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Activators in Accelerated Sulfur Vulcanization

Geert Heideman、Rabin Datta、J. W. M. Noordermeer 等 4 位作者2004-07-01Rubber Chemistry and Technology

Abstract This review provides relevant background information about the vulcanization process, as well as the chemistry of thiuram- and sulfenamide-accelerated sulfur vulcanization with emphasis on the role of activators, to lay a base for further research. It commences with an introduction of sulfur vulcanization and…

Polymer Nanocomposites and PropertiesSilicone and Siloxane ChemistrySynthesis and properties of polymers

Tunable Visible Photoluminescence from ZnO Thin Films through Mg-Doping and Annealing

Shinobu Fujihara、Yusuke Ogawa、Asayo Kasai2004-07-01Chemistry of Materials

Visible photoluminescence (PL) from ZnO has been found to be tunable in a wide range from blue to green and orange through chemical doping and annealing. Mg-doped, (Al, Li)-doped, and undoped ZnO thin films were deposited on glass substrates by a metal-organic decomposition method at temperatures around 600 °C. The fi…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

On the low-frequency spatial dispersion in wire media

C. R. Simovski、P. A. Belov2004-07-01arXiv

The work is dedicated to the theoretic analysis of wire media, i.e. lattices of perfectly conducting wires comprised of two or three doubly periodic arrays of parallel wires which are orthogonal to one another. An analytical method based on local field approach is used. The explicit dispersion equations are presented…

Materials Science

Propagation of a magnetic domain wall in magnetic wires with asymmetric notches

A. Himeno、T. Okuno、S. Kasai 等 7 位作者2004-07-01arXiv

The propagation of a magnetic domain wall (DW) in a submicron magnetic wire consisting of a magnetic/nonmagnetic/magnetic trilayered structure with asymmetric notches was investigated by utilizing the giant magnetoresistance effect. The propagation direction of a DW was controlled by a pulsed local magnetic field, whi…

cond-mat.otherMaterials Science

Magnetic tunneling junctions with the Heusler compound Co_2Cr_{0.6}Fe_{0.4}Al

A. Conca、S. Falk、G. Jakob 等 5 位作者2004-07-01arXiv

The Heusler alloy is used as an electrode of magnetic tunneling junctions. The junctions are deposited by magnetron dc sputtering using shadow mask techniques with AlO_{x} as a barrier and cobalt as counter electrode. Measurements of the magnetoresistive differential conductivity in a temperature range between 4K and…

Materials Sciencecond-mat.other

Investigation of microwave dielectric relaxation process in the antiferroelectric phase of NaNbO3 ceramics

M. H. Lente、J. de Los S. Guerra、J. A. Eiras2004-07-01arXiv

This letter reports microwave dielectric measurements performed in the antiferroelectric phase of NaNbO3 ceramics from 100 to 450 K. Remarkable dielectric relaxations were found within the antiferroelectric phase and in the vicinity of ferroelectric-antiferroelectric phase transition. Such dielectric relaxation proces…

Materials Science

Preliminary studies and potential applications of localized surface plasmon resonance spectroscopy in medical diagnostics

Amanda J. Haes、Richard P. Van Duyne2004-07-01Expert Review of Molecular Diagnostics

Miniature optical sensors that specifically identify low concentrations of environmental and biological substances are in high demand. Currently, there is no optical sensor that provides identification of the aforementioned species without amplification techniques at naturally occurring concentrations. Recently, it ha…

Advanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon ResearchGold and Silver Nanoparticles Synthesis and Applications

Light Amplification Using Inverted Core/Shell Nanocrystals: Towards Lasing in the Single-Exciton Regime

Sergei A. Ivanov、Jagjit Nanda、Andrei Piryatinski 等 9 位作者2004-07-01The Journal of Physical Chemistry B

Size-controlled spectral tunability and chemical flexibility make semiconductor nanocrystals (NCs) attractive as nanoscale building blocks for color-selectable optical-gain media. The technological potential of NCs as lasing materials is, however, significantly diminished by highly efficient nonradiative Auger recombi…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Molecular design of functional polymer surfaces

Jeffrey T. Koberstein2004-07-01Journal of Polymer Science Part B Polymer Physics

Abstract Three design principles are presented that allow for the molecular design of functional polymer surfaces: surface segregation, surface structure, and surface reorganization. These design principles are illustrated by a description of the behavior of model end‐functional polymers that accurately reflect the ge…

Block Copolymer Self-AssemblyAdhesion, Friction, and Surface InteractionsSurface Modification and Superhydrophobicity

The Sellaphora pupula species complex (Bacillariophyceae): morphometric analysis, ultrastructure and mating data provide evidence for five new species

David G. Mann、Sarah M. McDonald、Micha Bayer 等 8 位作者2004-07-01Phycologia

Morphometric shape analysis and ultrastructural data are provided for six genodemes of the Sellaphora pupula species complex that have been studied during the last 20 years from Blackford Pond, Edinburgh, UK. The demes have previously been shown to be separated by prezygotic reproductive barriers: cells of different d…

Diatoms and Algae ResearchAquatic Ecosystems and Phytoplankton Dynamics

Pit nucleation in the presence of 3D islands during heteroepitaxial growth

Mathieu Bouville、Joanna Mirecki Millunchick、Michael L. Falk2004-07-01arXiv

We present a model in which pit nucleation in thin films is considered to arise from a near-equilibrium nucleation process. In this model the adatom concentration plays a central role in controlling the morphological development of the surface. Although pits relieve elastic energy more efficiently than islands, pit nu…

