Materials Literature
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This chapter discusses polymeric materials that act as an oxidizer in composite energetic formulations that use aluminum as the fuel. It focuses on the synthesis and combustion characterization of these materials using various analysis methods. Fundamental combustion theories are explained to provide a more complete u…
This chapter contains sections titled: Introduction Fabrication of Cyclodextrin Poly(pseudo)Rotaxane-Based Hydrogels Stimulus-Response Properties of Cyclodextrin Poly(pseudo)Rotaxane Based Hydrogels Nanocomposite Supramolecular Hydrogels Biomedical Application of Cyclodextrin Poly(pseudo)Rotaxane-Based Hydrogels Concl…
Luminescent lanthanoid complexes fulfil many of the criteria for probes of sub-cellular structure and function, and offer superior photophysical properties to other optical probes, with their information-rich spectra and long luminescence lifetimes. This chapter summarises recent work towards an understanding of how l…
This chapter contains sections titled: Introduction Design and Preparation of Hemocompatible Polymeric Micro- and Nanoparticles The Biosafety and Hemocompatibility Evaluation System for Polymeric Micro- and Nanoparticles Construction of Biosensor for Direct Detection in Whole Blood Conclusion and Prospect
Chemical vapor deposition (CVD) polymerization methods result in a versatile platform for the fabrication of high quality fluoropolymer films. This chapter provides an insight into the mechanism of formation of these films, the ability to tailor their properties by tuning the experimental conditions and the chemistry…
Fluoropolymers can take on an amazing variety of characteristics depending on the details of their molecular structures. Modern methods of polymer synthesis have been adapted to provide tremendous flexibility in designing fluoropolymer structures so that materials can be prepared for a variety of applications. This ch…
Boronate-containing polymers (BCPs) have been widely studied and used for sugar sensing and sugar-responsive drug delivery, assays of pharmaceuticals, separation of glycoproteins and cells, encapsulation of animal cells and, recently, for gene transfection and detection of metastatic cell phenotypes. Spontaneous bindi…
This chapter discusses two closely relative areas, including the borane-mediated control radical polymerization to prepare some unique fluoropolymer structures and the resulting fluoropolymers for energy storage applications. The system of borane/oxygen control radical initiators is surprisingly effective for initiati…
This chapter contains sections titled: Introduction Anticancer Drug Entrapped Zeolite Structures as Drug Delivery Systems Mesoporous Silica Nanoparticles and Multifunctional Magnetic Nanoparticles in Biomedical Applications BioMOFs: Metal-Organic Frameworks for Biological and Medical Applications Conclusions
The presence of fluorine in the side group structure has led to some of the most intriguing developments, and this is the focus of this chapter. Using the two-step synthesis protocol, molecular diversity is accomplished in several different ways. One method for structural and property tuning involves the introduction…
This book is about the separation of enantiomers by synthetic methods, which is to say methods involving some chemical transformation as part of the separation process. We do not, in this book, cover chromatographic methods for the separation of enantiomers, nor do we focus on methods based on crystallizations as thes…
Thanks to its exceptional resolution and unlimited tissue penetration, magnetic resonance imaging (MRI) is one of the most efficient diagnostic modalities in clinical radiology and biomedical research today. Around 30–40% of clinical MR applications use paramagnetic, superparamagnetic or ferromagnetic substances as a…
Fluoropolymers are mostly manufactured from the free radical polymerization of fluorinated olefins. However, this chapter introduces a unique class of fluorinated alkenes-aryl trifluorovinyl ethers. Perfluorocyclobutane (PFCB) polymers are prepared through thermally activated [2+2] cycloaddition of aryl trifluorovinyl…
The field of Medicinal Inorganic Chemistry is making significant breakthroughs in our understanding of disease and how we approach treatment. Ligands that effectively bind metal ions and also include specific features to enhance targeting, reporting, and overall efficacy are driving innovation in areas of disease diag…
Polymers with perfluoroalkyl (Rf) groups have surface characteristics that differ greatly from those of comparable hydrogenated structures, for example, excellent chemical and thermal stability, nonadhesive properties, low friction coefficients, low surface free energies, and antifouling behavior. Fluoropolymers with…
This chapter discusses recent developments with the synthesis, functionalization, incorporation into polymer matrices, and applications of fluorinated silsesquioxanes. The synthesis of these structures follows the traditional methodology of producing polyhedral oligomeric silsesquioxanes (POSS) cages. The chapter desc…
Fluorosilicone is a rather imprecise term that could embrace a wide variety of polymer structures. In practice, it generally means poly[methyl(3,3,3-trifluoropropyl)siloxane] (PMTFPS), accounting for a predominant 96% share of the fluorosilicone market. The principal intent of this chapter is to compare and contrast t…
This chapter summarizes the synthesis methods for semifluorinated (sf) polymers, and discusses their phase separation behavior in bulk and thin films, derive the consequences of phase separation on the macroscopic wetting behavior, and propose applications for the interesting polymer class. It provides materials for l…
Natural and synthetic zeolites have emerged as potential materials for biomedical application in recent years. Zeolites are hydrated microporous tektoaluminosilicates consisting of three-dimensional frameworks of SiO4 and AlO4 tetrahedra linked through shared oxygen atoms. Clinoptilolite, a mineral from the heulandite…
Recent progress of ligand design in the field of medicinal inorganic chemistry includes sugar-based ligands and their metal complexes. Carbohydrate moieties are introduced to control cellular uptake, in vivo distribution and biological activities of the metal complexes. As a consequence, many carbohydrate-targeted lig…