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Detecting Selection on Protein Stability through Statistical Mechanical Models of Folding and Evolution

Ugo Bastolla2014-03-07Biomolecules

The properties of biomolecules depend both on physics and on the evolutionary process that formed them. These two points of view produce a powerful synergism. Physics sets the stage and the constraints that molecular evolution has to obey, and evolutionary theory helps in rationalizing the physical properties of biomo…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

High-Performance Inverted Solar Cells Based on Blend Films of ZnO Naoparticles and TiO2 Nanorods as a Cathode Buffer Layer

Pandeng Li、Chunming Sun、Tonggang Jiu 等 7 位作者2014-03-07ACS Applied Materials & Interfaces

We reported the favorable cathode buffer layer based on a blend of ZnO nanoparticles (NPs) and TiO2 nanorods (NRs) applied to inverted solar cells. In addition to the high optical transmittance, the resultant blend film gave a relatively dense film with lower roughness than that of the respective single-component film…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Linear or Cyclic Clusters of Cu(II) with a Hierarchical Relationship

Gavin A. Craig、Mike Schütze、David Aguilà 等 8 位作者2014-03-07Inorganic Chemistry

The polydentate ligand 2,6-bis(5-(2-hydroxyphenyl)-pyrazol-3-yl)-pyridine, H4L, exhibits a series of coordination pockets favoring the establishment of metal sequences with predetermined motifs, together with a degree of flexibility for the formation of clusters with various overall topologies. With Cu(II) under stron…

Metal complexes synthesis and propertiesMagnetism in coordination complexesNanocluster Synthesis and Applications

Double‐layer channel structure based ZnO thin‐film transistor grown by atomic layer deposition

Cheol Hyoun Ahn、Sohee Kim、Sung Woon Cho 等 5 位作者2014-03-07physica status solidi (RRL) - Rapid Research Letters

Abstract A double channel structure has been used by depositing a thin amorphous‐AlZnO (a‐AZO) layer grown by atomic layer deposition between a ZnO channel and a gate dielectric to enhance the electrical stability. The effect of the a‐AZO layer on the electrical stability of a‐AZO/ZnO thin‐film transistors (TFTs) has…

ZnO doping and propertiesSemiconductor materials and devicesThin-Film Transistor Technologies

Impact resistance of hygrothermally conditioned composite laminates with different lay-ups

Yucheng Zhong、Sunil C. Joshi2014-03-07Journal of Composite Materials

Low-velocity impact testing was conducted on carbon/epoxy composite laminates exposed to hygrothermal environments. Besides normal laminates, staggered lay-up structures were made from unidirectional prepreg materials. The specimens were immersed in water at 80℃ for different durations before impact testing. Experimen…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Radiosensitization of malignant gliomas following intracranial delivery of paclitaxel biodegradable polymer microspheres

Patrik Gabikian、Betty Tyler、Irma Zhang 等 6 位作者2014-03-07Journal of neurosurgery

OBJECT: The aim of this study was to demonstrate that paclitaxel could function as a radiosensitizer for malignant glioma in vitro and in vivo. METHODS: The radiosensitizing effect of paclitaxel was tested in vitro using the human U373MG and rat 9L glioma cell lines. Cell cycle arrest in response to paclitaxel exposur…

Nanoparticle-Based Drug DeliveryGlioma Diagnosis and TreatmentBrain Metastases and Treatment

The Thin Film Equation with Non-Zero Contact Angle: A Singular Perturbation Approach

Antoine Mellet2014-03-07Communications in Partial Differential Equations

In this paper we consider the thin film equation with prescribed non-zero contact angle condition for a large class of mobility coefficients, in dimension 1. We prove the global in time existence of weak solutions by using a diffuse approximation of the free boundary condition. This approach, which can be physically m…

Theoretical and Computational PhysicsSolidification and crystal growth phenomenaFluid Dynamics and Thin Films

Microstructure and Texture of Strip Cast Grain-Oriented Silicon Steel after Symmetrical and Asymmetrical Hot Rolling

Hong‐Yu Song、Hui‐Hu Lu、Haitao Liu 等 8 位作者2014-03-07steel research international

A grain-oriented silicon steel as-cast strip was produced by twin-roll strip casting. Then the as-cast strip was symmetrically and asymmetrically hot rolled, respectively. The microstructure and texture evolution was investigated by a combination of optical microscopy, X-ray diffraction, and electron backscattered dif…

Microstructure and Mechanical Properties of SteelsAluminum Alloy Microstructure PropertiesMagnetic Properties and Applications

Insight into the Tunable CuY Catalyst for Diethyl Carbonate by Oxycarbonylation: Preparation Methods and Precursors

Shouying Huang、Jijie Zhang、Yue Wang 等 6 位作者2014-03-07Industrial & Engineering Chemistry Research

Three different methods were used to prepare CuY catalysts, which play an important role in Cu loading and ion-exchange level during the oxidative carbonylation of ethanol to synthesize diethyl carbonate. Of the prepared CuY catalysts, those synthesized by the ammonia evaporation method exhibited a significantly enhan…

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceCarbon dioxide utilization in catalysis

The phase diagram of the square lattice bilayer Hubbard model: a variational Monte Carlo study

Robert Rüger、Luca F Tocchio、Roser Valentí 等 4 位作者2014-03-07New Journal of Physics

We investigate the phase diagram of the square lattice bilayer Hubbard model at half-filling with the variational Monte Carlo method for both the magnetic and the paramagnetic case as a function of the interlayer hopping and on-site Coulomb repulsion U . With this study we resolve some discrepancies in previous calcul…

Physics of Superconductivity and MagnetismTopological Materials and PhenomenaIron-based superconductors research

Photo-switching effect in stilbene organic field effect transistors

Hamidreza Karimi–Alavijeh、Farhad Panahi、Alireza Gharavi2014-03-07Journal of Applied Physics

In this paper, we have investigated experimentally the photo-response of the organic field effect transistors (OFETs) based on π-conjugated stilbene oligomers with mutual optical and electrical properties. The cis-trans photoisomerization of these oligomers in the active layer of the OFETs disturbs the intermolecular…

Organic Electronics and PhotovoltaicsAdvanced Memory and Neural ComputingConducting polymers and applications

Dynamic New World: Refining Our View of Protein Structure, Function and Evolution

Ranjan V. Mannige2014-03-07Proteomes

Proteins are crucial to the functioning of all lifeforms. Traditional understanding posits that a single protein occupies a single structure ("fold"), which performs a single function. This view is radically challenged with the recognition that high structural dynamism-the capacity to be extra "floppy"-is more prevale…

Protein Structure and DynamicsMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function

Evaluation of nanogels as supports for enzyme immobilization

Ghanshyam S. Chauhan2014-03-07Polymer International

Abstract Nanogels are hydrophilic polymers made up of crosslinked nano‐sized particles. These nanogels have large surface area that offers several functional groups as reserves for binding drugs, generating biosensors and as supports for enzyme immobilization. This mini‐review is an attempt to evaluate the recent deve…

Nanoparticle-Based Drug DeliveryElectrochemical sensors and biosensorsEnzyme Catalysis and Immobilization

Crystal Structure Elucidation and Anticancer Studies of (-)-Pseudosemiglabrin: A Flavanone Isolated from the Aerial Parts of Tephrosia apollinea

Loiy Elsir Ahmed Hassan、Mohamed B. Khadeer Ahamed、Aman Shah Abdul Majid 等 11 位作者2014-03-07PLoS ONE

Tephrosia apollinea is a perennial shrublet widely distributed in Africa and is known to have medicinal properties. The current study describes the bio-assay (cytotoxicity) guided isolation of (-)-pseudosemiglabrin from the aerial parts of T. apollinea. The structural and stereochemical features have been described us…

Natural product bioactivities and synthesisBioactive natural compoundsPhytochemistry and Bioactive Compounds

1,2,3‐triazole crosslinked polymers as binders for solid rocket propellants

Donghoon Lee、Kyoung‐Tae Kim、Yujin Jang 等 8 位作者2014-03-07Journal of Applied Polymer Science

ABSTRACT In this study, 1,2,3‐triazole crosslinked polymers were synthesized as a new binder for solid rocket propellant systems by reacting the azide groups of the polymer with the ethynyl groups of a dipolarophile curing agent. All the mixtures were cured in an oven at 52°C for 7 days, and the curing reactivity of t…

Click Chemistry and ApplicationsSynthesis and properties of polymersSynthesis and Characterization of Heterocyclic Compounds

Comparison of Thermal Neutron Flux Measured by $^{235}{\rm U}$ Fission Chamber and Rhodium Self-Powered Neutron Detector in MTR

D. Fourmentel、P. Filliatre、L. Barbot 等 9 位作者2014-03-07IEEE Transactions on Nuclear Science

Thermal neutron flux is one of the most important nuclear parameter to be measured online in material testing reactors (MTRs). In particular two types of sensors with different physical operating principles are commonly used: self-powered neutron detectors (SPND) and fission chambers with coating. This work aims to co…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Physics and Applications

Effects of electric field on thermal and tunneling carrier escape in InAs/GaAs quantum dot solar cells

Yushuai Dai、Stephen J. Polly、Staffan Hellström 等 8 位作者2014-03-07Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

The effects of electric field on carrier escape in InAs/GaAs quantum dots embedded in a p-i-n solar cell structures have been studied by quantum efficiency. Via band structure simulation, effective barrier height of carriers inside QDs is reduced with increasing local electric field, so tunneling and thermal escape ar…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesSemiconductor materials and interfaces

Intensive Interaction Region during Co-pyrolysis of Lignin and Cellulose: Experimental Observation and Kinetic Assessment

Shiliang Wu、Dekui Shen、Jun Hu 等 5 位作者2014-03-07BioResources

Interactions between biomass constituents (cellulose, hemicelluloses, and lignin) under pyrolytic conditions have received more and more attention in recent years. A synthesized sample was prepared through mixing of cellulose and lignin with a mass:mass ratio of 1:1. The cellulose-lignin mixture (C-L-M) was heated fro…

Thermochemical Biomass Conversion ProcessesLignin and Wood ChemistryThermal and Kinetic Analysis

pH effects on shear thickening behaviors of polystyrene-ethylacrylate colloidal dispersions

Chen Qian、Wei Zhu、Fang Ye 等 6 位作者2014-03-07Materials Research Express

In this study, the effects of pH on shear thickening behaviors were investigated based on concentrated dispersions consisting of polystyrene-ethylacrylate (PSt-EA) copolymer nanospheres. The pH values of the above shear thickening fluids were controlled by adding different kinds of acid and alkali solutions, and the r…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsRheology and Fluid Dynamics Studies

The role of endoglucanase and endoxylanase in liquefaction of hydrothermally pretreated wheat straw

Pernille Anastasia Skovgaard、Lisbeth Garbrecht Thygesen、Henning Jørgensen 等 8 位作者2014-03-07Biotechnology Progress

The role of endocellulases and endoxylanase during liquefaction and saccharification of hydrothermally pretreated wheat straw was studied. The use of a flow-loop setup with in-line magnetic resonance imaging enabled frequent measurements of viscosity at 55°C during saccharification at 6% total solids content. Viscosit…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesEnzyme Production and Characterization