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Stabilization of the high-temperature phases of HfO2 by pulsed laser irradiation

М. А. Пугачевский、V. I. Panfilov2014-05-04Inorganic Materials

Spherical hafnia nanoparticles have been prepared by laser ablation. The particle size has been shown to decrease with increasing incident laser intensity. X-ray diffraction and transmission electron microscopy data demonstrate that incident intensities above 5 × 10 9 W/m 2 ensure the formation of the high-temperature…

Semiconductor materials and devicesAdvancements in Semiconductor Devices and Circuit DesignElectronic and Structural Properties of Oxides

Study on the Reaction Mechanism of Potassium Titanate Fibers

Xiaoli Ji、Shijiang Wu、Song Zhang 等 4 位作者2014-05-04Integrated ferroelectrics

Potassium titanate fibers were synthesized using titaniumdioxide and K2CO3 as starting materials with Kneading-Drying-Calcination method. The reaction mechanism for the formation of K2Ti4O9 was investigated by TG-DSC, XRD and SEM with different TiO2/K2CO3 molar ratios. The results show that the TiO2/K2CO3 molar ratios…

Bone Tissue Engineering MaterialsMXene and MAX Phase MaterialsChemical Synthesis and Characterization

Structural changes accompanying color center formation in lithium fluoride exposed to femtosecond laser pulses

L. I. Bryukvina、S. V. Lipko、Andrey Kuznetsov 等 4 位作者2014-05-04Inorganic Materials

This paper examines structural changes produced in crystalline LiF by high-power femtosecond laser pulses and provides some insight into the mechanisms of structural damage to the material. In the region of the onset of multiple femtosecond laser beam filamentation and in the central part of the filaments, we observed…

Diamond and Carbon-based Materials ResearchLaser Material Processing TechniquesAdvanced Surface Polishing Techniques

Organic nitrate functional nanoparticles for the glutathione-triggered slow-release of nitric oxide

Hien Duong、Amy Ho、Thomas P. Davis 等 4 位作者2014-05-04Journal of Polymer Science Part A Polymer Chemistry

Nitrate-containing amphiphilic block copolymer chains were self-assembled into micellar nanostructures as a reservoir for the slow-release delivery of nitric oxide (NO). Poly(oligo(ethylene glycol) methyl ether methacrylate)-block-poly(vinyl benzyl chloride-co-styrene) was prepared by reversible addition fragmentation…

Nanoplatforms for cancer theranosticsLanthanide and Transition Metal ComplexesSulfur Compounds in Biology

Growth and spectroscopic characteristics of Yb3+-Doped NaBi(MoO4)2 crystals

Б. Н. Цыдыпова、Natali Gusakova、A. A. Pavlyuk 等 7 位作者2014-05-04Inorganic Materials

We have determined the growth charge composition and low thermal gradient (< 1°C/cm) Czochralski pulling parameters for the growth of bulk homogeneous Yb 3+ -doped NaBi(MoO 4 ) 2 crystals and assessed the main spectroscopic characteristics of the Yb 3+ :NaBi(MoO 4 ) 2 crystals as laser materials.

Luminescence Properties of Advanced MaterialsPhotorefractive and Nonlinear OpticsSolid State Laser Technologies

Advanced Soft Material Beamline Consortium at SPring-8 (FSBL)

Atsushi Takahara、Toshiro Takeda、Toshiji Kanaya 等 8 位作者2014-05-04Synchrotron Radiation News

Soft materials, such as polymers and fibers, are key industries in Japan and play a significant role in our daily lives [1 T. Yano, Polymer 21, 4702–4708 (2012).[Crossref], [Web of Science ®] , [Google Scholar]–3 Y. Shinohara, Macromolecules 43, 9480–9487 (2010).[Crossref], [Web of Science ®] , [Google Scholar]]. Thes…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Influence of phosphate sorption on dispersion of a Ferralsol

Dung Viet Pham、Munehide Ishiguro、Ha Thu Thi Tran 等 4 位作者2014-05-04Soil Science & Plant Nutrition

Soil dispersion induces soil erosion and colloidal leaching. Nutrients are lost at the same time and this causes water contamination. Phosphate is an essential element for living organisms. Because phosphate influences soil dispersion and it is an important limited resource, this influence must be evaluated well in or…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Ways of improving functional parameters of high-temperature ferroelectric/piezoelectric ceramics based on BiScO3-PbTiO3 solid solutions

А. Г. Сегалла、С. С. Нерсесов、Г. М. Калева 等 4 位作者2014-05-04Inorganic Materials

We have examined the effect of preparation conditions on the structure and piezoelectric characteristics of ceramic samples in the form of thin piezoelectric disks cut from large sintered (1 − x )BiScO 3 - x PbTiO 3 ( x = 0.635–0.645) bodies. The use of chemical coprecipitation from nitrate solutions allowed us to pre…

Ferroelectric and Piezoelectric MaterialsOptical and Acousto-Optic TechnologiesMaterial Science and Thermodynamics

Anti-inflammatory, antioxidant and in silico studies of Buddleja salviifolia (L). Lam leaf constituents

S.C. Pendota、A.R. Ndhlala、Adeyemi O. Aremu 等 5 位作者2014-05-04South African Journal of Botany

Buddleja salviifolia leaves are used for the treatment of eye infections and neurodegenerative conditions in South Africa. Three phenolic compounds identified as 4′-hydroxyphenyl ethyl vanillate (1), acteoside (2) and quercetin (3) from leaf extracts of the B. salviifolia were investigated for cyclooxygenase-2 (COX-2)…

Natural product bioactivities and synthesisPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

Triple stimuli-responsive amphiphilic glycopolymer

Wenjuan Guo、Tieshi Wang、Xinde Tang 等 6 位作者2014-05-04Journal of Polymer Science Part A Polymer Chemistry

Triple stimuli (temperature/pH/photo)-responsive amphiphilic glycopolymer, poly(2-(dimethylamino)ethyl methacrylate-co-6-O-methacryloyl-1,2,3,4-di-O-isopropylidene-D-galactopyranose)-b-poly(4-(4-methoxyphenylazo)phenoxy methacrylate) [P(DMAEMA-co-MAIpGP)-b-PMAZO] was synthesized by atom transfer radical polymerization…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationPolymer Surface Interaction Studies

Effect of Temperature and Nanoparticle Size on Sensor Properties of Nanostructured Tin Dioxide Films

Mortko Kozhushner、Л. И. Трахтенберг、V. L. Bodneva 等 6 位作者2014-05-04The Journal of Physical Chemistry C

The previously developed theory of sensor response is validated by detailed comparison with experiment. For this purpose, new experiments are performed to investigate the sensitivity of semiconductor tin dioxide (SnO 2 ) nanostructured thin films with average nanoparticle diameter ≈120 nm as a function of temperature…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsAdvanced Chemical Sensor Technologies

Intermediate coupling model of the cuprates

Tanmoy Das、R. S. Markiewicz、Arun Bansil2014-05-04Advances In Physics

We review the intermediate coupling model for treating electronic correlations in the cuprates. Spectral signatures of the intermediate coupling scenario are identified and used to adduce that the cuprates fall in the intermediate rather than the weak or the strong coupling limits. A robust, ‘beyond local-density appr…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Enhanced oil recovery using oil-in-water (o/w) emulsion stabilized by nanoparticle, surfactant and polymer in the presence of NaCl

Tushar Sharma、G. Suresh Kumar、Jitendra S. Sangwai2014-05-04Geosystem Engineering

A conventional waterflood often leads to unsuccessful recovery of oil, as most of the injected water tends to channel into the more permeable zones. Pickering emulsions stabilized using surfactant and colloidal particles, such as nanoparticles, are gaining wider recognition in the petroleum industry due to their bette…

Hydrocarbon exploration and reservoir analysisEnhanced Oil Recovery TechniquesPickering emulsions and particle stabilization

Life Cycle Impact of Rare Earth Elements

Paul Koltun、A. Tharumarajah2014-05-04ISRN Metallurgy

The diverse properties of rare earth elements have seen broad and growing applications in clean energy technologies, hybrid vehicles, pollution control, optics, refrigeration, and so on. This study presents a “cradle-to-gate” life cycle assessment of the energy use, resource depletion, and global warming potential res…

