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Solid–Solid Transition between Hydrated Racemic Compound and Anhydrous Conglomerate in Na-Ibuprofen: A Combined X-ray Diffraction, Solid-State NMR, Calorimetric, and Computational Study

Patrizia Rossi、Eleonora Macedi、Paola Paoli 等 7 位作者2014-03-21Crystal Growth & Design

A combined X-ray diffraction (XRD), solid state nuclear magnetic resonance (SSNMR), differential scanning calorimetry (DSC), and modeling approach has been applied to study the solid–solid transition of ibuprofen sodium salt between the hydrated racemic compound (RS-H) and the anhydrous conglomerate (RS-A). For compar…

Crystallography and molecular interactionsAdvanced NMR Techniques and ApplicationsX-ray Diffraction in Crystallography

Syntheses of Macromolecular Ruthenium Compounds: A New Approach for the Search of Anticancer Drugs

Andreia Valente、M. Helena García2014-03-21Inorganics

The continuous rising of the cancer patient death rate undoubtedly shows the pressure to find more potent and efficient drugs than those in clinical use. These agents only treat a narrow range of cancer conditions with limited success and are associated with serious side effects caused by the lack of selectivity. In t…

Metal complexes synthesis and propertiesDendrimers and Hyperbranched PolymersFerrocene Chemistry and Applications

A Novel Chitosan-γPGA Polyelectrolyte Complex Hydrogel Promotes Early New Bone Formation in the Alveolar Socket Following Tooth Extraction

Hao‐Hueng Chang、Yin‐Lin Wang、Yu‐Chih Chiang 等 9 位作者2014-03-21PLoS ONE

A novel chitosan-γPGA polyelectrolyte complex hydrogel (C-PGA) has been developed and proven to be an effective dressing for wound healing. The purpose of this study was to evaluate if C-PGA could promote new bone formation in the alveolar socket following tooth extraction. An animal model was proposed using radiograp…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsPeriodontal Regeneration and Treatments

A General, Tractable and Accurate Model for a Cascade of LRU Caches

Nicola Bléfari-Melazzi、Giuseppe Bianchi、Alberto Caponi 等 4 位作者2014-03-21IEEE Communications Letters

The recent evolution of the Internet towards "Information-centric" transfer modes has renewed the interest in characterizing multi-cache systems, in which requests not satisfied by a cache are forwarded to other caches. In this work, we characterize the traffic statistics of the output (miss) stream, via a simple but…

Advanced Data Storage TechnologiesCaching and Content DeliveryCovalent Organic Framework Applications

Calculation and Analysis of Can Losses of Canned Induction Motor

Yanping Liang、Yonglu Hu、Xin Liu 等 4 位作者2014-03-21IEEE Transactions on Industrial Electronics

The canned induction motors are widely used in pharmaceutical, chemical, and nuclear fields. It is necessary to calculate the losses, particularly the can losses, accurately. Combining steady-state ac magnetic 2-D finite-element solutions with the can harmonic loss formulas derived in this paper, the can losses under…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Poly[diammonium [diaqua(μ7-benzene-1,2,3,4,5,6-hexacarboxylato)tetraoxidodiuranium(VI)]]

Paula M. Cantos、Christopher L. Cahill2014-03-21Acta Crystallographica Section E Structure Reports Online

Uranyl-carboxyl-ate hybrid materials dominate the catalog of uranyl compounds owing in part to the affinity between COO(-) functional groups and UO2 (2+). Polycarboxyl-ate organic ligands may present a degree of steric hindrance and could thus influence the resulting uranyl topology. Single crystals of the title compo…

Metal-Organic Frameworks: Synthesis and ApplicationsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Observations of thermally excited ferromagnetic resonance on spin torque oscillators having a perpendicularly magnetized free layer

Shingo Tamaru、Hitoshi Kubota、Kay Yakushiji 等 12 位作者2014-03-21Journal of Applied Physics

