Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
We studied the electronic structure of the Kondo lattice system ${\mathrm{Ce}}_{2}{\mathrm{Co}}_{0.8}{\mathrm{Si}}_{3.2}$ by angle-resolved photoemission spectroscopy. The spectra obtained below the coherence temperature consist of a Kondo resonance, its spin-orbit partner, and a number of dispersing bands. The quasip…
ABSTRACT A detailed evaluation of the kinetics of domino free radical photopolymerization (DFRP) based on phototriggered base proliferation reaction and redox initiation was described in the condition of eliminating the heat of polymerization via reacting in the thin polymer films. First, domino photoinitiating system…
In entangled polymer melts and concentrated solutions, uncrossability of chains restricts the motions of a given chain transverse to its own path. Constraint release occurs when the end of a neighboring chain slips past a given chain, releasing it to hop transversely. We use molecular dynamics simulations of a melt of…
ABSTRACT Poly(vinyl alcohol) has been functionalized with aldehydes in tetrahydrofuran (THF) with a good control of the grafting. A wide library of poly(vinyl acetals) could be obtained in order to study some structure/property correlations. The influence of the aldehyde nature on the functionalization rates has been…
Equipment used in hybrid or electric vehicles (HEVs) must meet certain requirements. Beyond issues of electro-magnetic compatibility (EMC), it’s necessary to assess the risks related to the exposure of the passengers to electromagnetic field inside an HEV. At low frequencies, using the electromagnetic shielding as pro…
Nanoparticles are potentially powerful therapeutic tools that have the capacity to target drug payloads and imaging agents. However, some nanoparticles can activate complement, a branch of the innate immune system, and cause adverse side-effects. Recently, we employed an in vitro hemolysis assay to measure the serum c…
The effects of Mo content on the thermal stability, glass-forming ability (GFA), magnetic and mechanical properties of Fe75−xMoxP10C10B5 (x = 0–10) metallic glasses were investigated. The stabilization of supercooled liquid and GFA were significantly enhanced by addition of Mo. Although the saturation magnetization (I…
The effect of low thickness of CdTe on optical, front, and back recombination losses and hence on the efficiency of a CdS/CdTe solar cell is studied theoretically in this work. It is found that the optical losses are about 23%–24% and depend weakly on CdTe thickness. The recombination losses are about 28% at dCdTe = 0…
Abstract Attempts to synthesize 2‐hydroxynitrostyrenes by a Knoevenagel condensation of salicylaldehyde and subsequent elimination were unsuccessful because of the formation of a stable imine. This could be easily prevented by using secondary amines to catalyze the reaction, which then afforded 2‐hydroxynitrostyrenes…
A novel soft-hard cooperative approach was developed to synthesize bioactive mesoporous composite by pre-wrapping Penicillin G amidase with poly(acrylaimde) nanogel skin and subsequently incorporating such Penicillin G amidase nanocapsules into hierarchically mesoporous silica. The as-received bioactive mesoporous com…
NMR is a fast, nondestructive, and noninvasive technique that can provide information about the pore structure of macroporous polymer beads and the dynamics of liquids confined in them. In this work, we describe the study of the pore structure of the macroporous polymer of ethylene glycol dimethacrylate and 2-hydroxye…
We study the quantum phase transition between the ${Z}_{2}$ spin liquid and valence bond solid (VBS) orders on a triangular lattice. With a fully isotropic triangular lattice, the transition from a columnar or resonating-plaquette VBS order can either be first order or there could be two transitions with an intermedia…
Concrete is an extensively used construction material for its various advantages such as low cost, availability, fire resistance etc. But it cannot be used alone everywhere because of its low tensile strength. So, generally steel is used to reinforce the concrete. But considering high cost of steel, bamboo is one of t…
In the present paper, PbMoO 4 polyhedron microcrystals were prepared via a facile hydrothermal synthetic route in the absence of any surfactant, employing Pb(NO 3 ) 2 and Na 2 MoO 4 ·2H 2 O as starting materials. The phase and morphology of the product were characterized by powder X-ray diffraction (XRD), energy dispe…
Al foam has been used in a wide range of applications owing to its light weight, high energy absorption and high sound insulation. One of the promising processes for fabricating Al foam involves the use of a foamable precursor. In this study, ADC12 Al foams with porosities of 67%-78% were fabricated from Al alloy die…
Modified Shepard interpolation based on second order Taylor series expansions has proven to be a flexible tool for constructing potential energy surfaces in a range of situations. Extending this to gas-surface dynamics where surface atoms are allowed to move represents a substantial increase in the dimensionality of t…
ABSTRACT Millions of tons of plasticized poly(vinyl chloride) (PVC) materials are disposed every year. A biologically sustainable and green method for removal of toxic plasticizers from polymer systems after disposal is highly desired since plasticizers can leach out into the environment over decades. Here we compare…
Powdered Prussian blue analogues (PBAs) and PBAs confined in ordered mesoporous silica monoliths were used as oxide precursors through thermal treatment under an oxidizing atmosphere. The study focuses on the transformation of the alkali cation-free CoCo PBA of chemical formula K 0.1 Co II 4 [Co III (CN) 6 ] 2.7 ·20 H…
Measurements with nanomechanical cantilever (NMC) sensors often reveal only qualitative results. Here we overcome this issue by inkjet printing well-defined polyelectrolyte multilayers (PEMs). We present a method that allows fabricating a 40 bilayer (BL) thick and 5 mm long line made of poly(allylamine hydrochloride)…
The reaction of [Pt(N-N)2](2+) [N-N = 2,2'-bipyridine (bpy) or 4,4'-dimethyl-2,2'-bipyridine (4,4'-Me2bpy)] with phosphine ligands [PPh3 or PPh(PhSO3)2(2-)] in aqueous or methanolic solutions was studied by multinuclear ((1)H, (13)C, (31)P, and (195)Pt) NMR spectroscopy, X-ray crystallography, UV-visible spectroscopy,…