Extraction and Separation ProcessesGeochemistry and Elemental AnalysisMetallurgy and Material Science

MOF-derived Nanoporous Carbon as Intracellular Drug Delivery Carriers

Nagy L. Torad、Yunqi Li、Shinsuke Ishihara 等 11 位作者2014-05-04Chemistry Letters

We prepared nanoporous carbon (NC) particles of approximately 50-nm diameter by direct carbonization of metal–organic frameworks (MOFs). The obtained MOF-derived NC (MOF-NC) particles exhibit very high biocompatibility and, hence, are promising as intracellular drug delivery carriers.

Graphene research and applicationsMetal-Organic Frameworks: Synthesis and ApplicationsGraphene and Nanomaterials Applications

Supporting Technology for Chain of Custody of Nuclear Weapons and Materials Throughout the Dismantlement and Disposition Processes

Kyle J. Bunch、Mark Jones、Pradeep Ramuhalli 等 5 位作者2014-05-04Science and Global Security

Verification technologies based upon electromagnetics and acoustics could potentially play an important role in fulfilling the challenging requirements of future verification regimes. For example, researchers at the Pacific Northwest National Laboratory (PNNL) have demonstrated that low frequency EM signatures of seal…

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studies

X-ray diffraction study of the YbMII3Fe5O12 (MII = Mg, Ca, Sr) ferrites

Е. С. Мустафин、М. М. Матаев、Р. З. Касенов 等 6 位作者2014-05-04Inorganic Materials

Three compounds with the general formula YbM 3 II Fe5O12 (MII = Mg, Ca, Sr) have been prepared for the first time by high-temperature solid-state reactions between ytterbium(III) oxide, iron(III) oxide, and alkaline-earth carbonates. Their crystal class and unit-cell parameters have been determined by X-ray diffractio…

Glass properties and applicationsMagnetic Properties and Synthesis of FerritesX-ray Diffraction in Crystallography

Kinetics of terbium oxide film growth from Tb(dpm)3 vapor

В. В. Баковец、S. V. Belaya、M. N. Lobzareva 等 4 位作者2014-05-04Inorganic Materials

We have studied the kinetics of terbium oxide chemical vapor deposition using the Tb(dpm) 3 complex. At substrate temperatures in the range 465–560°C, films ranging in thickness from 25 to 360 nm have been obtained. At precursor partial pressures below 13 Pa in an argon atmosphere, the films had smooth surfaces with s…

Semiconductor materials and devicesLanthanide and Transition Metal ComplexesAtomic and Subatomic Physics Research

Werner Complexes Viewed Anew: Utilizing Cobalt Coordination Chemistry for ‘Traceless’ Stimuli-Responsive Bioconjugation Involving Therapeutic Nanoparticles, Protein PEGylation, and Drug-(Bio)polymer Conjugates

Duong Thanh Nguyen、Ronaldo J. Cavazos、Alesha N. Harris 等 4 位作者2014-05-04Comments on Inorganic Chemistry

Alfred Werner received the Nobel Prize in 1913 for his pioneering work in developing coordination theory for metal complexes. A crucial experiment leading to the widespread acceptance of Werner's theory involved the resolution of a set of chiral cobalt complexes, specifically cis-[Co(en)2(NH3)X]X2 (X˭Cl, Br). The kine…

Nanoparticle-Based Drug DeliveryChemical Synthesis and AnalysisRadiopharmaceutical Chemistry and Applications

Preparation of II–VI and IV–VI semiconductor films for solar cells by the isovalent substitution technique with a CBD-made substrate

I.R. Chávez-Urbiola、J. A. Bernal Martínez、V. P. Makhniy 等 5 位作者2014-05-04Inorganic Materials

II–VI and IV–VI semiconductor films for solar cell applications, namely, CdTe, CdS, CdSe, PbS, PbSe and PbTe, can be prepared in a two-stage deposition process. In this work we illustrate the two-stage process to obtain PbTe and CdSe films from precursor oxide or hydroxide films deposited by chemical bath deposition (…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications