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A reentrant phenomenon in magnetic and dielectric properties of Dy2BaNiO5 and an intriguing influence of external magnetic field

Tathamay Basu、P. L. Paulose、Kartik K. Iyer 等 8 位作者2014-04-11Journal of Physics Condensed Matter

We report that the spin-chain compound Dy2BaNiO5, recently proven by us to exhibit magnetoelectric coupling below its Néel temperature (TN) of 58 K, exhibits strong frequency-dependent behavior in ac magnetic susceptibility and complex dielectric properties at low temperatures (<10 K), mimicking the 'reentrant' multig…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Boron Substitution in Aluminum Cluster Anions: Magic Clusters and Reactivity with Oxygen

Jordan C. Smith、Arthur C. Reber、Shiv N. Khanna 等 4 位作者2014-04-11The Journal of Physical Chemistry A

We have studied the size-selective reactivity of AlnBm(-) clusters m = 1,2 with O2 to investigate the effect of congener substitution in energetic aluminum clusters. Mixed-metal clusters offer an additional strategy for tuning the electronic and geometric structure of clusters and by substituting an atom with a congen…

Energetic Materials and CombustionBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Pulsed feeding strategy is more favorable to medium‐chain‐length polyhydroxyalkanoates production from waste rapeseed oil

Justyna Możejko‐Ciesielska、Sławomir Ciesielski2014-04-11Biotechnology Progress

This article presents the results of production and characterization of medium-chain-length polyhydroxyalkanoates (mcl-PHAs) using Pseudomonas sp. Gl01. Studies have been carried out to find suitable feeding strategies for mcl-PHAs production and, for the first time, to investigate in-depth the properties of biopolyes…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCarbon dioxide utilization in catalysis

Hydroxypropyl methylcellulose as a polymeric corrosion inhibitor for aluminium

Innocent O. Arukalam、I. C. Madufor、O. Ogbobe 等 4 位作者2014-04-11Pigment & Resin Technology

Purpose – The paper aims to investigate the effectiveness of hydroxypropyl methylcellulose (HPMC) as corrosion inhibitor for aluminium in 0.5 M H2SO4solution. Design/methodology/approach – This study was carried out using weight loss and electrochemical techniques. Inhibition efficiency was determined by comparing the…

Concrete and Cement Materials ResearchCorrosion Behavior and InhibitionConcrete Corrosion and Durability

Inhibition of acid corrosion of mild steel by aqueous nettle extracts

Aida Zaabar、R. Aitout、L. Makhloufi 等 5 位作者2014-04-11Pigment & Resin Technology

Purpose – The aim of this research was to investigate the use of aqueous extracts of nettle plant (NE) as a green corrosion inhibitor of mild steel in hydrochloric acid solution. Design/methodology/approach – The inhibition efficiency was investigated by weight loss measurements, potentiodynamic polarizations, electro…

Corrosion Behavior and InhibitionMarine Biology and Environmental Chemistry

Crystal Growth and Design of Sapphire: Experimental and Calculation Studies of Anisotropic Crystal Growth upon Pulling Directions

Congting Sun、Dongfeng Xue2014-04-11Crystal Growth & Design

The anisotropic growth of large-size sapphire single crystals along different pulling directions was studied on the basis of the chemical bonding theory of single crystal growth and practical Czochralski growth. The projection of thermodynamic morphology of sapphire single crystal respectively along [210], [110], [001…

Liquid Crystal Research AdvancementsSolidification and crystal growth phenomenaCrystallization and Solubility Studies

Preparation of Nanocomposite Plasmonic Films Made from Cellulose Nanocrystals or Mesoporous Silica Decorated with Unidirectionally Aligned Gold Nanorods

Michael G. Campbell、Qingkun Liu、Aric W. Sanders 等 5 位作者2014-04-11Materials

Using liquid crystalline self-assembly of cellulose nanocrystals, we achieve long-range alignment of anisotropic metal nanoparticles in colloidal nanocrystal dispersions that are then used to deposit thin structured films with ordering features highly dependent on the deposition method. These hybrid films are comprise…

