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Continuous Pitch Stabilization of Cholesteric Liquid Crystals and Display Applications

Chang‐Jae Yu、Soo In Jo、You Jin Lee 等 4 位作者2014-05-03Molecular Crystals and Liquid Crystals

We report a mechanism of the continuous pitch variation of the cholestric liquid crystal (CLC) with reactive mesogen based on the phase separation model and the 4 × 4 matrix analysis. From the density variation of the polymerized RM with chirality, the corresponding pitch variation was directly estimated and the refle…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Liquid Crystals Nanocomposites for Photovoltaic Applications: Structural Properties

L. J. Martı́nez-Miranda、Jefferson W. Taylor、Lynn K. Kurihara2014-05-03Molecular Crystals and Liquid Crystals

Nanocomposites consisting of liquid crystals and nanoparticles have been studied for their applications in devices, such as photovoltaics and to model biological devices. Understanding the structure the liquid crystal assumes in the vicinity of the nanoparticles, and how it compares to the bulk structure of the liquid…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPlant Reproductive Biology

Microwave‐assistant route to hybrid semiconductor nanocrystals with quasi solution‐solid‐solid mechanism

Chunlin Bao、Guoxing Zhu、Mengqi Shen 等 5 位作者2014-05-03Crystal Research and Technology

A facile microwave‐assistant route was developed for the synthesis of hybrid nanocrystals. Colloidal hybrid nanocrystals, Ag2S‐CdS, were prepared by using Ag2S nanocrystals and cadmium diethyldithiocarbamate as raw materials under microwave irradiation. The fast ion conductor, Ag2S nanocrystal, catalyzes the growth of…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Structure and photoluminescence properties of SrWO4 3D microspheres synthesized by the surfactant‐assisted hydrothermal method

Guangru Tian、Ning Sheng、Xiaomei Qiu2014-05-03Crystal Research and Technology

In this paper, we report large‐scale high‐quality SrWO4 3D microspheres synthesized in aqueous solutions under mild conditions with cetyl trimethyl ammonium bromide as a simple cationic surfactant. These crystals have been characterized by X‐ray diffraction, transmission electron microscopy and field emission scanning…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Mechanochromic Photoluminescent Liquid Crystals Containing 5,5′-Bis(2-phenylethynyl)-2,2′-bithiophene

Masato Mitani、Shogo Yamane、Masafumi Yoshio 等 5 位作者2014-05-03Molecular Crystals and Liquid Crystals

5,5′-Bis(2-phenylethynyl)-2,2′-bithiophene derivative 1 containing dendritic moieties linked through amide groups was synthesized. Compound 1 exhibits a rectangular columnar phase on slow cooling from the isotropic liquid. In contrast, a cubic phase is formed as a metastable liquid-crystalline phase by rapid cooling o…

Liquid Crystal Research AdvancementsLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

The Transcriptional Response of Lactobacillus sanfranciscensis DSM 20451 T and Its tcyB Mutant Lacking a Functional Cystine Transporter to Diamide Stress

Mandy Stetina、Jürgen Behr、Rudi F. Vogel2014-05-03Applied and Environmental Microbiology

As a result of its strong adaptation to wheat and rye sourdoughs, Lactobacillus sanfranciscensis has the smallest genome within the genus Lactobacillus. The concomitant absence of some important antioxidative enzymes and the inability to synthesize glutathione suggest a role of cystine transport in maintenance of an i…

Probiotics and Fermented FoodsEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Engineering Aqueous Fiber Assembly into Silk‐Elastin‐Like Protein Polymers

Like Zeng、Linan Jiang、Weibing Teng 等 6 位作者2014-05-03Macromolecular Rapid Communications

Self-assembled peptide/protein nanofibers are valuable 1D building blocks for creating complex structures with designed properties and functions. It is reported that the self-assembly of silk-elastin-like protein polymers into nanofibers or globular aggregates in aqueous solutions can be modulated by tuning the temper…

