Materials Literature
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The Debye temperature, T_D, of sigma-phase Fe_(100-x)Mo_x compounds with 47 < x < 56.7 was determined from the temperature dependence of the centre shift of Mössbauer spectra recorded in the temperature range of 80 - 300 K. Its compositional dependence shows a weak increase with x whose rate, in a linear approximation…
Superlubricity is a frictionless tribological state sometimes occurring in nanoscale material junctions. It is often associated with incommensurate surface lattice structures appearing at the interface. Here, by using the recently introduced registry index concept which quantifies the registry mismatch in layered mate…
We report on room temperature low frequency noise due to magnetic inhomogeneities/domain walls (MI/DWs) in elliptic submicron FeCoB/MgO/FeCoB magnetic tunnel junctions with an area between 0.0245 and 0.0675μm2. In the smaller area junctions we found an unexpected random telegraph noise (RTN1), deeply in the parallel s…
Epitaxially grown, high quality semiconductor InSb nanowires are emerging material systems for the development of high performance nanoelectronics and quantum information processing and communication devices, and for the studies of new physical phenomena in solid state systems. Here, we report on measurements of a sup…
Using extensive tight-binding calculations, we investigate (including the spin) the Aharonov-Bohm (AB) effect in monolayer and bilayer trigonal and hexagonal graphene rings with zigzag boundary conditions. Unlike the previous literature, we demonstrate the universality of integer ($hc/e$) and half-integer ($hc/2e$) va…
We investigate the modulational instability and time-domain dynamics of nonlinear magnetic metamaterials composed of coupled split-ring resonators loaded by Kerr nonlinearity. Our results indicate that the recently proposed optical switching of local optical index based on uniform-response assumption seems fragile. We…
Fermi and kinetic energy are usually calculated in periodic boundary conditions model, which is not self-consistent for low-dimensional problems, where particles are confined. Thus for confined particles the potential box model was used self-consistently to calculate Fermi and kinetic energies in 3-, 2-, and 1-dimensi…
Water-dispersible CdS quantum dots (QDs) emitting from 510 to 650 nm were synthesized in a simple one-pot noninjection hydrothermal route using cadmium chloride, thiourea, and 3-mercaptopropionic acid (MPA) as starting materials. All these chemicals were loaded at room temperature in a Teflon sealed tube and the react…
This is the first report of using anatase TiO(2) nanosheets with exposed (001) facets in a high-efficiency PbS quantum dot/TiO(2) heterojunction solar cell. The TiO(2) nanosheets have higher conduction band, and surface energy compared to normal anatase (101) TiO(2) nanoparticles. This PbS QD/TiO(2) heterojunction sol…
Pd nanocrystals were prepared by the reduction of a H(2)PdCl(4) aqueous solution with C(2)H(4) in the presence of different amounts of poly(N-vinyl-2-pyrrolidone) (PVP). Their average size decreases monotonically as the PVP monomer/Pd molar ratio increases up to 1.0 and then does not vary much at higher PVP monomer/Pd…
Three porous luminescent covalent--organic polymers (COPs) have been synthesized through self-polycondensation of the monomers of tris(4-bromophenyl)amine, 1,3,5-tris(4-bromophenyl)benzene, and 2,4,6-tris-(4-bromo-phenyl)-[1,3,5]triazine by using Ni-catalyzed Yamamoto reaction. All the COP materials possess not only h…
Insect chitin was isolated from adult Holotrichia parallela by treatment with 1 M HCl and 1 M NaOH, following by 1% potassium permanganate solution for decolorization. The yield of chitin from this species is 15%. This insect chitin was compared with the commercial a-chitin from shrimp, by infrared spectroscopy, X-ray…
We report bandlike transport in solution-deposited, CdSe QD thin-films with room temperature field-effect mobilities for electrons of 27 cm(2)/(V s). A concomitant shift and broadening in the QD solid optical absorption compared to that of dispersed samples is consistent with electron delocalization and measured elect…
Carbon nanofibers prepared via electrospinning and following carbonization are summarized by focusing on the structure and properties in relation to their applications, after a brief review of electrospinning of some polymers. Carbon precursors, pore structure control, improvement in electrical conductivity,and metal…
Abstract We herein report a straightforward soot‐based synthesis and characterization of the negatively charged, hydrophilic, photoluminescent nanocarbon. The photoluminescent nanocarbon was prepared by refluxing castor oil soot in nitric acid. The as‐obtained fluorescent nanocarbon shows multiple colors under UV expo…
Dynamics of hole storage in spherical Ge nanocrystals (NCs) formed by a two step dewetting/nucleation process on an oxide layer grown on an n-doped 〈001〉 silicon substrate is studied using a nano-electron beam induced current technique. Carrier generation is produced by an electron beam irradiation. The generated curr…
In the present study, structural properties of Mono-(2-Pyridyl) Hydrazone were studied extensively utilizing density functional theory (DFT) employing B3LYP exchange correlation. The Fourier transform infrared (solid phase) was recorded. The vibrational frequencies in the ground state were calculated by using density…
Three rare compounds have been synthesized and structurally characterized; these species have paddlewheel structures and Re(2)(7+) cores surrounded by four bicyclic guanidinates and two axial ligands along the Re-Re axis. Each possesses a formal bond order of 3.5 and a σ(2)π(4)δ(1) electronic configuration that entail…
The presence of silicate during barium sulfate crystallization has different impacts depending on the pH of the solution. At pH 7 the dominance of the protonated form (H 4 SiO 4 ) and possible polymerization of the silicate impacts mainly on the aggregation state and on twinning of the barium sulfate formed. At higher…
Zinc sulfide nanoparticles were fabricated by solvent evaporation method with and without using capping agent, Hexa decyltrimethyl ammonium bromide (CTAB) at room temperature. The product was received in powder form. The structure and composition of the resultant product was characterized by means of UV and FTIR spect…