Materials Literature
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Abstract Während catena‐Phosphorkationen innerhalb der letzten Jahre intensiv untersucht wurden, gab es über gemischte kationische Ketten aus Gruppe‐13‐ und Gruppe‐15‐Elementen bislang keine Berichte. Die Umsetzung der Pnictogenborane H2EBH2⋅NMe3 (E=P, As) mit Monohalogenboranen führt zu den kationischen Kettenverbind…
Abstract RA110 is a computationally designed retro‐aldolase enzyme that utilizes amine catalysis to convert 4‐hydroxy‐4‐(6‐methoxy‐2‐naphthyl)‐2‐butanone to 6‐methoxy‐2‐naphthaldehyde and acetone. The original design accelerated substrate cleavage by a factor of 12 000 over background, and its activity was subsequentl…
Poly(amidoamine) (PAMAM) dendrimers play an important role in drug delivery systems, because the dendrimers are susceptible to gain unique features with modification of their structure such as changing their terminals or improving their interior core. To investigate the core improvement and the effect of core nature o…
The magnetic energy harvesting properties of piezoelectric bimorph/magnet composite are studied in this Letter. The devices are fabricated with NdFeB magnets and piezofiber (d33 mode), whose magnetoelectric (ME) coefficient reaches 526 V/cm·Oe (RMS) at the resonant frequency (27.3 Hz), and the maximum power density of…
Ru-aqua complex {[Ru(II)(trpy)(H2O)]2(μ-pyr-dc)}(+) is a powerful epoxidation catalyst for a wide range of linear and cyclic alkenes. High turnover numbers (TNs), up to 17000, and turnover frequencies (TOF), up to 24120 h(-1) (6.7 s(-1)), have been obtained using PhIO as oxidant. This species presents an outstanding s…
We have studied the correlation between the broadening of the isothermal magnetic entropy change and the Curie temperature (TC) distribution in nanostructured Pr2Fe17 and Nd2Fe17 alloys produced by high-energy ball-milling after milling times of 10, 20, and 40 h. The changes in the microstructure affect the Fe local e…
Laser irradiation of randomly oriented multi-walled carbon nanotube (MWCNT) networks has been carried out using a pulsed Nd:YAG UV laser in nitrogen gas environment. The evolution of the MWCNT morphology and structure as a function of laser fluence and number of accumulated laser pulses has been studied using electron…
Abstract A novel, simple, and efficient method for the preparation of the fluorinated hexagonal boron nitride nanosheets (F‐BNNSs) and the corresponding magnetic properties is presented. A one‐step route is used to exfoliate and fluorinate the BNNSs by ammonium fluoride (NH4F) from hexagonal boron nitride (h‐BN) powde…
The increasing morbidity and mortality of infectious diseases is an increasing concern. Despite the continuous development and synthesis of new antimicrobial drugs, microbial pathogens are exhibiting increased multi-drug resistance. Nanomaterials display unique and well-defined physical and chemical properties includi…
The helical nanofilament (HNF) liquid crystal phase is an ordered architecture exhibiting interesting properties for charge transport. It is a small molecule self-assembly of stacked and twisted crystalline layers, which form alignable organic nanorods with half the surface area of the filaments consisting of aromatic…
By introducing four displacement functions, the governing equations of the three-dimensional thermoelasticity of two-dimensional hexagonal quasicrystals are decoupled into two uncorrelated problems. Two higher-order displacement functions are introduced to represent the general solutions, which are eighth-order and fo…
We report a novel full-color display based on the generation of full-color by a highly efficient blue QD-LED light approach, or so called color-by-blue QD-LED display. This newly proposed color-by-blue QD-LED display combines a blue CdZnS/ZnS QD-LED blue subpixel and excitation source with front-emitting green/red pho…
Matsuoka-type zinc oxide (ZnO) varistor material was synthesized using a conventional solid-state reaction method. X-band electron paramagnetic resonance (EPR) data revealed that Mn ions substitute in the ZnO lattice with a 2+ paramagnetic state. Co ions with either 3+ or 2+ oxidation states are only detectable at cry…
We map band-edges across a pn-junction that was formed in a nanorod. We form a single junction between p-type Cu2S and n-type CdS through a controlled cationic exchange process of CdS nanorods. We characterize nanorods of the individual materials and the single junction in a nanorod with an ultrahigh vacuum scanning t…
In this study, acrylate (ACR) copolymer was used to toughen polylactide (PLA). Dynamic mechanical analysis and differential scanning calorimetry results showed that PLA was partially miscible with ACR. Isothermal crystalline behavior indicated that the incorporation of ACR significantly prevented the crystallization o…
The ferroelectric domain depinning in a polycrystalline BiFeO3 film is studied by a defect-mediated diffusion mechanism driven by a secondary re-oxidation anneal. The presence of defect complexes (oxygen-vacancy-associated dipoles) responsible for pinning is discussed from the current-voltage (I-V) characteristics of…
Liquid-phase exfoliation of layered materials offers a large-scale approach toward the synthesis of 2D nanostructures. Structural properties of materials can however change during transition from bulk to the 2D state. Any such changes must be examined and understood for successful implementation of 2D nanostructures.…
Abstract A highly efficient solid‐base organocatalyst for the gas‐phase aldol self‐condensation of n‐butanal to 2‐ethylhexenal was developed by grafting site‐isolated amines on tailored silica surfaces. The catalytic activity depends largely on the nature of amine species, the surface concentration of amine and silano…
In the search for porphyrinoids with a built-in cyclopentadienyl moiety (true carbaporphyrins), a rational synthesis of carbathiaporphyrin, the synthons, has been elaborated. The donors (C,N,S,N) in the porphyrinic core of carbathiaporphyrinoids are potentially of fundamental importance for generating organometallic c…
Carbon materials have shown great potential in solving environmental problems resulting from the pollution from oils or organic solvents. However, developing low-cost and high-performance carbon-based three-dimensional (3D) frameworks is still a great challenge and highly desired. Herein, monolithic macroporous carbon…