Materials Literature
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On the Q-dots: Fluorescent polystyrene beads loaded with CdTe quantum dots exhibit excellent pH-independent fluorescence and antisolvent properties (see figure). The beads, which were prepared by miniemulsion polymerization using polymerizable surfactants as both an emulsifier and a phase-transfer agent, offer excelle…
Solidification of the liquid medium in ceramic suspensions containing less than a critical volume fraction powder leads to the formation of particle‐free dendrites of the frozen medium. These particle‐free dendrites create, after sublimation of the frozen vehicle, large dendrite pores. We define the conditions under w…
By now more than 100 years passed since Paul Drude suggested his highly acclaimed model of electronic transport. In the form advanced by A. Sommerfeld, the Drude model is still heavily utilized to describe, for instance, the optical properties of metals. Surprisingly, the key prediction of the Drude model, the frequen…
Etching polymer‐derived silicon‐oxycarbide ceramics with hydrofluoric acid creates nanoporous structures of specific surface areas as high as 600 m 2 /g. The change in composition upon etching shows the removal of silica, not carbon. The structure remaining after etching is postulated to consist of a scaffolding of gr…
Hydrozincite (Zn5(CO3)2(OH)6) microspheres with a tunable surface architecture have been successfully synthesized via a homogeneous precipitation method under solvothermal conditions. For a smooth hydrozincite microsphere, various building blocks such as nanocubes, nanorods, and nanosheets are arranged to cover a sphe…
Abstract The blends of low molecular weight triacetin (TAC) and oligomeric poly(1,3‐butylene glycol adipate) (PBGA) were used as multiple plasticizers to lubricate poly(lactic acid) (PLA) in this study. The thermal and mechanical properties of plasticized polymers were investigated by means of dynamic mechanical analy…
Side-chain-functionalized lactide analogues have been synthesized from commercially available amino acids and polymerized using stannous octoate as a catalyst. The synthetic strategy presented allows for the incorporation of any protected amino acid for the preparation of functionalized diastereomerically pure lactide…
This work reports on the synthesis of chromium (III, IV) oxides films by KrF laser-assisted CVD. Films were deposited onto sapphire substrates at room temperature by photodissociation of Cr(CO)6 in dynamic atmospheres containing oxygen and argon. A study of the processing parameters has shown that partial pressure rat…
We calculated the optical excitation and thermal ionization energies of oxygen vacancies in m-HfO$_2$ using atomic basis sets, a non-local density functional and periodic supercell. The thermal ionization energies of negatively charged V$^-$ and V$^{2-}$ centres are consistent with values obtained by the electrical me…
Chromium oxides, CrxOy, are of great interest due to the wide variety of their technological applications. Among them, CrO2 has been extensively investigated in recent years because it is an attractive compound to be used in spintronic heterostructures. However, its synthesis at low temperatures has been a difficult t…
We use fiber-coupled photoconductive emitters and detectors to perform terahertz (THz) spectroscopy of lightly-doped n-InSb directly in the cryogenic (1.5 K) bore of a high-field superconducting magnet. We measure transmission spectra from 0.1-1.1 THz as the sample is driven through a metal-insulator transition (MIT)…
We discuss the origin of the finite size error of the energy in many-body simulation of systems of charged particles and we propose a correction based on the random phase approximation at long wave lengths. The correction comes from contributions mainly determined by the organized collective oscillations of the intera…
We analyze the simplest problem of electrochemical relaxation in more than one dimension - the response of an uncharged, ideally polarizable metallic sphere (or cylinder) in a symmetric, binary electrolyte to a uniform electric field. In order to go beyond the circuit approximation for thin double layers, our analysis…
We review some experimental and theoretical aspects of coherent acoustic phonon generation in piezoelectric semiconductor multiple quantum wells. In order to model more advanced and complicated nano-acoustic devices, a macroscopic continuum theory for the generation and propagation of coherent acoustic phonons in piez…
Tiny black pearls: Monodisperse, smooth carbon spheres (100–1000 nm in diameter) are prepared via the synthesis and subsequent carbonization of micrometer-sized particles of melamine–formaldehyde resin (see SEM image). The gradual transition of the copolymer to carbon results in uniform shrinkage without deformation o…
Luminescence properties of quantum dots (QDs) are closely related to their surface structure and chemical properties. In this work some ensemble techniques and fluorescence correlation spectroscopy (FCS) were used to study the fluorescence quenching and dialysis process of CdTe QDs. It is found that when some heavy me…
A novel method for the controlled embedding of multiple nanoparticles of various materials, such as gold nanoparticles, quantum dots, and magnetic nanoparticles, in silica colloids is presented. After adsorption of the amphiphilic polymer poly(vinylpyrrolidone) on hydrophobic or hydrophilic stabilized nanoparticles, t…
Synthesis of the diarylethene-containing ligand L1 based on Suzuki cross-coupling reaction between thienyl boronic acid and the dibromophenanthroline ligand is reported. On coordination to the rhenium(I) tricarbonyl complex system, the photochromism of L1 could be photosensitized and consequently extended from intrali…
We have studied charge injection across the metal/organic semiconductor interface in bottom-contact poly(3-hexylthiophene) (P3HT) field-effect transistors, with Au source and drain electrodes modified by self-assembled monolayers (SAMs) prior to active polymer deposition. By using the SAM to engineer the effective Au…
We report for the first time real time in situ and quantitative measurements of the mutarotation reaction of lactose in the solid state. The experiments have been performed by 13C NMR. We show that mutarotation is initiated on heating the amorphous state, and reaches chemical equilibrium close above the glass transiti…