Measurements of thermally excited ferromagnetic resonance were performed on spin torque oscillators having a perpendicularly magnetized free layer and in-plane magnetized reference layer (abbreviated as PMF-STO in the following) for the purpose of obtaining magnetic properties in the PMF-STO structure. The measured sp…

Magnetic properties of thin filmsQuantum and electron transport phenomenaMagnetic Properties and Applications

Concentration Evolution of the Dielectric Response of Hydrogen-Bonded Supramolecular Polymers Formed by Dialkylurea in Non-Polar Medium

Jolanta Świergiel、Laurent Bouteiller、Jan Jadżyn2014-03-21Macromolecules

Theoretical predictions on the dielectric response of different dynamic models of supramolecular chain polymers [ J. Chem. Phys. 2006, 125, 184905], have been experimentally verified for the strongly hydrogen-bonded linear polymers formed by N, N ′-di(2-ethylhexyl)urea (EHU), R·NH·CO·NH·R, R = CH 2 CH(C 4 H 9 )C 2 H 5…

Supramolecular Chemistry and ComplexesCrystallography and molecular interactionsSynthesis and properties of polymers

Cytocompatibility and osteogenesis evaluation of HA/GCPU composite as scaffolds for bone tissue engineering

Jingjing Du、Qin Zou、Yi Zuo 等 4 位作者2014-03-21International Journal of Surgery

Porous scaffolds for bone repair were prepared from newly designed segmented aliphatic polyurethane based on glyceride of castor oil and isophorone diisocyanate. To promote the scaffolds' biological and mechanical properties, hydroxyapatite powder was incorporated into the polymer matrix. The scaffold (named as HA/GCP…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsGraphene and Nanomaterials Applications

Evaluation of the thickness and roughness of homogeneous surface layers on spherical and irregular powder particles

Christos Oikonomou、D. Nikas、Eduard Hryha 等 4 位作者2014-03-21Surface and Interface Analysis

The present study describes the development of a theoretical model for estimating the thickness of homogeneous surface layers on spherical and irregular shaped powder particles using the XPS depth profiling. As opposed to flat surfaces, such an approach for substrates of specific geometry is not straightforward. One n…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesSurface Roughness and Optical Measurements

Anion Coordination Interactions in Solvates with the Lithium Salts LiDCTA and LiTDI

Dennis W. McOwen、Samuel A. Delp、Elie Paillard 等 8 位作者2014-03-21The Journal of Physical Chemistry C

Lithium 4,5-dicyano-1,2,3-triazolate (LiDCTA) and lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI) are two salts proposed for lithium battery electrolyte applications, but little is known about the manner in which the DCTA – and TDI – anions coordinate Li + cations. To explore this in depth, crystal structures a…

Advanced Battery Materials and TechnologiesIonic liquids properties and applicationsSolid-state spectroscopy and crystallography

Environmental degradation of advanced and traditional engineering materials

作者信息未提供2014-03-21Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

"Environmental degradation of advanced and traditional engineering materials." Corrosion Engineering, Science and Technology, 49(3), p. 167

Material Properties and Applications

Effects of calcium phosphate composition in sputter coatings onin vitroandin vivoperformance

Eva R. Urquia Edreira、Joop G.C. Wolke、Abdullah AlFarraj Aldosari 等 7 位作者2014-03-21Journal of Biomedical Materials Research Part A

Calcium phosphate (CaP) ceramic coatings have been used to enhance the biocompatibility and osteoconductive properties of metallic implants. The chemical composition of these ceramic coatings is an important parameter, which can influence the final bone performance of the implant. In this study, the effect of phase co…

Bone Tissue Engineering MaterialsOrthopaedic implants and arthroplastyTitanium Alloys Microstructure and Properties

Controlling temperature in magnetic hyperthermia with low Curie temperature particles

Iordana Aştefãnoaei、Ioan Dumitru、H. Chiriac 等 4 位作者2014-03-21Journal of Applied Physics

Hyperthermia induced by the heating of magnetic particles (MPs) in alternating magnetic field receives a considerable attention in cancer therapy. An interesting development in the studies dedicated to magnetically based hyperthermia is the possibility to control the temperature using MPs with selective magnetic absor…

Nanoparticle-Based Drug DeliveryMicrofluidic and Bio-sensing TechnologiesCharacterization and Applications of Magnetic Nanoparticles

Synthesis of a Water‐Soluble Conjugated Polymer Based on Thiophene for an Aqueous‐Processed Hybrid Photovoltaic and Photodetector Device

Haotong Wei、Gan Jin、Lei Wang 等 12 位作者2014-03-21Advanced Materials

A water-soluble polymer (PWTV) is synthesized and applied to aqueous-processed hybrid solar cells and photodetectors. PWTV can supply an effective secondary bond to the CdTe colloidal quantum dots. The hybrid PWTV:CdTe material exhibits excellent photoelectric properties, and the devices have a power conversion effici…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Loss-of-stability induced progressive collapse modes in 3D steel moment frames

Simos Gerasimidis、George Deodatis、Thalia Kontoroupi 等 4 位作者2014-03-21Structure and Infrastructure Engineering

This paper deals with the progressive collapse analysis of a tall steel frame following the removal of a corner column according to the alternate load path approach. Several analysis techniques are considered (eigenvalue, material nonlinearities, material and geometric nonlinearities), as well as 2D and 3D modelling o…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsFire effects on concrete materials

Fuel cycle modelling of open cycle thorium-fuelled nuclear energy systems

S. F. Ashley、Ben Lindley、Geoffrey T. Parks 等 12 位作者2014-03-21Annals of Nuclear Energy

In this study, we have sought to determine the advantages, disadvantages, and viability of open cycle thorium–uranium-fuelled (Th–U-fuelled) nuclear energy systems. This has been done by assessing three such systems, each of which requires uranium enriched to ∼20% 235U, in comparison to a reference uranium-fuelled (U-…

Nuclear reactor physics and engineeringRadioactive element chemistry and processingNuclear Materials and Properties

Effect of ethanol-water mixture on the structure and dynamics of lysozyme: A fluorescence correlation spectroscopy study

Shyamtanu Chattoraj、Amit Kumar Mandal、Kankan Bhattacharyya2014-03-21The Journal of Chemical Physics

Effect of ethanol-water mixture on the hydrodynamic radius (r(H)) and conformational dynamics of lysozyme has been studied by circular dichroism, emission spectra, and fluorescence correlation spectroscopy. For this purpose, the protein lysozyme is covalently labeled near the active site with a fluorescent probe, alex…

Protein Structure and DynamicsEnzyme Structure and FunctionProtein Interaction Studies and Fluorescence Analysis

Generation of optical vortices by using spiral phase plates made of polarization dependent devices

Jingtao Xin、Kunjian Dai、Lei Zhong 等 5 位作者2014-03-21Optics Letters

A method to construct spiral phase plates (SPPs) from quarter-wave plates and spatially variable half-wave plates (SVHWPs) is proposed. Optical vortices were experimentally generated by using SPPs made of polarization-dependent devices. The topological charge of the optical vortex can be also determined by the structu…

Metamaterials and Metasurfaces ApplicationsOrbital Angular Momentum in OpticsNear-Field Optical Microscopy

Formation of Hydroxyl Groups at Calcium-Silicate-Hydrate (C-S-H): Coexistence of Ca–OH and Si–OH on Wollastonite(001)

Simone Sanna、W. G. Schmidt、Peter Thissen2014-03-21The Journal of Physical Chemistry C

Total-energy calculations based on density-functional theory are combined with ab initio thermodynamics to better understand the pH-value-dependent water–wollastonite(001) (CaSiO 3 ) interaction. The truncation of wollastonite(001) is found to lead to nearly negligible ionic relaxation with respect to the bulk geometr…

Calcium Carbonate Crystallization and InhibitionClay minerals and soil interactionsIron oxide chemistry and applications