Connective tissue disorders researchSupramolecular Self-Assembly in MaterialsSilk-based biomaterials and applications

Gold nanoparticles grown inside carbon nanotubes: synthesis and electrical transport measurements

Rodrigo Segura、Claudia Contreras、Ricardo Henríquez 等 8 位作者2014-05-03Nanoscale Research Letters

The hybrid structures composed of gold nanoparticles and carbon nanotubes were prepared using porous alumina membranes as templates. Carbon nanotubes were synthesized inside the pores of these templates by the non-catalytic decomposition of acetylene. The inner cavity of the supported tubes was used as nanoreactors to…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

A Solid-State Nuclear Magnetic Resonance Study of Post-Plasma Reactions in Organosilicone Microwave Plasma-Enhanced Chemical Vapor Deposition (PECVD) Coatings

Colin Hall、Thirunavukkarasu Ponnusamy、Peter Murphy 等 6 位作者2014-05-03ACS Applied Materials & Interfaces

Plasma-polymerized organosilicone coatings can be used to impart abrasion resistance and barrier properties to plastic substrates such as polycarbonate. Coating rates suitable for industrial-scale deposition, up to 100 nm/s, can be achieved through the use of microwave plasma-enhanced chemical vapor deposition (PECVD)…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Study of the reaction between boron trifluoride methanol complex and sodium methoxide

Wuke Lang、Zhang Weijiang、Xu Jiao 等 4 位作者2014-05-03Journal of Coordination Chemistry

The reaction between boron trifluoride methanol complex and sodium methoxide in methanol solution was investigated using conductivity as the reaction indicator. The reaction conditions were examined and a mechanism of this reaction was proposed. Moreover, proper reaction conditions were proposed for boric acid prepara…

Ionic liquids properties and applicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Exotic Defect Structures and Their Optical Properties in a Strongly Confined Chiral Liquid Crystal

Jun‐ichi Fukuda、S. Žumer2014-05-03Molecular Crystals and Liquid Crystals

We numerically investigate structural and optical properties of a highly chiral liquid crystal when it is confined in a thin planar cell imposing strong homeotropic anchoring. Various stable exotic defect structures different from those of bulk cholesteric blue phases are found depending on temperature and cell thickn…

Liquid Crystal Research AdvancementsOptical Polarization and EllipsometryMolecular spectroscopy and chirality

Three 2-(4-thiazolyl)benzimidazole-based supramolecular assemblies oriented by Keggin and Wells–Dawson anions

Aixiang Tian、Yang Yang、Na Sun 等 7 位作者2014-05-03Journal of Coordination Chemistry

Three polyoxometalate supramolecular assemblies based on rigid 2-(4-thiazolyl)benzimidazole (L) and two types of polytungstate anions, [CuII2Cl(L)4(PW12O40)]·3H2O (1), [CuII(L)2(H2O)]2[P2W18O62]·(HL)2·6H2O (2), and [ZnII(L)3]4[H(KPW12O40)3] (3), have been synthesized and characterized by single-crystal X-ray diffracti…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Nonlinear Optics of Nematic and Blue Phase Liquid Crystals

Iam Choon Khoo、Chun-Wei Chen、Kuan Lung Hong 等 5 位作者2014-05-03Molecular Crystals and Liquid Crystals

We present a critical reexamination of individual electronic and collective optical nonlinearities of nematic liquid crystals (NLC) in the context of all-optical transmission switching of femtoseconds – CW lasers, and report recent observations of similar optical nonlinearities in Blue-phase liquid crystals (BPLC) and…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsNonlinear Optical Materials Studies

Physical properties and biocompatibility of UHMWPE-derived materials modified by synchrotron radiation

