent, respectively, for PLA. The as spun fiber was subjected to two‐stage hot drawing to study the effect of various process parameters, such a…
Abstract Exfoliated nylon‐11/layered silicate nanocomposites were prepared via in situ polymerization by dispersing organoclay in 11‐aminoundecanoic acid monomer. The original clay was modified by a novel method with 11‐aminoundecanoic acid. In situ Fourier transform infrared spectroscopy results show that stronger hy…
A key liquid crystalline property for electro-optic applications is the Fredericksz threshold electric field. There has been recent experimental interest in liquid crystal-based colloidal suspensions in which the colloidal nanoparticles both possess a permanent electric polarization and provide strong director anchori…
As a simple model for a Pickering emulsion droplet, we consider the adsorption of spherical particles to a spherical liquid-liquid interface in order to investigate the curvature effect on the particle adsorption. By taking into account both the surface and the volume energies due to the presence of a particle, we sho…
The numerical implementation of a gradient-enhanced continuum coupled damage—plasticity model as a constitutive framework to model the nonlocal response of materials is presented. By the introduction of “nonlocal, ” gradient-enhanced measures in the plasticity potential function and yield criterion and in the damage p…
Abstract Controlled grafting of well‐defined polymer brushes on the poly(vinylidene fluoride) (PVDF) films was carried out by the surface‐initiated atom transfer radical polymerization (ATRP). Surface‐initiators were immobilized on the PVDF films by surface hydroxylation and esterification of the hydroxyl groups coval…
Abstract Polystyrene (PS)/ZnAl layered double‐hydroxide (LDH) nanocomposites were synthesized via in situ emulsion and suspension polymerization in the presence of N ‐lauroyl‐glutamate surfactant and long‐chain spacer and characterized with elemental analysis, Fourier transform infrared spectrum, X‐ray diffraction (XR…
Abstract A multiepoxy cubic silsesquioxane was prepared by the hydrolysis and polycondensation of trifunctional monomer (γ‐glycidoxypropyl)trimethoxysilane in a solvent mixture of methyl isobutyl ketone and anhydrous ethanol with a tetraethyl ammonium hydroxide aqueous solution acting as the catalyst, and it was succe…
A new method is described for surface functionalization of silicon nanocrystals. Organic monolayers were self-assembled via gas-phase adsorption of amines, alkenes, alkynes, and aldehydes onto the surfaces of aerosolized crystalline silicon nanoparticles of 12.2 nm diameter in an atmospheric pressure tube reactor. Ass…
Sequenzielle Belegung von Siliciumoxidkügelchen durch kovalentes Binden von Magnetitnanopartikeln (blau) und Befestigen von funktionellen Au-, CdSe/ZnS- oder Pd-Nanopartikeln (rot) führte zu multifunktionellen Systemen, in denen Magnetismus mit Oberflächenplasmonenresonanz (Au), Lumineszenz (CdSe/ZnS) bzw. katalytisch…
Abstract Hemp fibers were used as natural reinforcement in composites of thermosetting vegetal oil based resin. Boards with fibers content from 0 to 65 vol % were produced by hot pressing. The mechanical properties were investigated with flexural testing. The effect of effect has been observed on both modulus and stre…
This paper provides a complete physical picture of optical response time as a function of cell gap (d) in a wide voltage regime. Normally both rise and decay times are known to be proportional to d 2 in the small angle approximation (), and in the high voltage regime where V π < V < V i the optical decay time is indep…