Materials Literature
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Using first-principles density functional theory (DFT) calculations, we study the thermodynamics and crystal structure of calcium alanate, $\mathrm{Ca}{(\mathrm{Al}{\mathrm{H}}_{4})}_{2}$, and its decomposition products $\mathrm{Ca}\mathrm{Al}{\mathrm{H}}_{5}$, $\mathrm{Ca}{\mathrm{H}}_{2}$, and $\mathrm{Ca}{\mathrm{A…
The dynamics of electro-optical switching processes in the biaxial nematic phase of an oxadizole-based bent-core liquid crystal (LC) was studied. This LC exhibits optical biaxiality in the lower temperature range of the nematic phase although it exhibits optical uniaxiality in the higher temperature range. In particul…
Wet fibrous structures such as nanotube carpets or macroscopic brushes tend to self-assemble into bundles when the liquid evaporates. The aggregation process relies on a balance between capillary attraction provided by liquid bridges and restoring torque due to structure stiffness. The final self-organized structure i…
The effect of adding surface-active solutes to water being insonated at 515 kHz has been investigated by monitoring the acoustic emission from the solutions. At low concentrations (<3 mM), sodium dodecyl sulfate causes marked changes to the acoustic emission spectrum which can be interpreted in terms of preventing bub…
Carbon nanotubes are being used in place of carbon fibers in making composites due to their high strength, high aspect-ratio and excellent thermal and electrical conductivity. Although carbon nanotubes were discovered more than a decade ago, works on preparation of satisfactory composites reinforced by carbon nanotube…
Abstract A general procedure is described for the synthesis and conversion of dispersible core/shell LaF 3 :Tm/LaF 3 nanoparticles to highly dispersible thulium‐doped lanthanum disilicate nanoparticles (La 2 Si 2 O 7 :Tm) with an average diameter of 7 nm that show emission at a wavelength of 1.47 μm. Measurement of th…
The influence of different factors (primarily, the temperature-time conditions for preparation and measurement of samples) on the glass transition temperatures determined from the temperature dependences of properties is analyzed using the calculations performed in terms of the relaxation theory of glass transition. T…
Superhydrophobic surfaces are biomimetic structures with potential applications in several key technological areas. In the past decade, several top-down and bottom-up fabrication methods have been developed to create such surfaces. These typically combine a hierarchical structure and low surface energy coatings to inc…
Landau theory has been used to develop expressions for the elastic anomalies that accompany octahedral tilting transitions in perovskites that are associated with the M and R points of the Brillouin zone. The master equation is a 246 Landau potential with saturation terms that provides phenomenological descriptions of…
In this letter, it is shown that, contrary to previous assumptions, the broadband characteristics of metamaterial transmission lines are not exclusive of the so called CL loaded composite right/left handed (CRLH) structures. In the balance condition, the typical frequency gap between the left handed (LH) and right han…
rf magnetron sputtering, an established and scalable large area deposition process, is used to deposit Nb:TiO2 and Ta:TiO2 films onto (100) SrTiO3 substrates at temperatures TS ranging from room temperature to 400°C. Optical, electrical, and structural properties similar to those reported for pulsed laser deposition g…
The effects of cross-linking by-products (residues) quantity and thermal treatment on space charge accumulation and decay in manufacturer modified XLPEs for DC power cable application have been investigated using the pulsed electro-acoustic technique. The threshold stress for space charge generation among the modified…
Abstract The effect of needle diameter on the resulting electrospun poly(methyl methacrylate) (PMMA) average nanofiber diameter has been evaluated for three different needle gauges. The resulting nanofibers were observed and analyzed by scanning electron microscopy (SEM), suggesting a lack of correlation between the n…
We have designed, synthesized, and characterized a short (32-mer; 8-nm), single-stranded, collagen-related peptide (CRP), 1a, which forms triple-helical building blocks that self-assemble into large, composite fibrils by strictly noncovalent means. Computational analysis suggested that the installation of complementar…
Dinuclear [(TPyA)MII(CA2-)MII(TPyA)]2+ [TPyA=tris(2-pyridylmethyl)amine; CA2-=chloranilate dianion; M=Co (1(2+)), Fe (2(2+))] complexes have been prepared by the reaction of M(BF4)(2).6H2O, TPyA, H2CA, and triethylamine in MeOH solution. Their reduced forms [(TPyA)MII(CA*3-)MII(TPyA)]+ [M=Co(1+), Fe (2+)] have been sy…
The rheological behaviour of frozen soils depends on a number of factors and is complex. Stress and temperature histories as well as the actual composition of the frozen soil are only some aspects that have to be considered when analysing the mechanical response. Recent improvements in measuring methods for laboratory…
Rheology is commonly used as a tool for analytics and quality control in latex technology. As soon as flow becomes essential for the structure measured in a scattering experiment we call it scattering from shear-ordered dispersions or rheologic scattering. In this paper it is shown that the structure of concentrated d…
The rheological behavior of a fugitive organic ink tailored for direct-write assembly of 3D microfluidic devices is investigated. Rheological experiments are carried out to probe the shear storage and loss moduli as well as the complex viscosity as a function of varying temperature, frequency and stress amplitude. Mas…