Materials Literature
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We propose that in the presence of an Ohmic, de-phasing type environment, a two-level-cavity system undergoes a quantum phase transition from a state with damped Rabi oscillation to a state without. We present the phase diagram and make predictions for pump and probe experiment. Such a strong coupling effect of the en…
The combination of self-assembly and electronic properties as well as its true nanoscale dimensions make DNA a promising candidate for a building block of single molecule electronics. We argue that the intrinsic double helix conformation of the DNA strands provides a possibility to drive the electric current through t…
A newly discovered group of alloys, called Gum Metals, approaches ideal strength in bulk form, exhibits significant plastic deformation prior to failure, and shows no indications of conventional-dislocation activity. Two conditions must be met for a material to exhibit this "ideal" behavior: (1) the stress required to…
Y 2 O 3: Eu 3+ microspheres, with an average diameter of 3 μm, were successfully prepared through a large-scale and facile solvothermal method followed by a subsequent heat treatment. X-ray diffraction, Fourier transform infrared spectroscopy, energy-dispersive X-ray spectra, thermogravimetric and differential thermal…
Abstract Man kennt eine Vielzahl magnetischer Materialien, deren magnetische Eigenschaften durch externe Stimuli geschaltet werden können. Das Hauptaugenmerk liegt auf der thermischen, photochemischen, elektrochemischen und chemischen Steuerung von Phasenübergängen, die mit einem Wechsel der Magnetisierung einhergehen…
Nickel ferrite (NiFe 2 O 4 ) nanoparticles with an average crystallite size of about 8.6 nm were prepared by mechanochemical synthesis (mechanosynthesis). In-field Mössbauer spectroscopy and high-resolution TEM studies revealed a nonuniform structure of mechanosynthesized NiFe 2 O 4 nanoparticles consisting of an orde…
The magnetic properties of many magnetic materials can be controlled by external stimuli. The principal focus here is on the thermal, photochemical, electrochemical, and chemical control of phase transitions that involve changes in magnetization. The molecular compounds described herein range from metal complexes, thr…
Understanding the energy it takes to build or break chemical bonds is essential for scientists and engineers in a wide range of innovative fields, including catalysis, nanomaterials, bioengineering, environmental chemistry, and space science. Reflecting the frequent additions and updates of bond dissociation energy (B…
Effect of the heat stabilizer on the melt rheological properties of the blends of polypropylene (PP) with mLLDPE (mettalocene linear low density polyethylene), after thermal degradation in an air oven, was studied. Study carried out is presented to describe the effect of blending ratio and presence of stabilizer on sh…
To prepare sulfur-containing natural polymers effectively, several plant oils and 3,3'-thiodipropionic acid (TDP) have been used as carbon sources for the biosynthesis of copolymer poly[(3-hydroxybutyrate)-co-(3-mercaptopropionate)] [poly(3HB-co-3MP)] by a wild-type bacterium Cupriviadus necator H16. By using the plan…
Abstract The objective of this work was to study the effectiveness of commercial compatibilizers (E‐EA‐MAH copolymer) on the morphology of blends of polypropylene/ethylene polypropylene rubber (PP/EPR) (78/22) and metallocenic ethylene‐octene copolymer (EOC) polluted by (poly (vinyl chloride) (PVC) and by an oil for e…
The molecular structure of the interphase between plasma-polymerized acetylene films and steel substrates was determined using in situ reflection–absorption infrared spectroscopy (RAIR) and X-ray photoelectron spectroscopy (XPS). Plasma-polymerized acetylene films were deposited onto polished steel substrates using ar…
Differential scanning calorimeter (DSC) and thermal conductivity meter were used for measurement of thermal conductivity by unsteady state technique of the high impact polystyrene (HIPS) composites filled with 0.5, 1.5, and 2.5 wt.% of CaCO3 nano particles. A comparison of experimental and theoretical values of (K c /…
Abstract Single crystals of lead magnesium niobate titanate, 0.65 PbMg 2/3 Nb 1/3 O 3 (PMN) ‐0.35PbTiO 3 (PT) were grown using flux method near morphotropic phase boundary (MPB) composition. The crystals grown at the centre of the platinum crucible were found to PT deficient compared to those grown near the walls of t…
Contrast agents are widely employed in medical imaging for improved visualization of anatomy and disease characterization. In recent years, there is increasing interest in developing novel contrast agents and using their tissue accumulation and clearance patterns to obtain physiological information. The goal of this i…
Abstract A simple synthetic method for preparing the core‐shell latex particles containing fluorinated shell was presented. Polymerization was achieved by a low‐sheer monomer‐starved emulsion polymerization process, thus facilitating mobility and subsequent polymerization of perfluoroacrylate (FA) along with methyl me…
The amidase reaction of trypsin, which is a member of the serine proteinase family, is accelerated by its complexation with block ionomers containing a polycarboxylate block, such as PEG-PAA, PEG-PGA, or PEG-PMA. PEG-PAA and PEG-PGA had similar effects, causing an increase in the k(cat) value and a shift in the pH pro…
Abstract 4‐(2‐hydroxyphenylamino)‐pent‐3‐en‐2‐one (HPAP) was synthesized and single crystals were grown by the solution growth technique using methanol as a solvent. The crystals having orthorhombic symmetry were characterized by single crystal XRD, FTIR spectroscopy, NMR spectroscopy, TGA, DSC and dielectric studies.…
In this paper, the authors have systematically studied the microphase separation and crystallization during spin coating of an ABC triblock copolymer, polystyrene-b-poly(2-vinylpyridine)-b-poly(ethylene oxide) (PS-b-P2VP-b-PEO). The microphase separation of PS-b-P2VP-b-PEO and the crystallization of PEO blocks can be…
Polymer blends of commercial polyphenylene oxide (mPPO) and polypropylene (PP) are immiscible and incompatible in blend system. Maleic anhydride-grafted-copolymer has been employed as in situ compatibilizer for the mPPO and PP blends. This copolymer contains reactive anhydride functional groups that were able to react…