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A selective hydrogen peroxide sensor based on chemiresistive polyaniline nanowires modified with silver catalytic nanoparticles

Edward Song、Jin‐Woo Choi2014-04-25Journal of Micromechanics and Microengineering

This paper presents a novel method to selectively detect hydrogen peroxide using a chemiresistive polyaniline nanowire network. The polyaniline nanowires modified with silver catalytic nanoparticles were demonstrated to give selective responses to hydrogen peroxide by changing the conductivity of the polyaniline. The…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Light-Induced Color Changes of Microgel-Based Etalons

Yongfeng Gao、Michael J. Serpe2014-04-25ACS Applied Materials & Interfaces

Poly(N-isopropylacrylamide) (pNIPAm) microgel-based etalons were used to fabricate systems that change visual color in response to light exposure. These systems were fabricated by adding pH responsive microgel-based etalons to a solution composed of the photoacid o-nitrobenzaldehyde (o-NBA). Upon exposure of this syst…

Photonic Crystals and ApplicationsPhotochromic and Fluorescence ChemistryElectrowetting and Microfluidic Technologies

One for Two: Conversion of Waste Chicken Feathers to Carbon Microspheres and (NH4)HCO3

Lei Gao、Haibo Hu、Xuelin Sui 等 5 位作者2014-04-25Environmental Science & Technology

Pyrolysis of 1 g of waste chicken feathers (quills and barbs) in supercritical carbon dioxide (sc-CO2) system at 600 °C for 3 h leads to the formation of 0.25 g well-shaped carbon microspheres with diameters of 1-5 μm and 0.26 g ammonium bicarbonate ((NH4)HCO3). The products were characterized by powder X-ray diffract…

Adsorption and biosorption for pollutant removalCalcium Carbonate Crystallization and InhibitionCatalysis and Hydrodesulfurization Studies

Liesegang Patterns Engineered by a Chemical Reaction Assisted by Complex Formation

Hideki Nabika、Mami Sato、Kei Unoura2014-04-25Langmuir

Liesegang rings based on a chemical reaction, not a conventional precipitation reaction, have been developed by appropriate design of the nucleation dynamics in a system involving complex formation in a matrix. The periodic and concentric rings consisted of well-dispersed Ag nanoparticles with diameters of a few nanom…

Nonlinear Dynamics and Pattern FormationPickering emulsions and particle stabilizationSlime Mold and Myxomycetes Research

Immuno-LipoTRAIL: Targeted Delivery of TRAIL-Functionalized Liposomal Nanoparticles

Oliver Seifert、Nadine Pollak、Anja Nusser 等 7 位作者2014-04-25Bioconjugate Chemistry

The TNF-related apoptosis-inducing ligand (TRAIL) is a powerful inducer of apoptosis in tumor cells; however, clinical studies with recombinant soluble TRAIL were rather disappointing. Here, we developed TRAIL-functionalized liposomes (LipoTRAIL, LT) to mimic membrane-displayed TRAIL for efficient activation of death…

Nanoparticle-Based Drug DeliveryCell death mechanisms and regulationRNA Interference and Gene Delivery

Investigation of defects in In–Ga–Zn oxide thin film using electron spin resonance signals

Yusuke Nonaka、Yoichi Kurosawa、Yoshihiro Komatsu 等 13 位作者2014-04-25Journal of Applied Physics

In–Ga–Zn oxide (IGZO) is a next-generation semiconductor material seen as an alternative to silicon. Despite the importance of the controllability of characteristics and the reliability of devices, defects in IGZO have not been fully understood. We investigated defects in IGZO thin films using electron spin resonance…

ZnO doping and propertiesThin-Film Transistor TechnologiesTransition Metal Oxide Nanomaterials

SYNTHESIS AND CHARECTERIZATION STUDIES OF NANO TIO2 PREPARED VIA SOL-GEL METHOD

Sankar Pariserum Perumal2014-04-25International Journal of Research in Engineering and Technology

Nanoparticles of titanium dioxide doped with Fe2+ ions have been synthesized via sol-gel technique using Titanium tetraisopropoxide (TTIP) and ferrous sulphate as a precursors. The synthesized nanopowders were characterized by Powder X-ray Diffraction (PXRD), Scanning Electron Microscope (SEM), Fourier Transform Infra…

