Materials Literature
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Biomimetic composite materials consisting of vanadium pentoxide (V2O5) and a liquid crystal (LC) "gluing" polymer were manufactured exhibiting six structural levels of hierarchy, formed through LC phases. The organic matrix was a polyoxazoline with pendant cholesteryl and carboxyl units, forming a lyotropic phase with…
Crystal growth due to recrystallization in rapidly solidified microstructures was experimentally observed. Deeply undercooled Ni–Cu alloy melts were quenched before rapid solidification by Ga–In liquid alloy. After the quenching, partially recrystallized microstructures were obtained and further investigated by means…
Performing time-tagged, time-correlated, single-photon-counting studies on individual colloidal nanocrystal quantum dots (NQDs), the evolution of photoluminescence (PL) intensity-fluctuation behaviors in near-infrared (NIR) emitting type II, InP/CdS core-shell NQDs is investigated as a function of shell thickness. It…
The electrochemically induced extraction of metal atoms from the ternary layered carbides Ti3AlC2, Ti2AlC, and Ti3SiC2 (MAX phases) at room temperature results in predominantly amorphous carbon with a narrow distribution of micropores, as described by Y. Gogotsi et al. in their Communication on page 4877 ff. This appr…
The α and β-positions of pyrrole were substituted with 3,5-dimethylpyrazolylmethyl groups in a single step that involved the reaction between 2,5-dimethylaminomethylpyrrole and 3,5-dimethylpyrazole-1-carbinol, affording 2,3,4,5-tetrakis(3,5-dimethylpyrazol-1-ylmethyl)pyrrole LH in 40% yield. The coordination chemistry…
A method for situ preparing a hybrid material consisting of silica nanoparticles (SiO2) attached onto the surface of functionalized graphene nanoplatelets (f-GNPs) is proposed. Firstly, polyacrylic acid (PAA) was grafted to the surface of f-GNPs to increase reacting sites, and then 3-aminopropyltriethoxysilane (APTES)…
Macroscopic supramolecular assembly is a promising bottom-up method to construct ordered three-dimensional structures in a programmable way because of its flexible tailoring features. To handle the challenges of precisely aligning the building blocks, we proposed the combination of magnetic field-assisted localization…
We present large-area ultrathin metasurfaces that transmit visible light and reflect near-infrared (NIR) wavelengths. These visible-transparent metasurfaces consist of 10 nm-thick monolayer of randomly dispersed silver nanodisks, that is only λ/90 thickness at the reflection peak wavelength. Calculated optical propert…
CoxFe100−x and CoxFe95−xCu5, with 30 < x < 90, arrays of nanowire, around 20 nm in diameter and about 5 μm long, have been prepared by electrodeposition filling the self‐assembled nanopores of anodic alumina templates. These samples were later thermally annealed for 2 h in the range of temperatures up to 600 °C. Cryst…
The ability of solid-state 13 C NMR to detect and quantify small amounts of sp 2 -hybridized carbon on the surface of ∼5 nm diameter nanodiamond particles is demonstrated. The C═C carbon fraction is only 1.1 ± 0.4% in pristine purified detonation nanodiamond, while a full single-layer graphitic or “bucky diamond” shel…
Polymer nanoparticles are prepared by self-assembly of visible light and pH sensitive perylene-functionalized copolymers which are synthesized by quaternization between 1-(bromomethyl)perylene and the dimethylaminoethyl units of poly(dimethylaminoethyl methacrylate) (PDMAEMA). The perylene-containing polymethacrylate…
Protein phosphorylation on serine, threonine, and tyrosine (Ser/Thr/Tyr) is well established as a key regulatory posttranslational modification used in signal transduction to control cell growth, proliferation, and stress responses. However, little is known about its extent and function in diatoms. Phaeodactylum trico…
The adsorption and reaction of propanal and 1-propanol were compared on Ni(111), Fe/Ni(111), and Cu/Ni(111) surfaces by using density functional theory (DFT), temperature-programmed desorption (TPD), and high-resolution electron energy loss spectroscopy (HREELS) as probe reactions for reforming of oxygenates for hydro…
Highly epitaxial LaBaCo2O5.5+δ (LBCO) thin films were grown on different miscut (001) SrTiO3 substrates (miscut angle of 0.5°, 3.0°, and 5.0°) to study the substrate surface step terrace effect on the in-plane electrical transport properties. The microstructure studies by X-ray diffraction and transmission electron mi…
In this paper, we describe the fabrication, simulation and characterization of dense arrays of freestanding silver capped polystyrene nanotubes, and demonstrate their suitability for surface enhanced Raman scattering (SERS) applications. Substrates are fabricated in a rapid, low-cost and scalable way by melt wetting o…
In a recent paper [Mandal et al., Phys. Rev. E 88, 022129 (2013)], the nature of spatial correlations of plasticity in hard-sphere glasses was addressed both via computer simulations and in experiments. It was found that the experimentally obtained correlations obey a power law, whereas the correlations from simulatio…
Phosphogypsum (PG) is a solid waste (a byproduct of the “wet process” phosphoric acid production) in the phosphate fertilizer industry which is environmentally harmful. The thermal decomposition of PG to recycle the sulfur source and produce cement is a proper way for the utilization of PG. In the previous work of our…
Linear low‐density polyethylene (LLDPE)‐based composites were prepared through melt compounding and hot pressing using both untreated and treated halloysite nanotubes (HNT) up to filler contents of 8 wt% to assess the role of the filler exfoliation and surface treatment on the thermal, mechanical, and rheological prop…
Abstract The enzymeless glucose oxidation process readily occurs on nano‐gold electrocatalyst at pH 7, but it is highly susceptible to poisoning (competitive binding), for example from protein or chloride. Is it shown here that gold nanoparticle catalyst can be protected against poisoning by a polymer of intrinsic mic…
We present the design, fabrication, and characterization of guided-mode resonance (GMR) linear polarizers that operate in the optical communications C-band near a wavelength of 1550 nm. We provide theoretical and experimental spectra using resonant elements fashioned in three material systems. In particular, we invest…