Advanced Cellulose Research Studies

Multichannel mixed‐conducting hollow fiber membranes for oxygen separation

Jiawei Zhu、Ziye Dong、Zhengkun Liu 等 6 位作者2014-04-11AIChE Journal

Significance A multichannel mixed‐conducting hollow fiber (MMCHF) membrane, 0.5 wt % Nb 2 O 5 ‐doped SrCo 0.8 Fe 0.2 O 3‐δ (SCFNb), has been successfully prepared by phase inversion and sintering technique. The crystalline structure, morphology, sintering behavior, breaking load, and oxygen permeability of the MMCHF m…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsMembrane-based Ion Separation Techniques

Rheological and mechanical properties of polypropylene/calcium carbonate nanocomposites prepared from masterbatch

Achmad Chafidz、Mujtahid Kaavessina、Saeed M. Al‐Zahrani 等 4 位作者2014-04-11Journal of Thermoplastic Composite Materials

Polypropylene (PP)/calcium carbonate (CaCO 3 ) nanocomposites were prepared from masterbatch by melt blending in a twin-screw extruder. The effect of three different nano-CaCO 3 loadings (5, 10, and 15 wt%) on the rheological/viscoelastic and mechanical properties of the nanocomposites was investigated. A scanning ele…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Plasticity of hexagonal systems: Split slip modes and inverse Peierls relation in α -Ti

P. Kwaśniak、Piotr Śpiewak、Halina Garbacz 等 4 位作者2014-04-11Physical Review B

The plasticity of hexagonal titanium is reexamined based on the split slip modes phenomenon, revealing the existence of subslip modes in prismatic and pyramidal hcp slip systems. The energetics of dislocation emission and motions were described using all-dimension relaxed atomic models of crystal slip, calculated with…

Microstructure and mechanical propertiesIntermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and Properties

Tuning Al 2 O 3 Surface with SnO 2 to Prepare Improved Supports for Pd for CO Oxidation

Xiang Wang、Jin Tian、Yu Zheng 等 6 位作者2014-04-11ChemCatChem

Abstract SnO 2 /Al 2 O 3 supports with different SnO 2 loadings were prepared by using a deposition–precipitation method and characterized by using N 2 and CO adsorption–desorption, XRD, H 2 temperature‐programmed reduction, and X‐ray photoelectron spectroscopy techniques. SnO 2 dispersed finely on the Al 2 O 3 surfac…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Experimental evidence of Cr magnetic moments at low temperature in Cr2A(A=Al, Ge)C

M. Jaouen、Matthieu Bugnet、Nicolas Jaouen 等 7 位作者2014-04-11Journal of Physics Condensed Matter

From x-ray magnetic circular dichroism experiments performed at low temperature on Cr2AlC and Cr2GeC thin films, it is evidenced that Cr atoms carry a net magnetic moment in these ternary phases. It is shown that the Cr magnetization of the Al-based compound nearly vanished at 100 K in agreement with what has been rec…

2D Materials and ApplicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Excited-state absorption in various bismuth-doped fibers

Konstantin Riumkin、Mikhail Melkumov、Igor Varfolomeev 等 10 位作者2014-04-11Optics Letters

Excited-state absorption (ESA) in various bismuth-doped fibers (BDFs) was investigated. No significant ESA in IR emission bands of Bi-doped germanosilicate and phosphosilicate fibers was found. Considerable ESA was observed in Bi-doped aluminosilicate fibers at 800-1700 nm. The ESA spectra of the aluminosilicate BDFs…

Advanced Fiber Optic SensorsGlass properties and applicationsPhotonic Crystal and Fiber Optics

Some New Concepts of Shape Memory Effect of Polymers

Abbas Tcharkhtchi、Sofiane Abdallah-Elhirtsi、Kambiz Ebrahimi 等 6 位作者2014-04-11Polymers

In this study some new concepts regarding certain aspects related to shape memory polymers are presented. A blend of polylactic acid (PLA) (80%) and polybutylene succinate (PBS) (20%) was prepared first by extrusion, then by injection molding to obtain the samples. Tensile, stress-relaxation and recovery tests were pe…

Polymer composites and self-healingMarine Sponges and Natural ProductsPhotochromic and Fluorescence Chemistry

Supramolecular Liquid-Crystal Gels Formed by Polyfluorene-Based π-Conjugated Polymer for Switchable Anisotropic Scattering Device

Junwei Chen、Chiu-Chang Huang、Chih-Yu Chao2014-04-11ACS Applied Materials & Interfaces

To overcome the problem of high driving voltage and low contrast ratio in the switchable scattering device of conventional liquid-crystal (LC) physical gel, a new type of supramolecular LC physical gel has been developed and fabricated through the fibrous self-assembly of the polyfluorene-based π-conjugated polymer, p…

Liquid Crystal Research AdvancementsSupramolecular Self-Assembly in MaterialsAdvanced Materials and Mechanics

Highly purified mussel adhesive protein to secure biosafety for in vivo applications

Bong‐Hyuk Choi、Hogyun Cheong、Yun Kee Jo 等 6 位作者2014-04-11Microbial Cell Factories

BACKGROUND: Unique adhesive and biocompatibility properties of mussel adhesive proteins (MAPs) are known for their great potential in many tissue engineering and biomedical applications. Previously, it was successfully demonstrated that redesigned hybrid type MAP, fp-151, mass-produced in Gram-negative bacterium Esche…

Polymer Surface Interaction StudiesAntimicrobial agents and applicationsSurgical Sutures and Adhesives

Influence of Layer-by-Layer Polyelectrolyte Deposition and EDC/NHS Activated Heparin Immobilization onto Silk Fibroin Fabric

M. Fazley Elahi、Guoping Guan、Lu Wang 等 4 位作者2014-04-11Materials

To enhance the hemocompatibility of silk fibroin fabric as biomedical material, polyelectrolytes architectures have been assembled through the layer-by-layer (LbL) technique on silk fibroin fabric (SFF). In particular, 1.5 and 2.5 bilayer of oppositely charged polyelectrolytes were assembled onto SFF using poly(allyla…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Avidity Mechanism of Dendrimer–Folic Acid Conjugates

Mallory A. van Dongen、Justin E. Silpe、Casey A. Dougherty 等 8 位作者2014-04-11Molecular Pharmaceutics

Multivalent conjugation of folic acid has been employed to target cells overexpressing folate receptors. Such polymer conjugates have been previously demonstrated to have high avidity to folate binding protein. However, the lack of a monovalent folic acid-polymer material has prevented a full binding analysis of these…

RNA Interference and Gene DeliveryClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

A novel technique for the production of electrospun scaffolds with tailored three-dimensional micro-patterns employing additive manufacturing

Catherine Rogers、G E Morris、Toby Gould 等 10 位作者2014-04-11Biofabrication

Electrospinning is a common technique used to fabricate fibrous scaffolds for tissue engineering applications. There is now growing interest in assessing the ability of collector plate design to influence the patterning of the fibres during the electrospinning process. In this study, we investigate a novel method to g…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applicationsTissue Engineering and Regenerative Medicine

Pore Structure and Bifunctional Catalyst Activity of Overlayers Applied by Atomic Layer Deposition on Copper Nanoparticles

Ana C. Alba‐Rubio、Brandon J. O’Neill、Fengyuan Shi 等 11 位作者2014-04-11ACS Catalysis

We present a model system, based on spherical nonporous supports, to facilitate the characterization of supported metal catalysts stabilized by atomic layer deposition (ALD) against sintering and leaching under liquid-phase conditions. Calcination at high temperatures (973 K) produces pores in the ALD overcoat, and we…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides