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Structural and biophysical characterization of Staphylococcus aureus SaMazF shows conservation of functional dynamics

Valentina Zorzini、L. Buts、Mike Sleutel 等 10 位作者2014-04-19Nucleic Acids Research

The Staphylococcus aureus genome contains three toxin-antitoxin modules, including one mazEF module, SamazEF. Using an on-column separation protocol we are able to obtain large amounts of wild-type SaMazF toxin. The protein is well-folded and highly resistant against thermal unfolding but aggregates at elevated temper…

Bacterial Genetics and BiotechnologyAntimicrobial Resistance in StaphylococcusEnzyme Structure and Function

Rigid-Object Water-Entry Impact Dynamics: Finite-Element/Smoothed Particle Hydrodynamics Modeling and Experimental Validation

Ravi Challa、Solomon C. Yim、V. G. Idichandy 等 4 位作者2014-04-19Journal of Offshore Mechanics and Arctic Engineering

A numerical study on the dynamic response of a generic rigid water-landing object (WLO) during water impact is presented in this paper. The effect of this impact is often prominent in the design phase of the re-entry project to determine the maximum force for material strength determination to ensure structural and eq…

Fluid Dynamics and Heat TransferFluid Dynamics Simulations and InteractionsHigh-Velocity Impact and Material Behavior

Towards an integrative structural biology approach: combining Cryo-TEM, X-ray crystallography, and NMR

Jeffrey Lengyel、Eric Hnath、Marc Storms 等 4 位作者2014-04-19Journal of Structural and Functional Genomics

Cryo-transmission electron microscopy (Cryo-TEM) and particularly single particle analysis is rapidly becoming the premier method for determining the three-dimensional structure of protein complexes, and viruses. In the last several years there have been dramatic technological improvements in Cryo-TEM, such as advance…

RNA and protein synthesis mechanismsAdvanced Electron Microscopy Techniques and ApplicationsEnzyme Structure and Function

AN OVERVIEW OF RECENT NANOFLUID RESEARCH

K. Sreelakshmy、Aswathy S Nair、KM Vidhya 等 5 位作者2014-04-19International Research Journal of Pharmacy

Nanofluids consist of nanoparticles suspended in a liquid medium and the particle size is smaller than 100 nm.Nanofluids have great thermo-physical properties such as thermal conductivity, thermal diffusivity, viscosity and heat transfer coefficient as compared to their base fluids.The key feature of nanofluid is its…

Carbon Nanotubes in CompositesNanofluid Flow and Heat TransferNanopore and Nanochannel Transport Studies

Wet-Chemical Enzymatic Preparation and Characterization of Ultrathin Gold-Decorated Single Glass Nanopore

Haili He、Xiaolong Xu、Yongdong Jin2014-04-19Analytical Chemistry

The conical glass nanopore was modified through layer-by-layer electrostatic deposition of a monolayer of glucose oxidase, and then an ultrathin gold film was formed in situ through enzyme-catalyzed reactions. The morphology and components of single glass nanopore before and after ultrathin Au deposition were characte…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesIon-surface interactions and analysis

Insights into Nanoscale Electrochemical Reduction in a Memristive Oxide: the Role of Three‐Phase Boundaries

Christian Lenser、M. Patt、Stephan Menzel 等 8 位作者2014-04-19Advanced Functional Materials

The nanoscale electro‐reduction in a memristive oxide is a highly relevant field for future non‐volatile memory materials. Photoemission electron microscopy is used to identify the conducting filaments and correlate them to structural features of the top electrode that indicate a critical role of the three phase bound…

Advanced Memory and Neural ComputingNeural dynamics and brain functionTransition Metal Oxide Nanomaterials

N ‐Annulated Perylene as a Coplanar π‐Linker Alternative to Benzene as a Low Energy‐Gap, Metal‐Free Dye in Sensitized Solar Cells

Zhaoyang Yao、Cancan Yan、Min Zhang 等 6 位作者2014-04-19Advanced Energy Materials

Perylenes are well‐known pigments with excellent chemical, thermal, and photochemical stabilities and have been used in various optical and electronic fields. Although for sensitized mesoscopic solar cells there is rapid progress of metal‐free thiophene dyes, which now reach over 11.5% power conversion efficiency (PCE…

TiO2 Photocatalysis and Solar CellsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Silicon Decorated Cone Shaped Carbon Nanotube Clusters for Lithium Ion Battery Anodes

Wei Wang、Isaac Ruiz、Kazi Ahmed 等 9 位作者2014-04-19Small

In this work, we report the synthesis of an three-dimensional (3D) cone-shape CNT clusters (CCC) via chemical vapor deposition (CVD) with subsequent inductively coupled plasma (ICP) treatment. An innovative silicon decorated cone-shape CNT clusters (SCCC) is prepared by simply depositing amorphous silicon onto CCC via…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Assessing punching shear failure in reinforced concrete flat slabs subjected to localised impact loading

K. Micallef、Juan Sagaseta、Miguel Fernández Ruiz 等 4 位作者2014-04-19International Journal of Impact Engineering

Reinforced concrete flat slab structures are used widely in construction projects due to their economic and functional advantages. Punching shear failure in such structures can have catastrophic effects in the case of, for example, multi-storey framed structures and the designer aims to ensure that ductile flexural de…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsFire effects on concrete materials

Effective Solution‐ and Vacuum‐Processed n‐Doping by Dimers of Benzimidazoline Radicals

Benjamin D. Naab、Siyuan Zhang、Koen Vandewal 等 7 位作者2014-04-19Advanced Materials

Benzimidazoline radical dimers that can be handled in air but that function as powerful reductants are reported and evaluated as n-dopants by solution- and vacuum processing. In several host materials, one of these dimers is found to have a more-consistent doping effect than a hydride-donor dopant analog. Notably, a r…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Nonlinear Constitutive Model for Anisotropic Biobased Composite Materials

A.T. Michel、Sarah L. Billington2014-04-19Journal of Engineering Mechanics

Biobased composites have been widely proposed in the literature as suitable replacements for a variety of engineered materials, with applications ranging from biomedical devices to automotive components to construction materials. Previous research has primarily focused on engineering biobased alternatives with mechani…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesInnovations in Concrete and Construction Materials

Enhancing the PLA crystallization rate by incorporating a polystyrene‐block‐poly(methyl methacrylate) block copolymer: Synergy of polystyrene and poly(methyl methacrylate) segments

Chien‐Pang Wu、Cheng‐Chien Wang、Chuh‐Yung Chen2014-04-19Journal of Polymer Science Part B Polymer Physics

ABSTRACT A polystyrene‐block‐poly(methyl methacrylate) (PS‐b‐PMMA) exhibiting a well‐defined structure was prepared combining anionic polymerization and mercaptan/ε‐caprolactam living polymerization. To evaluate how this block copolymer affected the crystallization of polylactide (PLA), 0.5 wt % thiol‐terminated PS ho…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Halogeno‐modified polystyrene: monomer reactivity ratios, thermal behaviour and flammability

Małgorzata Wiącek、Dorota Wesołek、Szymon Rojewski 等 5 位作者2014-04-19Polymer International

Abstract Chemical modification based on incorporation of flame retardants into polymer backbones was used in order to reduce flammability of polystyrene (PSt). The halogeno‐substituted styrenes: 4‐chlorostyrene (ClSt), 4‐bromostyrene (BrSt) and 2,3,4,5,6‐pentafluorostyrene (5FSt) were applied as reactive flame retarda…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesThermal and Kinetic Analysis

Influence of microwave heating time on the structure and properties of chitosan films

Charlotte Jacquot、Muriel Jacquot、Patrícia Marques de Farias 等 7 位作者2014-04-19Journal of Applied Polymer Science

ABSTRACT The aim of this study was to investigate chitosan film behavior during microwave heating for 10 different heating times from 0 to 40 min. Chitosan films were produced by casting. Their structure and properties were investigated with several techniques, including Fourier transform infrared spectroscopy and dif…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Transient adsorption studies of automotive hydrocarbon traps

Jing Luo、Robert W. McCabe、Mark A. Dearth 等 4 位作者2014-04-19AIChE Journal

A chromatographic adsorption unit was designed and built to study the adsorption of alkanes in zeolites for the hydrocarbon trap systems in three‐way catalysts, to assist in the selection of optimal materials for this application. The experimental apparatus used a zeolite bed in place of the column in an ordinary gas…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

Cup‐Stacked Carbon Nanotube Schottky Diodes for Photovoltaics and Photodetectors

Ki‐Hwan Kim、David Brunel、A. Gohier 等 6 位作者2014-04-19Advanced Materials

High-performance optoelectronic devices based on cup-stacked carbon nanotubes are realized. Based on a Schottky barrier model, rectifying behaviors and high photo­response are observed by using growth catalysts as nanoscale electronic contacts. Similar performances are also obtained and furthermore tuned by using the…

Carbon Nanotubes in CompositesNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

Effect of organoclay reinforcement on the curing characteristics and technological properties of styrene–butadiene rubber

E. M. Sadek、D. E. El‐Nashar、Sahar M. Ahmed2014-04-19Polymer Composites

Rubber nanocomposites based on styrene–butadiene rubber (SBR) and organophilic layered silicate were prepared. Clay structures based on dodecyl benzene sulfonic acid (DBSA), nonyl phenol ethoxylate (NPE), and DBSA/NPE (50/50%) were prepared and characterized. The results indicate the intercalation of the used surfacta…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Analysis of Spalling in Roughing Mill Backup Rolls of Wide and Thin Strip Hot Rolling Process

Qiang Dong、Jianguo Cao、Hongbo Li 等 6 位作者2014-04-19steel research international

In this paper, the spalling causes of backup rolls in a roughing mill of a hot strip rolling mill were investigated. The roughing mill withstood extreme service conditions with long service cycles for backup and work rolls, a large variety of the same width rolling campaigns, severe and non‐uniform wear contours of ba…

Metallurgy and Material FormingMechanical stress and fatigue analysisMetal Alloys Wear and Properties

Mechanical, morphology, and thermal properties of carbon fiber reinforced poly(butylene succinate) composites

Jicai Liang、Ding Chen、Zhiyong Wei 等 9 位作者2014-04-19Polymer Composites

Biodegradable poly(butylene succinate) (PBS)/carbon fiber (CF) composites were prepared by melt blending method using twin‐screw extruder followed by injection molding. Mechanical properties, crystallization behavior, morphology, crystal structure, and thermal stability of PBS/CF composites were investigated with diff…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Generation of gold nanoparticles according to procedures described in the eighteenth century

Álvaro Mayoral、Javier Agúndez、Ignacio Miguel Pascual-Valderrama 等 4 位作者2014-04-19Gold bulletin

Gold nanoparticles have received much attention in recent years due to their unique size-dependent properties, as they find useful applications in materials science [Mayoral et al. (Nanoscale 2:335–342, 2010 )], catalysis [Schwerdtfeger (Angew Chem Int Ed 42:1892–1895, 2003 )] [Hashmi and Hutchings (Angew Chem Int Ed…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and Applications