I. N. Bykova、Venera Weinhardt、A. Kashkarova 等 8 位作者2014-05-03Journal of Materials Science Materials in Medicine

The applications of synchrotron radiation (SR) in medical imaging have become of great use, particularly in angiography, bronchography, mammography, computed tomography, and X-ray microscopy. Thanks to recently developed phase contrast imaging techniques non-destructive preclinical testing of low absorbing materials s…

Orthopaedic implants and arthroplastyElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposite Synthesis and Irradiation

Human airway smooth muscle maintain in situ cell orientation and phenotype when cultured on aligned electrospun scaffolds

G E Morris、Jack C. Bridge、Osama Eltboli 等 9 位作者2014-05-03American Journal of Physiology-Lung Cellular and Molecular Physiology

Human airway smooth muscle (HASM) contraction plays a central role in regulating airway resistance in both healthy and asthmatic bronchioles. In vitro studies that investigate the intricate mechanisms that regulate this contractile process are predominantly conducted on tissue culture plastic, a rigid, 2D geometry, un…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Identification and characterization of an acyl-CoA dehydrogenase from Pseudomonas putida KT2440 that shows preference towards medium to long chain length fatty acids

Maciej Guzik、Tanja Narančić、Tatjana Ilic‐Tomic 等 12 位作者2014-05-03Microbiology

Diverse and elaborate pathways for nutrient utilization, as well as mechanisms to combat unfavourable nutrient conditions make Pseudomonas putida KT2440 a versatile micro-organism able to occupy a range of ecological niches. The fatty acid degradation pathway of P. putida is complex and correlated with biopolymer medi…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicrobial Metabolic Engineering and Bioproduction

Zr‐doped CeO2 Hollow slightly‐truncated nano‐octahedrons: One‐pot synthesis, characterization and their application in catalysis of CO oxidation

Xiufang Liu、Wei Liu、Xueying Zhang 等 6 位作者2014-05-03Crystal Research and Technology

Zirconium‐doped ceria hollow slightly‐truncated nano‐octahedrons (HTNOs) (Ce1‐xZrxO2) were synthesized by a one‐pot, facile hydrothermal method. The morphology and crystalline structure were characterized with powder X‐ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) an…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Effect of 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide on liquid oxygen compatibility of bisphenol a epoxy resin

Zhanjun Wu、Jialiang Li、Yingpu Chen 等 5 位作者2014-05-03Journal of Applied Polymer Science

ABSTRACT In this study, bisphenol A epoxy resin (DGEBA) was chemically modified by 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO), and the molecular structure of the modified epoxy resin was characterized by Fourier transform infrared spectra. The effects of DOPO on liquid oxygen compatibility of DGEBA were…

Epoxy Resin Curing ProcessesFlame retardant materials and propertiesSynthesis and properties of polymers

A Novel Route to Surface‐Enhanced Raman Scattering: Ag Nanoparticles Embedded in the Nanogaps of a Ag Substrate

Zhi‐Ming Jin、Wei Gu、Xiaobo Shi 等 6 位作者2014-05-03Advanced Optical Materials

An intense surface‐enhanced Raman scattering (SERS) effect is realized by depositing Ag nanoparticles (NPs) into the nanogaps of a Ag substrate. The nanogaps are formed by the thermal annealing of a Ag film on a silicon substrate. This SERS substrate has an enhancement factor (EF) of 2.3 × 106 and a strong signal enha…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchQuantum Dots Synthesis And Properties

A Detailed Description of the Chemistry of Thiol Supporting Plasma Polymer Films

Damien Thiry、Rémy Francq、Damien Cossement 等 6 位作者2014-05-03Plasma Processes and Polymers

In this work, the plasma polymerization of propanethiol is investigated with the aim to control the thiol density [SH] in the coatings. The results reveal a nearly constant evolution of [SH] regarding the mean power dissipated in the discharge. This peculiar behavior is explained considering (i) mass spectrometry data…

Surface Modification and SuperhydrophobicityGas Sensing Nanomaterials and SensorsMolecular Junctions and Nanostructures