TiO2 Photocatalysis and Solar CellsGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Failure analysis of Cu(In,Ga)Se2 photovoltaic modules: degradation mechanism of Cu(In,Ga)Se2 solar cells under harsh environmental conditions

Dong‐Won Lee、Won‐Ju Cho、Jun‐Kwang Song 等 9 位作者2014-04-25Progress in Photovoltaics Research and Applications

Abstract High‐temperature‐induced and humidity‐induced degradation behaviors were investigated through the failure analysis of encapsulated Cu(In,Ga)Se2 (CIGS) modules and non‐encapsulated CIGS cells. After being exposed to high temperature (85 °C) for 1000 h, the efficiency loss of CIGS modules and the resistivities…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Controlled overgrowth of Pd on Au nanorods

Hao Jing、Hui Wang2014-04-25CrystEngComm

In this paper, we present a detailed, systematic study of the controlled overgrowth of Pd on Au nanorods. Pd nanoshells with fine-controlled dimensions and architectures were overgrown on single-crystalline Au nanorods through seed-mediated growth using H2PdCl4 as the Pd precursor and ascorbic acid as the reducing age…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanomaterials and Printing Technologies

Antheraea pernyi Silk Fibroin-Coated PEI/DNA Complexes for Targeted Gene Delivery in HEK 293 and HCT 116 Cells

Yu Liu、Renchuan You、Guiyang Liu 等 7 位作者2014-04-25International Journal of Molecular Sciences

Polyethylenimine (PEI) has attracted much attention as a DNA condenser, but its toxicity and non-specific targeting limit its potential. To overcome these limitations, Antheraea pernyi silk fibroin (ASF), a natural protein rich in arginyl-glycyl-aspartic acid (RGD) peptides that contains negative surface charges in a…

Virus-based gene therapy researchRNA Interference and Gene DeliverySilk-based biomaterials and applications

A compatibly differenced total energy conserving form of SPH

J. Michael Owen2014-04-25International Journal for Numerical Methods in Fluids

SUMMARY We describe a modified form of smoothed particle hydrodynamics (SPH) in which the specific thermal energy equation is based on a compatibly differenced formalism, guaranteeing exact conservation of the total energy. We compare the errors and convergence rates of the standard and compatible SPH formalisms on a…

Computational Fluid Dynamics and AerodynamicsFluid Dynamics Simulations and InteractionsHigh-Velocity Impact and Material Behavior

IUPAC-NIST Solubility Data Series. 102. Solubility of Nonsteroidal Anti-inflammatory Drugs (NSAIDs) in Neat Organic Solvents and Organic Solvent Mixtures

William E. Acree2014-04-25Journal of Physical and Chemical Reference Data

Solubility data are compiled and reviewed for 33 nonsteroidal anti-inflammatory drugs dissolved in neat organic solvents and in well-defined binary and ternary organic solvents. The compiled solubility data were retrieved primarily from the chemical and pharmaceutical literature covering the period from 1980 to the be…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesPharmacological Effects of Natural Compounds

Accuracy in quantitative phase analysis of mixtures with large amorphous contents. The case of stoneware ceramics and bricks

Alessandro F. Gualtieri、Vincenzo Riva、A. Bresciani 等 6 位作者2014-04-25Journal of Applied Crystallography

For the first time, this work inspects the accuracy of quantitative phase analysis of both crystalline and amorphous components of stoneware tiles and bricks. A number of variables were considered: the nature of the internal standard, experimental conditions and counting statistics. The so-calledG-factor method has al…

Glass properties and applicationsCultural Heritage Materials AnalysisRecycling and utilization of industrial and municipal waste in materials production

Alginate‐coated magnetic nanoparticles for noninvasive MRI of extracellular calcium

Amnon Bar‐Shir、Liat Avram、Shani Yariv‐Shoushan 等 10 位作者2014-04-25NMR in Biomedicine

Nanoparticles (NPs) have great potential to increase the diagnostic capacity of many imaging modalities. MRI is currently regarded as the method of choice for the imaging of deep tissues, and metal ions, such as calcium ions (Ca(2+)), are essential ingredients for life. Despite the tremendous importance of Ca(2+) for…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

In Vivo Assessment of Aqueous Humor Dynamics Upon Chronic Ocular Hypertension and Hypotensive Drug Treatment Using Gadolinium-Enhanced MRI

Leon C. Ho、Ian P. Conner、Chi Wai 等 8 位作者2014-04-25Investigative Ophthalmology & Visual Science

PURPOSE: Although glaucoma treatments alter aqueous humor (AH) dynamics to lower intraocular pressure, the regulatory mechanisms of AH circulation and their contributions to the pathogenesis of ocular hypertension and glaucoma remain unclear. We hypothesized that gadolinium-enhanced magnetic resonance imaging (Gd-MRI)…

Glaucoma and retinal disordersLanthanide and Transition Metal ComplexesCerebral Venous Sinus Thrombosis

Uptake and Distribution of Stable Strontium in 26 Cultivars of Three Crop Species: Oats, Wheat, and Barley for Their Potential Use in Phytoremediation

Lin Qi、Xiaoliang Qin、Feng‐Min Li 等 7 位作者2014-04-25International Journal of Phytoremediation

The main objective of this study was to investigate the accumulation and distribution of strontium (Sr) in 26 cultivars of wheat (Triticum aestivum L.), husk oat (Avena sativa L) and naked oat (Avena nuda), and barley (Hordeum vulgare L.) for their potential use in phytoremediation.Sr levels had no effect on the accum…

Groundwater and Isotope GeochemistryRadioactive contamination and transferClay minerals and soil interactions

Correlating Fischer–Tropsch activity to Ru nanoparticle surface structure as probed by high-energy X-ray diffraction

Xian‐Yang Quek、Ivo A. W. Filot、Robert Pestman 等 6 位作者2014-04-25Chemical Communications

Synchrotron X-ray diffraction coupled to atomic pair distribution function analysis and Reverse Monte Carlo simulations is used to determine the atomic-scale structure of Ru nanoparticle catalysts for the Fischer-Tropsch reaction. The rate of CO hydrogenation strongly correlates with the abundance of surface atoms wit…

Catalytic Processes in Materials ScienceCatalysts for Methane Reformingnanoparticles nucleation surface interactions

Four Syntheses of 4‐Amino‐3,5‐dinitropyrazole

Stefan Ek、Nikolaj V. Latypov2014-04-25Journal of Heterocyclic Chemistry

In this paper, syntheses of 4‐amino‐3,5‐dinitropyrazole from four different starting materials are described. The starting materials were 4‐nitropyrazole, 4‐nitro‐3,5‐dimethylpyrazole, 3,5‐dinitropyrazole, and 4‐chloropyrazole, respectively. They are compared in terms of yield, number of steps and suitability for scal…

Energetic Materials and CombustionThermal and Kinetic AnalysisChemical Reactions and Mechanisms

CoPc and CoPcF16 on gold: Site-specific charge-transfer processes

F. Petraki、Heiko Peisert、Johannes Uihlein 等 5 位作者2014-04-25Beilstein Journal of Nanotechnology

Interface properties of cobalt(II) phthalocyanine (CoPc) and cobalt(II) hexadecafluoro-phthalocyanine (CoPcF16) to gold are investigated by photo-excited electron spectroscopies (X-ray photoemission spectroscopy (XPS), ultraviolet photoemission spectroscopy (UPS) and X-ray excited Auger electron spectroscopy (XAES)).…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Spontaneous vesicle phase formation by pseudogemini surfactants in aqueous solutions

Nan Sun、Lijuan Shi、Fei Lü 等 5 位作者2014-04-25Soft Matter

The phase behavior of a kind of pseudogemini surfactant in aqueous solutions, formed by the mixture of sodium dodecyl benzene sulfonate (SDBS) and butane-1,4-bis (methylimidazolium bromide) ([mim-C4-mim]Br2) or butane-1,4-bis(methylpyrrolidinium bromide) ([mpy-C4-mpy]Br2) in a molar ratio of 2 : 1, is reported in the…

Supramolecular Chemistry and ComplexesSurfactants and Colloidal SystemsSupramolecular Self-Assembly in Materials