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Morphological Control for Highly Efficient Inverted Polymer Solar Cells Via the Backbone Design of Cathode Interlayer Materials

Wenjun Zhang、Yulei Wu、Qinye Bao 等 5 位作者2014-04-09Advanced Energy Materials

Two alcohol-soluble organic molecules are synthesized and introduced into inverted organic solar cells as the cathode interlayer. A power conversion efficiency as high as 9.22% is obtained by using the more hydrophobic molecule FTBTF-N as the cathode interlayer. Morphological studies suggest that design of the backbon…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Strategy for Nano‐Catalysis in a Fixed‐Bed System

Jiating He、Weijie Ji、Yao Lin 等 7 位作者2014-04-09Advanced Materials

For industry applications of nano-catalysts, the main bottlenecks are the low loading per unit support area and the slow flow rate through the support particles. By growing a dense Au nanowire forest on a loose network of glass fibers, continuous-flow catalysis can be achieved with a processing rate about 100 times th…

Catalytic Processes in Materials ScienceAdvanced Data Storage TechnologiesNanomaterials for catalytic reactions

Accidental degeneracy of double Dirac cones in a phononic crystal

Ze‐Guo Chen、Xu Ni、Ying Wu 等 8 位作者2014-04-09Scientific Reports

Artificial honeycomb lattices with Dirac cone dispersion provide a macroscopic platform to study the massless Dirac quasiparticles and their novel geometric phases. In this paper, a quadruple-degenerate state is achieved at the center of the Brillouin zone in a two-dimensional honeycomb lattice phononic crystal, which…

Metamaterials and Metasurfaces ApplicationsTopological Materials and PhenomenaAcoustic Wave Phenomena Research

Large area fabrication of vertical silicon nanowire arrays by silver-assisted single-step chemical etching and their formation kinetics

Sanjay K. Srivastava、Dinesh Kumar、Sebastian W. Schmitt 等 6 位作者2014-04-09Nanotechnology

Vertically aligned silicon nanowire (SiNW) arrays have been fabricated over a large area using a silver-assisted single-step electroless wet chemical etching (EWCE) method, which involves the etching of silicon wafers in aqueous hydrofluoric acid (HF) and silver nitrate (AgNO3) solution. A comprehensive systematic inv…

Advancements in Semiconductor Devices and Circuit DesignSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

A Three Dimensional Multi‐Layered Sliding Triboelectric Nanogenerator

Weiming Du、Xun Han、Long Lin 等 7 位作者2014-04-09Advanced Energy Materials

A novel design of a 3D triboelectric nanogenerator (TENG) is demonstrated. Because of its largely increased friction areas, the device has a multi-layered structure, high transferred-charge-quantity, and current output. It delivers an open-circuit voltage of 800 V, a short-circuit current density of 5.5 mA m-2 with a…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Core–Shell In2O3/ZnO Nanoarray Nanogenerator as a Self-Powered Active Gas Sensor with High H2S Sensitivity and Selectivity at Room Temperature

Weili Zang、Yuxin Nie、Dan Zhu 等 6 位作者2014-04-09The Journal of Physical Chemistry C

Self-powered active gas sensing has been realized from core–shell In 2 O 3 /ZnO nanoarray nanogenerator, and extremely high H 2 S sensitivity and selectivity at room temperature have been obtained. In 2 O 3 /ZnO nanoarrays have two functions: one is an energy source because In 2 O 3 /ZnO nanoarrays can produce piezoel…

ZnO doping and propertiesAdvanced Sensor and Energy Harvesting MaterialsGas Sensing Nanomaterials and Sensors

Selective Allylic Oxidation of Cyclohexene Catalyzed by Nitrogen-Doped Carbon Nanotubes

Yonghai Cao、Hao Yu、Feng Peng 等 4 位作者2014-04-09ACS Catalysis

Carbon nanotubes (CNTs) and nitrogen-doped CNTs (NCNTs) were systematically investigated as metal-free catalysts in the selective allylic oxidation of cyclohexene using molecular oxygen as oxidant in the liquid phase. High cyclohexene conversion (up to 59.0%) and 620.1 mmol g –1 h –1 mass-normalized activity were obta…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Dissolution Behaviors and Applications of Silicon Oxides and Nitrides in Transient Electronics

Seung‐Kyun Kang、Suk‐Won Hwang、Huanyu Cheng 等 8 位作者2014-04-09Advanced Functional Materials

Silicon oxides and nitrides are key materials for dielectrics and encapsulation layers in a class of silicon‐based high performance electronics that has ability to completely dissolve in a controlled fashion with programmable rates, when submerged in bio‐fluids and/or relevant solutions. This type of technology, refer…

ZnO doping and propertiesSemiconductor materials and devicesAnalytical Chemistry and Sensors

Symmetry-protected mode coupling near normal incidence for narrow-band transmission filtering in a dielectric grating

Justin M. Foley、S. Young、Jamie Phillips2014-04-09Physical Review B

A narrow-band transmission filter is demonstrated near normal incidence that operates through relaxation of supported-mode selection rules and is explained in the context of group theory. We calculated the transverse magnetic and transverse electric dispersion relations of a dielectric grating in the subwavelength and…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Bicontinuous Nanoporous N‐doped Graphene for the Oxygen Reduction Reaction

Yoshikazu Ito、Hua‐Jun Qiu、Takeshi Fujita 等 6 位作者2014-04-09Advanced Materials

Bicontinuous nanoporous N-doped graphene with tunable pore size is synthesized by nanoporous Ni-based chemical vapor deposition. The novel 3D graphene material shows an outstanding catalytic activity towards the oxygen reduction reaction with a low onset potential of -0.08 V and a high kinetic current density of 8.2 m…

