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Synthesis of Cd1-xZnxS/K4Nb6O17Composite and its Photocatalytic Activity for Hydrogen Production

Yinghua Liang、Meiyi Shao、Li Liu 等 5 位作者2014-04-20Bulletin of the Korean Chemical Society

$Cd_{1-x}Zn_xS$ -sensitized $K_4Nb_6O_{17}$ composite photocatalysts (designated $Cd_{1-x}Zn_xS/K_4Nb_6O_{17}$ ) were prepared via a simple deposition-precipitation method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy disp…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Triterpenoid Saponins from Stauntonia chinensis

Yu Chen、Fang Yang、Sha Wang 等 6 位作者2014-04-20Bulletin of the Korean Chemical Society

E-mail: yanggz888@126.comReceived July 15, 2013, Accepted December 9, 2013Key Words : Triterpenoid saponins, Lardizabalaceae, Stauntonia chinensisStauntonia chinensis DC. (Lardizabalaceae), an evergreenherb growing in southern China, commonly known as “YeMu Gua”, has been used as a traditional Chinese medicine,especia…

Natural product bioactivities and synthesisPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

Scaffold structure and fabrication method affect proinflammatory milieu in three‐dimensional‐cultured chondrocytes

Heenam Kwon、Roshni S. Rainbow、Lin Sun 等 8 位作者2014-04-20Journal of Biomedical Materials Research Part A

Cartilage tissue engineering has emerged as an attractive therapeutic option for repairing damaged cartilage tissue in the arthritic joint. High levels of proinflammatory cytokines present at arthritic joints can cause cartilage destruction and instability of the engineered cartilage tissue, and thus it is critical to…

Osteoarthritis Treatment and MechanismsKnee injuries and reconstruction techniquesSilk-based biomaterials and applications

Synthesis and Optical Characteristics of PAM/HgS Nanocomposites

Dezhi Qin、Guangrui Yang、Li Zhang 等 5 位作者2014-04-20Bulletin of the Korean Chemical Society

Polyacrylamide (PAM) -HgS nanocomposites were successfully prepared in polyacrylamide (PAM) matrix. From TEM and XRD characterizations, the synthesized HgS nanocrystals were chain-like spherical in shape with a diameter of about 40-60 nm and high crystalline quality. The quantum-confined effect of HgS nanocrystals was…

Quantum Dots Synthesis And PropertiesCrystal Structures and PropertiesLaser-Ablation Synthesis of Nanoparticles

EFFECT OF Nb ON TRANSFORMATION AND MICROSTRUCTURE REFINEMENT IN MEDIUM CARBON STEEL

Si Wu、LI Xiucheng、Juan Zhang 等 4 位作者2014-04-20Acta Metallurgica Sinica

Medium carbon steel is widely used in structural steels because of its favorable strength,but lack of toughness is a limitation in industrial applications.Among the different strengthening mechanism,grain refinement is the only method to improve both strength and toughness simultaneously.The toughness of steels can be…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsMetal Alloys Wear and Properties

Branched DNA-based Synthesis of Fluorescent Silver Nanocluster

Juwon Park、Jaejung Song、Joonhyuck Park 等 5 位作者2014-04-20Bulletin of the Korean Chemical Society

While single strand DNAs have been widely used for the scaffold of brightly fluorescent silver nanoclusters (Ag NCs), double strand DNAs have not been as successful. Herein, we report a novel synthetic approach for bright Ag NCs using branched double strand DNAs as the scaffolds for synthesis. X-shaped DNA (X-DNA) and…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

ZnO Nanorods Based Dye Sensitized Solar Cells Sensitized using Natural Dyes Extracted from Beetroot, Rose and Strawberry

T.S. Senthil、N. Muthukumarasamy、Misook Kang2014-04-20Bulletin of the Korean Chemical Society

Dye sensitized solar cells were fabricated using natural dyes extracted from beetroot, rose and strawberry. The ZnO nanorod working electrode has been prepared by simple hydrothermal method. The crystallinity and morphology of the prepared electrode has been studied using X-ray diffraction and scanning electron micros…

TiO2 Photocatalysis and Solar CellsConducting polymers and applicationsAnalytical Chemistry and Sensors

A Novel Donor-Acceptor-Acceptor-Acceptor Polymer Containing Benzodithiophene and Benzimidazole-Benzothiadiazole-Benzimidazole for PSCs

Vellaiappillai Tamilavan、Myungkwan Song、Rajalingam Agneeswari 等 5 位作者2014-04-20Bulletin of the Korean Chemical Society

New electron deficient acceptor-acceptor-acceptor type of monomer unit composed of weak electron accepting benzimidazole and relatively strong electron accepting benzothiadiazole derivatives namely 4,7-bis(6-bromo-1-(2-ethylhexyl)-1H-benzo[d]imidazol-2-yl)benzo[c][1,2,5]thiadiazole (BBB) was synthesized. The Stille po…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

Highly Sensitive and Naked Eye Dual-readout Method for ʟ-Cysteine Detection Based on the NSET of Fluorophore Functionalized Gold Nanoparticles

Xin Fu、Yuan Liu、Zhitao Wu 等 4 位作者2014-04-20Bulletin of the Korean Chemical Society

A simple, highly sensitive and selective method based on the rhodamine B-covered gold nanoparticle with dual-readout (colorimetric and fluorometric) detection for $\small{L}$ -cysteine is proposed. A mechanism is that citrate-stabilized AuNPs were modified with RB by electrostatic interaction, which enables the nanome…

Advanced biosensing and bioanalysis techniquesNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Fully Unstructured Mesh based Computation of Viscous Flow around Marine Propellers

Min-Geon Kim、Hyung Taek Ahn、Jin-Tae Lee 等 4 位作者2014-04-20Journal of the Society of Naval Architects of Korea

A CFD(Computational Fluid Dynamics) analysis is presented to predict hydrodynamic characteristics of a marine propeller. A commercial RANS(Reynolds Averaged Navier-Stokes equation) solver, namely FLUENT, is utilized in conjunction with fully unstructured meshes around rotating propeller. Mesh generation process is gre…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics Simulations and Interactions

Improved Energy Conversion Efficiency of Dye-sensitized Solar Cells Fabricated using Open-ended TiO2Nanotube Arrays with Scattering Layer

Won‐Yeop Rho、Myeoung-Hwan Chun、Ho-Sub Kim 等 6 位作者2014-04-20Bulletin of the Korean Chemical Society

We prepared dye-sensitized solar cells (DSSCs) with enhanced energy conversion efficiency using open-ended $TiO_2$ nanotube arrays with a $TiO_2$ scattering layer. As compared to closed-ended $TiO_2$ nanotube arrays, the energy conversion efficiency of the open-ended $TiO_2$ nanotube arrays was increased from 5.63% to…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Role of HCl in Atomic Layer Deposition of TiO2Thin Films from Titanium Tetrachloride and Water

Jina Leem、Inhye Park、Yinshi Li 等 7 位作者2014-04-20Bulletin of the Korean Chemical Society

Atomic layer deposition (ALD) of $TiO_2$ thin film from $TiCl_4$ and $H_2O$ has been intensively studied since the invention of ALD method to grow thin films via chemical adsorptions of two precursors. However the role of HCl which is a gaseous byproduct in ALD chemistry for $TiO_2$ growth is still intriguing in terms…

Semiconductor materials and devicesAdvanced Memory and Neural ComputingElectronic and Structural Properties of Oxides

PAMAM Dendrimer Conjugated with N-terminal Oligopeptides of Mouse Fibroblast Growth Factor 3 as a Novel Gene Carrier

Jin‐Woo Jung、Jeil Lee、Tae-Hun Kim 等 8 位作者2014-04-20Bulletin of the Korean Chemical Society

In this study, we introduced the RRLR oligopeptide sequences on the surface of polyamidoamine (PAMAM) dendrimer and characterized the physical properties and gene carrier activity of the novel polymer using HEK 293, NIH3T3, and HeLa cells. The RRLR peptide sequences were derived from a mouse fibroblast growth factor 3…

Advanced biosensing and bioanalysis techniquesRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Design of Amphiphilic Zwitterions Forming Liquid-Crystalline Phases and Effects of Lithium Salt Addition on Their Phase Behavior

Takuro Matsumoto、Takahiro Ichikawa、Junji Sakuda 等 5 位作者2014-04-20Bulletin of the Chemical Society of Japan

Abstract We prepared pyridinium-based amphiphilic zwitterions and examined their liquid-crystalline (LC) phase behavior in the presence and absence of lithium salts. Addition of lithium salts induced nanosegregated LC phases such as bicontinuous cubic phase and smectic phase depending on the anion species of the lithi…

Liquid Crystal Research AdvancementsIonic liquids properties and applicationsPolyoxometalates: Synthesis and Applications

Viscoelastic properties of collagen–adhesive composites under water‐saturated and dry conditions

Viraj Singh、Anil Misra、R. Parthasarathy 等 5 位作者2014-04-20Journal of Biomedical Materials Research Part A

To investigate the time- and rate-dependent mechanical properties of collagen-adhesive composites, creep and monotonic experiments are performed under dry and wet conditions. The composites are prepared by infiltration of dentin adhesive into a demineralized bovine dentin. Experimental results show that for small stre…

Bone Tissue Engineering MaterialsDental materials and restorationsCollagen: Extraction and Characterization

Lung cancer risk due to residential radon exposures: estimation and prevention

L A Truta、W. Hofmann、C. Cosma2014-04-20Radiation Protection Dosimetry

Epidemiological studies proved that cumulative exposure to radon is the second leading cause of lung cancer, the world's most common cancer. The objectives of the present study are (i) to analyse lung cancer risk for chronic, low radon exposures based on the transformation frequency-tissue response (TF-TR) model formu…

Radiation Dose and ImagingRadioactivity and Radon MeasurementsGraphite, nuclear technology, radiation studies

Kernel Density Estimation Applied to Bond Length, Bond Angle, and Torsion Angle Distributions

Patrick McCabe、Oliver Korb、Jason C. Cole2014-04-20Journal of Chemical Information and Modeling

We describe the method of kernel density estimation (KDE) and apply it to molecular structure data. KDE is a quite general nonparametric statistical method suitable even for multimodal data. The method generates smooth probability density function (PDF) representations and finds application in diverse fields such as s…

Computational Drug Discovery MethodsAnalytical Chemistry and ChromatographyMachine Learning in Materials Science

Antimicrobial and Genotoxicity Effects of Zero-valent Iron Nanoparticles

Elham Barzan、Sedigheh Mehrabian、Saeed Irian2014-04-20Jundishapur Journal of Microbiology

BACKGROUND: In a world of nanotechnology, the first concern is the potential environmental impact of nanoparticles. An efficient way to estimate nanotoxicity is to monitor the responses of bacteria exposed to these particles. OBJECTIVES: The current study explored the antimicrobial properties of nZVI (zero-valent Iron…

Nanoparticles: synthesis and applicationsEnvironmental remediation with nanomaterialsGraphene and Nanomaterials Applications

Confocal SERS Mapping of Glycan Expression for the Identification of Cancerous Cells

Derek Craig、Sarah McAughtrie、Jonathan Simpson 等 6 位作者2014-04-20Analytical Chemistry

Lectin-functionalized silver nanoparticles have been successfully designed for use as molecular imaging agents to investigate carbohydrate-lectin interactions at the surface of mammalian cells, using surface-enhanced Raman scattering (SERS). Carbohydrate-lectin interactions are key to many cellular processes and are r…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchProtein Interaction Studies and Fluorescence Analysis

A novel synthetic route for magnesium aluminate (MgAl2O4) nanoparticles using sol–gel auto combustion method and their photocatalytic properties

Mostafa Y. Nassar、Ibrahim S. Ahmed、Ihab Samir2014-04-20Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy

In this paper a novel and inexpensive route for the preparation of spinel magnesium aluminate nanoparticles (MgAl2O4) is proposed. Magnesium aluminate photocatalyst was synthesized via sol-gel auto combustion method using oxalic acid, urea, and citric acid fuels at 350°C. Subsequently, the burnt samples were calcined…

Advanced Photocatalysis TechniquesMicrowave Dielectric Ceramics SynthesisMagnesium Oxide Properties and Applications