Materials Science

Sodium Doped LaMnO3 Thin Films: Influence of Substrate and Thickness on Physical Properties

Lorenzo Malavasi、Maria Cristina Mozzati、Ivano Alessandri 等 6 位作者2004-07-01arXiv

In this paper we report the results about the synthesis and characterization of optimally doped La1-xNaxMnO3 thin films grown onto SrTiO3 (100), NdGaO3 (100) and NdGaO3 (110) for thickness ranging from 11 to 82 nm. The effect of substrate nature and orientation, film thickness and annealing procedure was investigated…

Materials Science

Reversible Control of Free Energy and Topography of Nanostructured Surfaces

Qiang Fu、G. V. Rama Rao、Solomon B. Basame 等 7 位作者2004-07-01Journal of the American Chemical Society

We describe a facile method for the formation of dynamic nanostructured surfaces based on the modification of porous anodic aluminum oxide with poly(N-isopropyl acrylamide) (PNIPAAm) via surface-initiated atom transfer radical polymerization. The dynamic structure of these surfaces was investigated by atomic force mic…

Polymer Surface Interaction StudiesSurface Modification and SuperhydrophobicityAdhesion, Friction, and Surface Interactions

The role of inorganic fillers in silicone rubber for outdoor insulation alumina tri-hydrate or silica

Luiz Henrique Meyer、E.A. Cherney、Shesha Jayaram2004-07-01IEEE Electrical Insulation Magazine

A systematic study to understand how alumina tri-hydrate (ATH) and silica fillers improve the erosion resistance of silicone rubber during dry band arcing showed that the thermal conductivity of the resulting composite material is the main criterion governing material erosion. The thermal conductivity of the composite…

Aerosol Filtration and Electrostatic PrecipitationPower Transformer Diagnostics and InsulationHigh voltage insulation and dielectric phenomena

Relationship between antibacterial activity of chitosan and surface characteristics of cell wall.

Ying-chien Chung、Ya Su、Chiing-Chang Chen 等 7 位作者2004-07-01PubMed

AIM: Five representative waterborne pathogens were used to illustrate the relationship between chitosan's antibacterial activity and the surface characteristics of the bacterial cell wall. METHODS: Chitosan was prepared with averaged 75% or 95% deacetylated degree to examine its antibacterial activity against waterbor…

Antimicrobial agents and applicationsNanocomposite Films for Food Packaging

Milk Proteins for Edible Films and Coatings

Khaoula Khwaldia、CRISTINA PEREZ、Sylvie Banon 等 5 位作者2004-07-01Critical Reviews in Food Science and Nutrition

Due to the recent increase in ecological consciousness, research has turned toward finding edible materials. Viable edible films and coatings have been produced using milk proteins. These films and coatings may retard moisture loss, are good oxygen barriers, show good tensile strength and moderate elongation, are flex…

Nanocomposite Films for Food PackagingProteins in Food SystemsMicroencapsulation and Drying Processes

Surface composition and structure of Co3O4(110) and the effect of impurity segregation

Sarah C. Petitto、M. A. Langell2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The Co3O4(110) single crystal surface has been characterized by low energy electron diffraction (LEED), Auger electron spectroscopy, and x-ray photoelectron spectroscopy (XPS). LEED analysis of the clean Co3O4(110) spinel surface shows a well-ordered pattern with sharp diffraction features. The XPS spectra are consist…

Catalytic Processes in Materials ScienceElectronic and Structural Properties of OxidesCopper-based nanomaterials and applications

Drug Delivery Systems: Past, Present, and Future

Rubiana Mara Mainardes、Luciano Paulino Silva2004-07-01Current Drug Targets

Drug delivery systems are essential components of drugs controlled release. In the last decades, several drug delivery technologies have emerged including capsules, liposomes, microparticles, nanoparticles, and polymers. These components must be biocompatible, biodegradable, and display a desired biodistribution provi…

Drug Solubulity and Delivery SystemsNanoparticle-Based Drug DeliveryAdvanced Drug Delivery Systems

The Observation of Superparamagnetic Behavior in Molecular Nanowires

Shi Wang、Jing‐Lin Zuo、Song Gao 等 7 位作者2004-07-01Journal of the American Chemical Society

Using the anionic precursor [(Tp)Fe(CN)3]-, a new one-dimensional Ising cyanide-bridged chain, [(Tp)2FeIII2(CN)6Cu(CH3OH).2CH3OH]n, has been prepared. The crystal structure and magnetic studies demonstrate that it is a single-chain magnet and the blocking temperature is ca. 6 K.

Porphyrin and Phthalocyanine ChemistryOrganic and Molecular Conductors ResearchMagnetism in coordination complexes

The Effect of Hydrogen Bonding on Self‐Assembled Polyaniline Nanostructures

Lu Zhang、Yun‐Ze Long、Zhe Chen 等 4 位作者2004-07-01Advanced Functional Materials

Abstract Polyaniline (PANI) nanotubes with an outer diameter of 165–240 nm and an inner diameter of 10–70 nm were prepared by a self‐assembly process in the presence of six different carboxylic acids—propionic acid (PA), lactic acid (LA), succinic acid (SA), malic acid (MA), tartaric acid (TA), and citric acid (CA)—as…

Conducting polymers and applicationsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications