Materials Literature
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We determine from first principles the finite-temperature properties-linewidths, line shifts, and lifetimes-of the key vibrational modes that dominate inelastic losses in graphitic materials. In graphite, the phonon linewidth of the Raman-active E(2g) mode is found to decrease with temperature; such anomalous behavior…
Increasing use of metallic nanomaterials is likely to result in release of these particles into aqueous environments; however, it is unclear if these materials present a hazard to aquatic organisms. Because some dissolution of metal particles will occur, it is important to distinguish effects of nanoparticulates from…
Logic gates are basic digital elements for computers. We build up thermal logic gates that can perform similar operations as their electronic counterparts. The thermal logic gates are based on nonlinear lattices, which exhibit very intriguing phenomena due to their temperature dependent power spectra. We demonstrate t…
Nanotechnology is the understanding and control of matter generally in the 1-100 nm dimension range. The application of nanotechnology to medicine, known as nanomedicine, concerns the use of precisely engineered materials at this length scale to develop novel therapeutic and diagnostic modalities. Nanomaterials have u…
The performance of X-ray microanalysis in the variable pressure or environmental scanning electron microscope (VP-SEM or ESEM) is limited by skirting. Under certain conditions, charging effects can occur and change the X-ray emission, which affects the X-ray microanalysis. The conventional way to evaluate charging is…
Abstract The term bio‐active packaging refers to a packaging material that has been modified by the attachment or immobilization of bioactive components on the food contact surface. This article describes a novel, economical, and feasible technique for embedding bioactive components in energy curable food contact resi…
Gamma radiation levels at the well heads in the Nigerian Petroleum Development Company Oil Field located at Ologbo in Edo State of Nigeria have been investigated using a Digilert 50 Radiation Geiger Muller Counter. The sites investigated include one heavy crude oil producing well (A), one light crude producing well (B…
This paper presents a multidimensional extension of the Schur-Cohn algorithm for testing BIBO stability in N variables. This new method only needs a unique condition to be checked, as an alternative to the set of conditions of the well-known Huang-Jury-Anderson stability test. The proposed algorithm is based on a gene…
Arylhydrazones were linked onto gold nanoparticles through the poly(ethylene glycol) spacer to produce a new type of photoinduced DNA-cleaving nanomaterials with great potency.
The synthesis is described for a small series of oligomers built from (2, 3, 4 or 6) ethynyl-naphthalene repeat units and end-capped with solubilising 1,2,3-tris-dodecyloxy-benzene groups. These compounds absorb in the near-UV region and exhibit strong fluorescence in both fluid solution and a glassy matrix at 77 K. T…
The electronic energy loss of swift H and He ions in gold is studied, paying special attention to the contribution to the projectile energy loss due to the ionization of the target inner-shells. We calculate the stopping power and the energy-loss straggling as a function of the projectile energy, taking into account t…
The reaction of boehmite with diethyl phosphoric acid generated in situ in a boiling water solution of triethyl phosphate has been studied in detail. Two kinds of solid products have been isolated and characterized by elemental and XPS analysis, in addition to XRD, TGA, FT-IR, SEM, and MAS NMR techniques. One of them…
alpha-sheet has been proposed as the main constituent of the prefibrillar intermediate during amyloid formation. Here the helical parameters of the alpha-sheet strand are calculated from average main-chain dihedral angles reported from molecular dynamics simulations. It is an almost linear polypeptide that forms a rig…
We investigate the tunneling escape of confined excitons in CdSe core-shell quantum dots by means of the time-dependent Schrodinger equation. Our results indicate that obtaining efficient charge extraction strongly depends on the interplay between parameters such as nanocrystal sizes, shell thicknesses, external elect…
The crystallization of macromolecules as an intermediate in the production of protein structures is often the rate-limiting factor. Achievements in the field of protein crystallization such as automation, availability of commercial crystallization kits, the application of developments in nanotechnology, and informatio…
Plants encode the bifunctional dehydroquinase-shikimate dehydrogenase (DHQ-SDH), which catalyzes the third and fourth steps of the shikimate pathway. We report the Arabidopsis thaliana DHQ-SDH structure in complex with all of its natural substrates. The DHQ-SDH enzyme was first cocrystallized with shikimate. NADP + wa…
Polyurethane flexible foam having shape memory effects has been synthesized from polyester polyol and 4,4'-diphenylmethane diisocyanate (MDI) following the quasi-prepolymer method in the presence of water as the blowing agent, and the effect of the organometallic catalyst and the molecular weight of polyol has been st…
Abstract We present a novel method of controlling the specular and diffuse reflection of light by the electrostatic deposition of a spherical particle monolayer followed by electroless plating. Charged polystyrene colloidal particles, ranging in size from 100 nm to 5 μm, were adsorbed from solution onto oppositely cha…
A general approach toward amphiphilic systems bearing multimetallic clusters and their ability to form Langmuir-Blodgett films is presented. The synthetic strategy to stabilize these clusters involves the use of a ligand (HL) containing an N(2)O-donor set and long octadecanoic chains to obtain the carboxylate-supporte…
The magnetoelectric (ME) coupling from 20 Hz to 100 kHz and the hydrogen effect on Ni–PZT–Ni trilayer composites made by electrodeposition have been investigated. The results show that the magnetoelectric voltage coefficient, α E ,31 , increases with increased Ni layer thickness, up to α E ,31 = 16 V cm −1 Oe −1 . The…