Materials Literature
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Abstract This paper demonstrates the first steps towards self‐healing composites that exploit a design philosophy inspired by the damage tolerance and self‐repair functions of bone. Cracking in either fibre reinforced polymers (FRP) or bone, if left unattended, can grow under subsequent cyclic stresses eventually lead…
The electrocaloric effect (ECE) was directly measured in a relaxor ferroelectric poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) terpolymer. It was observed that the temperature dependence of ECE of the terpolymer films depends critically on the film preparation conditions. While the…
Plate impact experiments have been carried out to examine the influence of grain boundary characteristics on the dynamic tensile response of Cu samples with grain sizes of 30, 60, 100, and 200 μm. The peak compressive stress is ∼1.50 GPa for all experiments, low enough to cause an early stage of incipient spall damage…
Abstract A micromachined reconfigurable metamaterial is presented, whose unit cell consists of a pair of asymmetric split‐ring resonators (ASRRs); one is fixed to the substrate while the other is patterned on a movable frame. The reconfigurable metamaterial and the supporting structures (e.g., microactuators, anchors,…
Photocatalytic oxygenation of benzene with oxygen and water to phenol has been achieved under ambient conditions by using the 3-cyano-1-methylquinolinium ion as a photocatalyst (see picture). The mechanism was clarified by detecting the π-dimer benzene radical cation produced by photoinduced electron transfer from ben…
We study the response of graphene to high-intensity, 50-femtosecond laser pulse excitation. We establish that graphene has a high (∼3 × 1012 Wcm−2) single-shot damage threshold. Above this threshold, a single laser pulse cleanly ablates graphene, leaving microscopically defined edges. Below this threshold, we observe…
Dendrimers show increasing promise as drug-delivery vectors and can be generated with a wide range of scaffold structures, sizes and surface functionalities. To this point, the majority of studies of dendrimer-based drug-delivery systems have detailed pharmacodynamic outcomes, or have followed the pharmacokinetics of…
Nanotechnology and nanomaterials have tremendous potential to enhance the food supply through novel applications, including nutrient and bioactive absorption and delivery systems; ingredient functionality; improved colors and flavors; microbial, allergen, and contaminant detection and control; and food packaging prope…
Polycrystalline samples of a layered magnetic ceramic oxide, Ba2Co2Fe12O22 (Co2Y), doped with Bi2O3 were prepared by the solid state reaction method. The dielectric impedance properties were studied over the range of frequency between 1 Hz–1MHz and in the temperature range of 313–493 K, using the modulus formalism. Th…
OBJECTIVE: To develop a simple rapid procedure for bioreduction of silver nanoparticles (AgNPs) using aqueous leaves extracts of Catharanthus roseus (C. roseus). METHODS: Characterization were determined by using UV-Vis spectrophotometry, scanning electron microscopy (SEM), energy dispersive X-ray and X-ray diffractio…
This work investigates crystal lattice, electronic structure, relative stability, and high pressure behavior of TiO(2) polymorphs (anatase, rutile, and columbite) using the density functional theory (DFT) improved by an on-site Coulomb self-interaction potential (DFT+U). For the latter the effect of the U parameter va…
The electronic structure of Vanadium pentoxide (V2O5), a transition metal oxide with an exceedingly large work function of 7.0 eV, is studied via ultraviolet, inverse and x-ray photoemission spectroscopy. Very deep lying electronic states with electron affinity and ionization energy (IE) of 6.7 eV and 9.5 eV, respecti…
The stability and bulk properties of two-dimensional boronate ester-linked covalent organic frameworks (COFs) were investigated upon exposure to aqueous environments. Enhanced stability was observed for frameworks with alkylation in the pores of the COF compared to nonalkylated, bare-pore frameworks. COF-18Å and COF-5…
There is great demand for the development of novel therapies for ischemic cardiovascular disease, a leading cause of morbidity and mortality worldwide. We report here on the development of a completely synthetic cell-free therapy based on peptide amphiphile nanostructures designed to mimic the activity of VEGF, one of…
The application of biomass, such as starch, cellulose, wood, and sugar, used to substitute fossil resources for the production of plastics, is a widely accepted strategy towards sustainable development. In fact, this way a significant reduction of non renewable energy consumption and carbon dioxide emission is accompl…
A simple metamaterial-based wide-angle plasmonic absorber is introduced, fabricated, and experimentally characterized using angle-resolved infrared spectroscopy. The metamaterials are prepared by nano-imprint lithography, an attractive low-cost technology for making large-area samples. The matching of the metamaterial…
The discovery of cuprate high T C superconductors has inspired the search for unconventional superconductors in magnetic materials. A successful recipe has been to suppress long-range order in a magnetic parent compound by doping or high pressure to drive the material towards a quantum critical point. We report an exc…
Nanotechnology is the creation of functional materials, devices and systems at atomic and molecular scales (1-100 nm), where properties differ significantly from those at a larger scale. The use of nanotechnology and nanomaterials in medical research is growing rapidly. Recently, nanotechnologic developments in microb…
A small rise in tumor temperature (hyperthermia) makes cancer cells more susceptible to radiation and chemotherapy. The means of achieving this is not trivial, and traditional methods have certain drawbacks. Loading tumors with systematically asministered energy-transducing nanoparticles can circumvent several of the…
The development of a convenient method for the removal (or collection) of oils and organic solvents from water surface is of great significance for water environmental protection, especially for the cleanup of oil spillage on seawater. A major challenge is the fabrication of an oil absorber with high absorption capaci…