Materials Literature
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Glu230, one of the acidic residues that cluster around the active site of the catalytic subunit of cAMP-dependent protein kinase, plays an important role in substrate recognition. Specifically, its side chain forms a direct salt-bridge interaction with the substrate's P-2 Arg. Previous studies showed that mutation of…
Preface. Symbols. 1 Principles of X-ray Diffraction. 1.1 The Basic Phenomenon. 1.2 The &theta /2&theta Scan. 1.3 Intensity of Bragg Ref lections. 1.4 Applications. 2 Identification of Chemical Phases. 2.1 Histogram-Based Techniques. 2.2 Linear Attenuation Coefficient &mu . 2.3 Determination and Interpretation of the &…
The preparation of smooth mesoporous silica layers on rough, porous stainless steel supports and the subsequent synthesis of well-intergrown b -oriented MFI films on these intermediate layers were investigated. Parameters such as surfactant−silica sol dilution, number of coating cycles, drying, and calcination were sy…
Radial ZnO nanowire arrays were self-assembled on the amorphous carbon thin layer on silicon substrates using thermal chemical vapor transport and condensation without any metal catalysts. We experimentally performed a systematic study to clarify the mechanism of the anomalous nucleation and growth and found that the…
We studied the homogeneous nucleation kinetics of an aqueous suspension of charged colloidal spheres under de-ionized conditions. Samples of equilibrium crystalline structure were shear molten and the metastable melt left to solidify after cessation of shear. At low particle number densities n, corresponding to low me…
A continuous wave 4 kW Nd:YAG laser system was used to weld 2-mm butt joints of sand-cast ZE41A-T5 magnesium alloys at a power of 2.5 kW, welding speed of 6.0 m/min, and defocusing distance from − 2 to + 3 mm for the material in the machined surface conditions. It was found that the adjustment of defocusing distance g…
Reconstructing a protein in three dimensions from its backbone torsion angles is an ongoing challenge because minor inaccuracies in these angles produce major errors in the structure. As a familiar example, a small change in an elbow angle causes a large displacement at the end of your arm, the longer the arm, the lar…
New lanthanide thioantimonate(V) compounds, [Ln(en)3(H2O)x(mu(3-x)-SbS4)] (en = ethylenediamine, Ln = La, x = 0, Ia; Ln = Nd, x = 1, Ib) and [Ln(en)4]SbS4.0.5en (Ln = Eu, IIa; Dy, IIb; Yb, IIc), were synthesized under mild solvothermal conditions by reacting Ln2O3, Sb, and S in en at 140 degrees C. These compounds wer…
A quasielastic neutron-scattering experiment carried out on a backscattering spectrometer with sub-micro eV resolution in the temperature range of 200-250 K has revealed the dynamics of surface water in cerium oxide on the time scale of hundreds of picoseconds. This slow dynamics is attributed to the translational mob…
Summary Films/casings produced using pectin (PN) and gelatin/sodium alginate blends (GSAB) containing 2.5 and 5% added corn oil (CO) or olive oil (OO) and non‐oil containing were manufactured using extrusion technology. Films/casings formed from PN and GSAB had great difference in properties of tensile strength, elong…
Semicrystalline syndiotactic polystyrene (s-PS) films, for all crystalline phases based on helical chains (δ, γ and clathrates), have been prepared with high degrees of three different kinds of uniplanar orientation. In particular, by suitable solution- or solvent-induced crystallizations, (010), (002), or (2̄10) crys…
Porous boron carbonitride nanotubular fibers with BCN stoichiometry and homogeneous B, C, and N species distribution were fabricated via the CVD method. Spatially resolved cathodoluminescence measurements on individual nanostructures revealed intense ultraviolet emission centered at 319 nm, suggesting the characterist…
SecA, the preprotein translocase ATPase, has a helicase DEAD motor. To catalyze protein translocation, SecA possesses two additional flexible domains absent from other helicases. Here we demonstrate that one of these "specificity domains" is a preprotein binding domain (PBD). PBD is essential for viability and protein…
The oxide-based supported catalysts with high specific surface area (>200 m(2)/g) were produced in one step through combination of the impregnation and solution combustion synthesis approaches. As a model system, iron oxide was selected, which was loaded on different porous supports including alpha-Al(2)O(3), gamma-Al…
Due to the continuously increasing demand for ultimate miniaturization of electronic and photonic systems, molecular electronics and plasmonic devices are currently booming as alternative technologies because of their very promising potential in writing, reading, storing, and processing information at the nanoscale. C…
[reaction: see text] The pyridineethenyl-substituted tetrathiafulvalene (TTF) compounds, 4-(4-pyridineethenyl)tetrathiafulvalene (1a) and 4,4'(5')-[bis-(4-pyridineethenyl)]tetrathiafulvalene (2a) together with the styryl-substituted TTF compounds, 4-styryltetrathiafulvalene (1b) and 4,4'(5')-bis-styryltetrathiafulvale…
Atomic volumes, magnetic moments, mixing energies, and the elastic properties of bcc ${\mathrm{Fe}}_{1\ensuremath{-}x}{\mathrm{Cu}}_{x}$ solid solutions are studied by ab initio calculations based on the cluster expansion framework. For the calculation of concentration-dependent elastic moduli in disordered solid solu…
The cluster expansion method provides a standard framework to map first-principles generated energies for a few selected configurations of a binary alloy onto a finite set of pair and many-body interactions between the alloyed elements. These interactions describe the energetics of all possible configurations of the s…
Simultaneous conductance and capacitance measurements on a single-walled carbon nanotube (SWNT) network are used to extract an intrinsic property of molecular adsorbates. Adsorbates from dilute chemical vapors produce a rapid response in both the capacitance and the conductance of the SWNT network. These responses are…
We report extensive numerical simulations of a simple model for charged colloidal particles in suspension with small nonadsorbing polymers. The chosen effective one-component interaction potential is composed of a short-range attractive part complemented by a Yukawa repulsive tail. We focus on the case where the scree…