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Deconvoluting the Mechanism of Microwave Annealing of Block Copolymer Thin Films

Cong Jin、Jeffrey N. Murphy、Kenneth D. Harris 等 4 位作者2014-03-21ACS Nano

The self-assembly of block copolymer (BCP) thin films is a versatile method for producing periodic nanoscale patterns with a variety of shapes. The key to attaining a desired pattern or structure is the annealing step undertaken to facilitate the reorganization of nanoscale phase-segregated domains of the BCP on a sur…

Block Copolymer Self-AssemblyFluid Dynamics and Thin FilmsAnodic Oxide Films and Nanostructures

Influence of sterilisation methods on collagen-based devices stability and properties

Luis M. Delgado、Abhay Pandit、Dimitrios I. Zeugolis2014-03-21Expert Review of Medical Devices

Sterilisation is essential for any implantable medical device in order to prevent infection in patients. The selection of the most appropriate sterilisation method depends on the nature and the physical state of the material to be sterilised; the influence of the sterilisation method on the properties of the device; a…

Bone Tissue Engineering MaterialsAdditive Manufacturing and 3D Printing TechnologiesCollagen: Extraction and Characterization

Exciton Drift in Semiconductors under Uniform Strain Gradients: Application to Bent ZnO Microwires

Xuewen Fu、Gwénolé Jacopin、Mehran Shahmohammadi 等 11 位作者2014-03-21ACS Nano

Optimizing the electronic structures and carrier dynamics in semiconductors at atomic scale is an essential issue for innovative device applications. Besides the traditional chemical doping and the use of homo/heterostructures, elastic strain has been proposed as a promising possibility. Here, we report on the direct…

ZnO doping and propertiesAdvanced Sensor and Energy Harvesting MaterialsNanowire Synthesis and Applications

Explosives detection by fluorescence quenching of conjugated polymers in suspended core optical fibers

Fenghong Chu、Georgios Tsiminis、Nigel A. Spooner 等 4 位作者2014-03-21Sensors and Actuators B Chemical

In this work we demonstrate a suspended core microstructured optical fiber-based sensor platform for explosives detection based on the fluorescence quenching of a surface-attached conjugated polymer poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV). These fibers allow for strong evanescent field inte…

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Growth mechanisms of MgO nanocrystals via a sol-gel synthesis using different complexing agents

Mohd Sufri Mastuli、Norlıda Kamarulzaman、Mohd Azizi Nawawi 等 6 位作者2014-03-21Nanoscale Research Letters

In the preparation of nanostructured materials, it is important to optimize synthesis parameters in order to obtain the desired material. This work investigates the role of complexing agents, oxalic acid and tartaric acid, in the production of MgO nanocrystals. Results from simultaneous thermogravimetric analysis (STA…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionMagnesium Oxide Properties and Applications

Short-Bite PNP Ligand-Supported Rare Tetranuclear [Cu4I4] Clusters: Structural and Photoluminescence Studies

Susmita Naik、Joel T. Mague、Maravanji S. Balakrishna2014-03-21Inorganic Chemistry

The group 11 metal complexes of two short-bite PNP ligands, C6H5N{P(OC6H3(OMe-o)(C3H5-p))2}2 (1) and C6H5N{P(OC6H4C3H5-o)2}2 (2), are described. Ligands 1 and 2 on treatment with copper(I) halides (CuX, X = Cl, Br, or I) yielded dimeric, tetranuclear complexes of the type [(CuX)4{C6H5N(PR2)2}] (R = OC6H3(OMe-o)(C3H5-p…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesNanocluster Synthesis and Applications

Synthesis of polythiophene/graphene oxide composites by interfacial polymerization and evaluation of their electrical and electrochemical properties

Chandramika Bora、Rupa Pegu、Bhaskar Jyoti Saikia 等 4 位作者2014-03-21Polymer International

Abstract We report a new method for the synthesis of polythiophene (PTh)/graphene oxide (GO) nanocomposites by interfacial polymerization. Polymerization occurred at the interface of two immiscible solvents, i.e. n‐hexane containing thiophene and nitromethane containing GO and an initiator. Characterizations were done…

Organic Electronics and PhotovoltaicsSupercapacitor Materials and FabricationConducting polymers and applications

Dielectric behaviors of carbon nanotube/silicone elastomer composites

Hongyan Li、Hongli Liu、Junwei Li 等 6 位作者2014-03-21Science and Engineering of Composite Materials

Abstract Carbon nanotubes (CNTs) with different aspect ratios were modified by a silane coupling agent. The modified CNTs were embedded into a silicone elastomer (SE) matrix to obtain the composites. The dielectric behaviors of the composites with different frequencies of outer electric field were investigated. The re…

Advanced Sensor and Energy Harvesting MaterialsElectromagnetic wave absorption materialsDielectric materials and actuators

Triticale straw and its thermoplastic biocomposites

Tri-Dung Ngo、Minh‐Tan Ton‐That、Wei Hu2014-03-21Science and Engineering of Composite Materials

Abstract The potential of triticale straw for the production of green composites based on polypropylene (PP) was evaluated. The composites were prepared by melt compounding of PP and chopped triticale straw (so-called triticale particles) using different formulations and triticale concentrations. The morphology and cr…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Heat exchangers made of polymer-bonded La(Fe,Si)13

Konstantin Skokov、D. Karpenkov、M. D. Kuz’min 等 8 位作者2014-03-21Journal of Applied Physics

We report on magnetocaloric properties of polymer-bonded La(Fe,Si)13 heat exchangers with respect to the grain size of the powder used and the pressure applied for compaction of plates. Quite remarkably, it was found that the values of the adiabatic temperature change of polymer-bonded plates are 10% higher than in th…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsMagnetic Properties of Alloys

Nanodiamond-Based Thermal Fluids

Jaime Taha‐Tijerina、Tharangattu Narayanan Narayanan、Chandra Sekhar Tiwary 等 6 位作者2014-03-21ACS Applied Materials & Interfaces

Dispersions of nanodiamond (average size ∼6 nm) within dielectric insulator mineral oil are reported for their enhanced thermal conductivity properties and potential applications in thermal management. Dynamic and kinematic viscosities-very important parameters in thermal management by nanofluids-are investigated. The…

Nanofluid Flow and Heat TransferPhase Equilibria and ThermodynamicsDiamond and Carbon-based Materials Research

Carbon Nanotube Circuit Integration up to Sub-20 nm Channel Lengths

Max M. Shulaker、Jelle Van Rethy、Tony F. Wu 等 10 位作者2014-03-21ACS Nano

Carbon nanotube (CNT) field-effect transistors (CNFETs) are a promising emerging technology projected to achieve over an order of magnitude improvement in energy-delay product, a metric of performance and energy efficiency, compared to silicon-based circuits. However, due to substantial imperfections inherent with CNT…

Carbon Nanotubes in CompositesAnalog and Mixed-Signal Circuit DesignMechanical and Optical Resonators

Ab initio calculations of SrTiO 3, BaTiO 3, PbTiO 3, CaTiO 3, SrZrO 3, PbZrO 3 and BaZrO 3 (001), (011) and (111) surfaces as well as F centers, polarons, KTN solid solutions and Nb impurities therein

R. I. Eglitis2014-03-21International Journal of Modern Physics B

In this paper, the review of recent results of calculations of surface relaxations, energetics, and bonding properties for ABO 3 perovskite (001), (011) and (111) surfaces using mostly a hybrid description of exchange and correlation is presented. Both AO and BO 2-terminations of the nonpolar (001) surface and A , BO…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

GLOBAL AND NONGLOBAL PARAMETERS OF HORIZONTAL-BRANCH MORPHOLOGY OF GLOBULAR CLUSTERS

A. P. Milone、A. F. Marino、A. Dotter 等 13 位作者2014-03-21The Astrophysical Journal

The horizontal-branch (HB) morphology of globular clusters (GCs) is mainly determined by metallicity. However, the fact that GCs with almost the same metallicity exhibit different HB morphologies demonstrates that at least one more parameter is needed to explain the HB morphology. It has been suggested that one of the…

Crystal Structures and PropertiesMineralogy and Gemology StudiesMetallurgical and Alloy Processes

Zinc Induced a Dramatic Enhancement of the Nonlinear Optical Properties of an Azo-Based Iminopyridine Ligand

Imen Guezguez、Awatef Ayadi、Karolina Ordon 等 9 位作者2014-03-21The Journal of Physical Chemistry C

An azobenzene based iminopyridine ligand 1 has been synthesized by a condensation reaction between N,N -dimethyl-4,4′-azodianiline and 2-formylpyridine. The complexation of the ligand with ZnCl 2 afforded a tetrahedral neutral zinc metal complex ( 2 ) formulated as [(Azo-Imino-Py)ZnCl 2 ]. The crystal structure analys…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryNonlinear Optical Materials Research

Quantum Electrodynamical Density-Functional Theory: Bridging Quantum Optics and Electronic-Structure Theory

Michael Ruggenthaler、Johannes Flick、Camilla Pellegrini 等 6 位作者2014-03-21arXiv

In this work we give a comprehensive derivation of an exact and numerically feasible method to perform ab-initio calculations of quantum particles interacting with a quantized electromagnetic field. We present a hierachy of density-functional-type theories that describe the interaction of charged particles with photon…

Materials Sciencephysics.optics

Flexible Teflon Nanocone Array Surfaces with Tunable Superhydrophobicity for Self-Cleaning and Aqueous Droplet Patterning

Mana Toma、Gabriel Loget、Robert M. Corn2014-03-21ACS Applied Materials & Interfaces

Tunable hydrophobic/hydrophilic flexible Teflon nanocone array surfaces were fabricated over large areas (cm(2)) by a simple two-step method involving the oxygen plasma etching of a colloidal monolayer of polystyrene beads on a Teflon film. The wettability of the nanocone array surfaces was controlled by the nanocone…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPolymer Surface Interaction Studies

A Three-Step Model for Protein–Gold Nanoparticle Adsorption

Ailin Wang、Karthikeshwar Vangala、Tam Vo 等 5 位作者2014-03-21The Journal of Physical Chemistry C

Gold nanoparticles (AuNPs) are an attractive delivery vector in biomedicine because of their low toxicity and unique electronic and chemical properties. AuNP bioconjugates can be used in many applications, including nanomaterials, biosensing, and drug delivery. While the phenomenon of spontaneous protein–AuNP adsorpti…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesProtein Interaction Studies and Fluorescence Analysis

New Perovskite-Related Structure Family of Oxide-Ion Conducting Materials NdBaInO4

Kotaro Fujii、Yuichi Esaki、Kazuki Omoto 等 7 位作者2014-03-21Chemistry of Materials

Oxide-ion conducting ceramic materials, which include\npure oxide-ion conductors and mixed oxide-ion and\nelectronic or hole conductors, have received considerable\nattention because of their potential application for oxygen\nseparation membranes, oxygen sensors, and solid oxide fuel\ncells (SOFCs) electrolytes and ca…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Dislocations mediate hydrogen retention in tungsten

D. Terentyev、V.I. Dubinko、A. Bakaev 等 6 位作者2014-03-21Nuclear Fusion

In this letter, a comprehensive mechanism for the nucleation and growth of bubbles on dislocations under plasma exposure of tungsten is proposed. The mechanism reconciles long-standing experimental observations of hydrogen isotopes retention, essentially defined by material microstructure, and so far not fully explain…

Metal and Thin Film MechanicsFusion materials and technologiesAdvanced materials and composites