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Toward more realistic drug-target interaction predictions

Tapio Pahikkala、Antti Airola、Samuli Pietilä 等 7 位作者2014-04-09Briefings in Bioinformatics

A number of supervised machine learning models have recently been introduced for the prediction of drug-target interactions based on chemical structure and genomic sequence information. Although these models could offer improved means for many network pharmacology applications, such as repositioning of drugs for new t…

Computational Drug Discovery MethodsBioinformatics and Genomic NetworksMachine Learning in Materials Science

Electrochemical Tuning of MoS2 Nanoparticles on Three-Dimensional Substrate for Efficient Hydrogen Evolution

Haotian Wang、Zhiyi Lu、Desheng Kong 等 6 位作者2014-04-09ACS Nano

Molybdenum disulfide (MoS2) with the two-dimensional layered structure has been widely studied as an advanced catalyst for hydrogen evolution reaction (HER). Intercalating guest species into the van der Waals gaps of MoS2 has been demonstrated as an effective approach to tune the electronic structure and consequently…

Electrocatalysts for Energy Conversion2D Materials and ApplicationsMXene and MAX Phase Materials

Metal Oxide Nanomaterials

Kajal Kumar Dey2014-04-09Pan Stanford Publishing eBooks

This is a timely collection of recent diverse work on metal oxide nanomaterials, connecting their fundamental aspects and application perspectives in a concise fashion to give a broad view of the current status of this fascinating field. This book presents eight original research articles and two comprehensive reviews…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Studies of Adiponitrile as an Electrochemical Solvent

Graham T. Cheek2014-04-09ECS Transactions

The usefulness of adiponitrile (ADN) as a solvent for electrochemical studies has been investigated using several solutes. In the present work, tetraethylammonium tetrafluorborate ( TEA BF4 ) has been used as supporting electrolyte. Ferrocene undergoes reversible redox behavior in ADN/TEABF4, and the peak potential se…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

The molecular structure of high-spin (S = {\bf 5} \over {\bf 2}) manganese(II) phthalocyanine in tetrabutylammonium bromido(phthalocyaninato)manganese(II)

Dmitri V. Konarev、Alexey V. Kuźmin、Salavat S. Khasanov 等 4 位作者2014-04-09Acta Crystallographica Section C Structural Chemistry

The title complex salt, (C16H36N)[MnBr(C32H16N8)] or (TBA)[Mn(II)Br(Pc)] (TBA is tetrabutylammonium and Pc is phthalocyaninate), has been obtained as single crystals by the diffusion technique and its crystal structure was determined using X-ray diffraction. The high-spin (S = 5/2) [Mn(II)Br(Pc)](-) macrocycle has a c…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Effects of Nb addition on glass-forming ability and magnetization behaviors of nanocomposite Nd–Fe–B–Nb strip flakes

Qiong Wu、Hongliang Ge、Pengyue Zhang 等 5 位作者2014-04-09Japanese Journal of Applied Physics

The influences of Niobium doping on the glass-forming ability (GFA) and magnetization properties of Nd–Fe–B–Nb alloys were investigated. It is found that the GFA of Nd–Fe–B–Nb alloys are improved by the Nb addition. It is also revealed that the GFA of the samples increases with the Nb content. Rapidly solidified Nd4.5…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties of Alloys

Effects of alloy disorder and confinement on phonon modes and Raman scattering in SixGe1−x nanocrystals: A microscopic modeling

А. С. Васин、О. В. Вихрова、M. I. Vasilevskiy2014-04-09Journal of Applied Physics

Confinement and alloy disorder effects on the lattice dynamics and Raman scattering in Si1−xGex nanocrystals (NCs) are investigated numerically employing two different empirical inter-atomic potentials. Relaxed NCs of different compositions (x) were built using the Molecular Dynamics method and applying rigid boundary…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

Study of Cu–Zn–Co ternary alloy-coated steel cord in cobalt-free skim compound

Guy Buytaert、Yiwen Luo2014-04-09Journal of Adhesion Science and Technology

In this study, it is shown that the rate of bond degradation due to ageing in hot & humid conditions can be significantly reduced by the use of a Cu–Zn–Co ternary alloy coating, compared to current compounds and normal brass-coated steel cord. To better understand the adhesion mechanism, X-ray photoelectron spectrosco…

Corrosion Behavior and InhibitionElectronic Packaging and Soldering TechnologiesAluminum Alloys Composites Properties

Focal-Series Reconstruction in Low-Energy Electron Microscopy

Thomas Duden、A. Thust、Christian Kumpf 等 4 位作者2014-04-09Microscopy and Microanalysis

In low-energy electron microscopy (LEEM) we commonly encounter images which, beside amplitude contrast, also show signatures of phase contrast. The images are usually interpreted by following the evolution of the contrast during the experiment, and assigning gray levels to morphological changes. Through reconstruction…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Stabilization of Catalytically Active Cu+ Surface Sites on Titanium–Copper Mixed‐Oxide Films

Ashleigh E. Baber、Xiaofang Yang、Hyun You Kim 等 15 位作者2014-04-09Angewandte Chemie

Abstract The oxidation of CO is the archetypal heterogeneous catalytic reaction and plays a central role in the advancement of fundamental studies, the control of automobile emissions, and industrial oxidation reactions. Copper‐based catalysts were the first catalysts that were reported to enable the oxidation of CO a…

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions