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Spider Silk and Amyloid Fibrils: A Structural Comparison

Ute Slotta、Simone Heß、Kristina Spieß 等 6 位作者2007-02-12Macromolecular Bioscience

Although spider silks have been studied for decades, the assembly properties of the underlying silk proteins have still not been unravelled. Previously, the detection of amyloid-like nanofibrils in the spider's silk gland suggested their involvement in the assembly process.Recombinantly produced spider silk also self-…

Silk-based biomaterials and applicationsProtease and Inhibitor MechanismsBiochemical and Structural Characterization

Anisotropy and Order of Epitaxial Self-Assembled Quantum Dots

Lawrence H. Friedman2007-02-12arXiv

Epitaxial self-assembled quantum dots (SAQDs) represent an important step in the advancement of semiconductor fabrication at the nanoscale that will allow breakthroughs in electronics and optoelectronics. In these applications, order is a key factor. Here, the role of crystal anisotropy in promoting order during early…

Materials Science

Stripes in thin ferromagnetic films with out-of-plane anisotropy

D. Clarke、O. A. Tretiakov、O. Tchernyshyov2007-02-12arXiv

We examine the T=0 phase diagram of a thin ferromagnetic film with a strong out-of-plane anisotropy in the vicinity of the reorientation phase transition (with Co on Pt as an example). The phase diagram in the anisotropy-applied field plane is universal in the limit where the film thickness is the shortest length scal…

Materials Science

Room-temperature ballistic transport in narrow graphene strips

Daniel Gunlycke、Hadley M. Lawler、C. T. White2007-02-12Physical Review B

We investigate electron-phonon couplings, scattering rates, and mean free paths in zigzag-edge graphene strips with widths of the order of $10\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$. Our calculations for these graphene nanostrips show both the expected similarity with single-wall carbon nanotubes (SWNTs) and the suppr…

Diamond and Carbon-based Materials ResearchCarbon Nanotubes in CompositesGraphene research and applications

Potential of Various Archae‐ and Eubacterial Strains as Industrial Polyhydroxyalkanoate Producers from Whey

Martin Koller、Paula Johanna Hesse、Rodolfo Bona 等 6 位作者2007-02-12Macromolecular Bioscience

Three different microbial wild-type strains are compared with respect to their potential as industrial scale polyhydroxyalkanoate (PHA) producers from the feed stock whey lactose. The halophilic archaeon Haloferax mediterranei as well as two eubacterial strains (Pseudomonas hydrogenovora and Hydrogenophaga pseudoflava…

Enzyme Catalysis and ImmobilizationCarbon dioxide utilization in catalysisbiodegradable polymer synthesis and properties

Principles of superplasticity in ultrafine-grained materials

Megumi Kawasaki、Terence G. Langdon2007-02-12Journal of Materials Science

Ultrafine-grained materials are attractive for achieving superplastic elongations provided the grains are reasonably stable at elevated temperatures. Since the strain rate in superplasticity varies inversely with the grain size raised to a power of two, a reduction in grain size to the submicrometer level leads to the…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesAdvanced materials and composites

Ultrasonic technique for extracting nanofibers from nature materials

Hongping Zhao、Xi‐Qiao Feng、Huajian Gao2007-02-12Applied Physics Letters

This letter reports a simple and versatile approach for extracting bionanofibers from natural materials using the ultrasonic technique. Bionanofibers have been fabricated from various materials, e.g., spider and silkworm silks, chitin fibers, collagen, cotton, bamboo, and ramee and hemp fibers. The obtained nanofibers…

Electrospun Nanofibers in Biomedical ApplicationsSupramolecular Self-Assembly in MaterialsSilk-based biomaterials and applications

Piezoelectric Gated Diode of a Single ZnO Nanowire

Jr‐Hau He、Cheng‐Lun Hsin、Jane Liu 等 5 位作者2007-02-12OpenAlex

A ZnO nanowire behaves like a rectifier under bending strain, as demonstrated by its current–voltage characteristics (see graph). This is interpreted with the consideration of a piezoelectricity-induced potential energy barrier at the interface of the conductive tip and nanowire (see schematic). Under appropriate bend…

Advanced Sensor and Energy Harvesting MaterialsGas Sensing Nanomaterials and SensorsZnO doping and properties

Quantum dot-induced cell death involves Fas upregulation and lipid peroxidation in human neuroblastoma cells

Angela O. Choi、Sung Ju Cho、Julie Desbarats 等 5 位作者2007-02-12OpenAlex

BACKGROUND: Neuroblastoma, a frequently occurring solid tumour in children, remains a therapeutic challenge as existing imaging tools are inadequate for proper and accurate diagnosis, resulting in treatment failures. Nanoparticles have recently been introduced to the field of cancer research and promise remarkable imp…

Quantum Dots Synthesis And PropertiesCarbon and Quantum Dots ApplicationsSilicon Nanostructures and Photoluminescence

Influence of strain on the magnetization and magnetoelectric effect inLa0.7A0.3MnO3∕PMN−PT(001)(A=Sr,Ca)

C. Thiele、K. Dörr、O. Bilani 等 5 位作者2007-02-12arXiv

We investigate the influence of a well-defined reversible biaxial strain $\ensuremath{\leqslant}0.12%$ on the magnetization $(M)$ of epitaxial ferromagnetic manganite films. $M$ has been recorded depending on temperature, strain and magnetic field in $20--50\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$ thick films. This is…

Multiferroics and related materialsAdvanced Condensed Matter PhysicsMagnetic and transport properties of perovskites and related materials

Leakage mechanisms in BiFeO3 thin films

Gary Pabst、Lane W. Martin、Ying‐Hao Chu 等 4 位作者2007-02-12OpenAlex

The authors report results of transport studies on high quality, fully epitaxial BiFeO3 thin films grown via pulsed laser deposition on SrRuO3∕DyScO3 (110) substrates. Ferroelectric tests were conducted using symmetric and asymmetric device structures with either SrRuO3 or Pt top electrodes and SrRuO3 bottom electrode…

Multiferroics and related materialsMagnetic and transport properties of perovskites and related materialsFerroelectric and Piezoelectric Materials

Benefits of Micaceous Iron Oxide, Aluminum Flake and Glass Flake Filled High Performance Coatings

M. Connor、Dan Baribault2007-02-11OpenAlex

Abstract For several decades, engineered coatings have been used to protect steel from corrosion. Many formulas were made and tested for their ability to prevent corrosion. Changes in the formulas would include different resins, pigments, solvents and additives. In this paper, we will talk about three specific pigment…

Tribology and Wear AnalysisAdvanced materials and compositesMetal Alloys Wear and Properties

Exchange interaction between single magnetic adatoms

P. Wahl、P. Simon、L. Diekhoener 等 7 位作者2007-02-11arXiv

The magnetic coupling between single Co atoms adsorbed on a copper surface is determined by probing the Kondo resonance using low-temperature scanning tunneling spectroscopy. The Kondo resonance, which is due to magnetic correlation effects between the spin of a magnetic adatom and the conduction electrons of the subs…

Strongly Correlated ElectronsMaterials Science

A Facile Route to Mesoporous Carbon Catalyst Support Modified with Magnetic Nanoparticles

Ye Tian、Guodong Li、Qian Gao 等 6 位作者2007-02-10Chemistry Letters

Abstract Magnetically separable ordered mesoporous carbon with Fe3O4 nanoparticles, which were grafted on the outer surface of the mesoporous carbon material CMK-3, was prepared through a facile route. The catalytic performance for hydrogenation of cyclohexene to cyclohexane validates the mesoporous nanocomposite mate…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Facile Activation of Hydrogen by an Unsaturated Platinum−Osmium Cluster Complex

Richard D. Adams、Burjor Captain、Lei Zhu2007-02-10Journal of the American Chemical Society

The electronically unsaturated platinum−osmium complex Pt 2 Os 3 (CO) 10 (P t Bu 3 ) 2, 3, has been obtained from the reaction of Os 3 (CO) 10 (NCMe) 2 with Pt(P t Bu 3 ) 2 . Compound 3 adds hydrogen at 0 °C to yield the dihydrido complex Pt 2 Os 3 (CO) 10 (P t Bu 3 ) 2 (μ-H) 2, 4 (93% yield) within 10 min and subsequ…

Hydrogen Storage and MaterialsAsymmetric Hydrogenation and CatalysisOrganometallic Complex Synthesis and Catalysis

Proton Migration in –N···H···O– Hydrogen-bonded Complex of (Chloranilic Acid)(1,2-Diazine)2 Studied by Dielectric Response and Infrared Absorption Spectra

Hideaki Suzuki、Hatsumi Mori、Jun-ichi Yamaura 等 6 位作者2007-02-10Chemistry Letters

Abstract A dielectric response by an intermolecular –N···H···O–proton transfer was observed around 120 K for (Chloranilic acid)(1,2-Diazine)2 [CA(1,2-DA)2]. This response, observed on the way of the migration from N–H···O at 300 K to O–H···N below 90 K, was demonstrated by infrared absorption spectra and the temperatu…

Solid-state spectroscopy and crystallographyNonlinear Optical Materials ResearchElectron Spin Resonance Studies

Glassy Dynamics, Aging in Mobility, and Structural Relaxation of Strongly Adsorbed Polymer Films: Corrugation or Confinement?

Debashish Mukherji、Martin H. Müser2007-02-10Macromolecules

A molecular dynamics simulation (MD) of a generic model for polymers adsorbed on a discrete surface is presented. We investigate the effect of surface roughness on the film's diffusion constant, its influence on aging, and other properties. The model reproduces many experimentally observed features such as logarithmic…

Theoretical and Computational PhysicsMaterial Dynamics and PropertiesPhase Equilibria and Thermodynamics

Photophysics of Reduced Silicon Tetraphenylporphyrin

Hee-eun Song、J.A. Cissell、Thomas P. Vaid 等 4 位作者2007-02-10The Journal of Physical Chemistry B

The contrasting photophysical properties of two silicon (IV) tetraphenylporphyrins, Si(TPP)(py)2 and Si(TPP)Cl2, have been investigated using static absorption and fluorescence spectroscopy and ultrafast transient absorption measurements. The parent Si(TPP)Cl2, in which the porphyrin macrocycle has its normal 2- oxida…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsPhotochemistry and Electron Transfer Studies

Photoactive Barbiturate Receptors: An Ultimate Lock-and-Key System in Which the Key Unlocks the Lock

Suman Lakkakula、Oleg D. Mitkin、R.A. Valiulin 等 4 位作者2007-02-10Organic Letters

Conditional photofragmentation is achieved with binary systems incorporating the isophthaloyl bis-aminopyridine barbiturate recognition motif and dithiane- or trithiane-based photolabile modules, which cleave only in the presence of an external sensitizer. The components of the host-guest molecular recognition pair we…

Photochromic and Fluorescence ChemistryMolecular Sensors and Ion DetectionChemical Synthesis and Analysis