Materials Literature
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The drug benzocaine (ethyl 4-aminobenzoate), commonly used as a local anaesthetic, is a bimorphic solid at room temperature. Form (I) is monoclinic P2(1)/c, while the metastable form (II) is orthorhombic P2(1)2(1)2(1). Three-dimensional diffuse X-ray scattering data have been collected for the two forms on the 11-ID-B…
Rotationally resolved high-resolution spectra and fluorescence decay curves have been observed for weak and short-lived vibronic bands of the S(1) (1)B(3u) <-- S(0) (1)A(g) transition of naphthalene. Fluorescence lifetime of the vibronic band with an excess energy of 1390 cm(-1) (0(0)(0) + 1390 cm(-1) band) is remarka…
The title compound, [Ca(C4H4O6)].4H2O, calcium tartrate tetrahydrate, is a new triclinic centrosymmetric form identified in rat kidney calculus. The crystal structure was determined from powder and single-crystal X-ray diffraction. The four water molecules belong to one square face of the Ca-atom coordination (a squar…
This study demonstrates carbon nanotube (CNT) reinforced conductors for flexible electronics. The supreme mechanical strength of the CNT is toughened by the structure of the metal conductor. Conventional metal lines, fabricated using a screen printing technique on flexible substrates, usually suffer a great deal of st…
We report a novel method for the synthesis of fractal Zn structures through a solution phase reaction. An Al-film-deposited substrate was immersed in an aqueous ammonia solution containing Zn ions and maintained at 95 degrees C for 5 min. After the reaction, the Al-deposited side of the substrate was found to be cover…
The properties of guiding modes of a slab waveguide composed of impedance-matched epsiv (permittivity) negative and mu (permeability) negative media were investigated. This special type of waveguide supports only a single mode having polarization degeneracy: transverse-electric (TE)- and transverse-magnetic (TM)-polar…
Hydroxylamine (HA) has been independently involved in several tragic accidents, which incurred numerous fatalities and injuries. Following these incidents, adiabatic calorimetry and computational chemistry research was conducted, suggesting potential reaction pathways of HA decomposition, but the mechanism of HA behav…
The investigation of the dynamics of water and organic species confined in minerals or adsorbed at their surface is of significant geochemical, environmental, catalytic, biomedicine, and life’s growth interests but is poorly understood on the molecular scale. This work explores the behavior of water molecules and glut…
Introduction of reinforcing fillers in RPP matrix help to enhance the properties of the matrix. In this study, waste jute fibers called jute caddies have been used as the filler material to RPP and their properties have been studied. The composites have been prepared by solution impregnation method. A silane coupling…
A major driving force behind the research of SWNT electronic properties is their potential in nanoelectronic applications. It has been predicted and experimentally verified that the electronic properties of metallic and semiconducting SWNTs are dependent on their diameter and chirality. With the increase in the densit…
Abstract Transparent single crystals of PbSbO 2 Br (green), PbSbO 2 I, and PbBiO 2 Br (yellow) were obtained by solid state reactions of stoichiometric amounts of PbO, Pn 2 O 3 ( Pn = Sb, Bi) and PnX 3 ( X = Br, I). The crystal structures were determined from single‐crystal X‐ray data. The title compounds crystallize…
Abstract Hollow, urchin‐like carbon spheres with electromagnetic function were prepared by a carbonization process at 1200 °C under an argon atmosphere by using template‐free‐synthesized, urchin‐like, hollow spheres of polyaniline containing FeCl 3 as the precursors. The resulting hollow, urchin‐like carbon spheres no…
Abstract With the aim to give more hints to a theoretical model that describes the phenomenon of delayed luminescence (DL) from biological systems as due to the collective electron states that are excited in macromolecular structures by external illumination, a spectral characterization of DL from bovine Achilles' ten…
We show that mechanical stiffness is a useful metric for characterizing complex collagen assemblies, providing insight about aggregation products and pathways in collagen-based materials. This study focuses on mechanically robust collagenous membranes produced by an electrochemical synthesis process. Changing the dura…
We have investigated the temperature and pressure variation of the ${M}_{3}$ phonon mode of ${\text{ReO}}_{3}$ by inelastic neutron scattering on a single crystal. The energy of the ${M}_{3}$ phonon mode decreases with decreasing temperature contrary to the normal hardening behavior. The energy of this mode also decre…
The field-induced first-order phase transition in $({\text{Er}}_{1\ensuremath{-}x}{\text{Y}}_{x}){\text{Co}}_{2}$ with the yttrium concentration $x=0.45$ is observed to be accompanied by a butterflylike behavior and significant irreversibility of the specific heat. The coefficient $\ensuremath{\gamma}$ of the $T$-line…
Hydrogels of calcium alginate are the cross-linked networks containing a large fraction of water, which were used as the precursors of calcium carbonate (CaCO 3 ) mineralization for the first time. The well-defined geometry, the permeability, and the ion-exchange property of these pregels favored the facile fabricatio…
This work reported for the first time a facile template-free method to prepare polypeptide-based vesicles (peptosomes) through one-step complex self-assembly of carboxyl-terminated hyperbranched polyester and cationic poly-l-lysine (PLL). The preparation of such peptosomes, named complex peptosomes (CPs) here, is very…
Various Pt species were shown to be present in Pt/H-mordenite catalyst preparations containing 1.5 and 2.6 wt % Pt. Air calcination of the catalyst precursor generated large Pt 0 x metal particles (average size of >10 nm) by autoreduction, whereas a fraction of the platinum was converted to cations and oxycations, suc…
Composite films containing silver nanoparticles embedded in diamond-like carbon (DLC) matrix were deposited on glass substrates by using capacitatively coupled plasma (CCP) chemical vapour deposition techninique (CVD). Particle size and metal volume fraction were tailored by varying the relative amount of methane of a…