Materials Literature
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Abstract Homopolyaddition reactions of AB‐type monomers containing a 2‐oxazoline and a phenol group in different positions of the phenyl ring, namely, 2‐(4‐hydroxyphenyl)‐2‐oxazoline, 2‐(3‐hydroxyphenyl)‐2‐oxazoline, 2‐(2‐hydroxyphenyl)‐2‐oxazoline, and 2‐(4‐hydroxyphenyl)‐4,4‐dimethyl‐2‐oxazoline, were studied. Excep…
ZnO thin films were deposited on semi-insulating (0 0 1) GaAs substrates at different growth conditions by metal-organic chemical vapour deposition. The effect of growth temperature and ambient oxygen partial pressure on the properties of the ZnO films was studied. It was found that these two important parameters affe…
We describe photoluminescence (PL) quenching experiments by oxygen for a series of transition metal dyes adsorbed to commercial silica thin-layer chromatography plates. These TLC plates have been used by others as rapidly responding PL pressure sensors. The quenching kinetics show interesting differences from the beha…
The room-temperature Raman spectra of single crystals of GaSe, GaS, and mixed compounds GaSe1−xSx with 0.02⩽x⩽0.8 were measured with a HeNe laser in confocal configuration. The changes in the spectra indicate changes of the crystal structure. The spectra of pure GaSe and of the mixed compound with x=0.02 show pronounc…
The ordered complex perovskite lead ytterbium tantalate undergoes a change in structural and dielectric properties as the concentration of Ba increases. The x-ray diffraction patterns show a decrease in the intensity of superlattice reflections due to Pb-antiparallel displacement as well as to B-site ordering. The str…
Photoluminescence and Raman spectra of ZnO single-crystal nanosheets have been studied as a function of applied hydrostatic pressure using the diamond-anvil-cell technique at room temperature. The ZnO nanosheets synthesized via a vapor transport process have uniform plane surfaces with lateral dimensions up to several…
Infrared and Raman spectroscopies were employed to study the temperature dependence of the optical phonons of the $\mathrm{Sr}\mathrm{Mn}{\mathrm{O}}_{3}$ manganite in both the hexagonal and the cubic phase. Changes in the phonon spectrum of the hexagonal $\mathrm{Sr}\mathrm{Mn}{\mathrm{O}}_{3}$ (four-layer structure)…
Abstract Using a low‐melting‐point polymer, copolyamide, as raw material, adhesive meltblown webs were formed on the ordinary melt‐blowing line by using the accessory air and the accessory air chamber. The webs thus produced exhibit narrower fiber diameter distribution and a more uniform pore structure. At the same ti…
Thermally stable and 2-D hexagonal super-microporous silicas were obtained utilizing hydrated α-sodium disilicate over a diverse range of surfactant/Si molar ratios. Silica-based mesostructured materials composed of hydrated α-sodium disilicate and hexadecyltrimethylammonium (C 16 TMA) cations were acid-treated, resul…
High-resolution x-ray reflectivity (XRR) and heavy-ion elastic recoil detection were employed to study the role of hydrogen on the softening behavior observed in Si-incorporated hydrogenated amorphous carbon (Si-a-C:H) films synthesized by plasma-enhanced chemical-vapor deposition using tetramethylsilane (TMS) precurs…
The superconductivity that occurs below the charge ordering temperature in a quasi-two-dimensional (quasi-2D) organic conductor, the α-(ET) 2 I 3 salt, has been examined by applying the mean field theory and the random phase approximation to the extended Hubbard model with four sites in the unit cell and anisotropic n…
This paper describes the mechanism of leader discharge inception in SF6 gas with and without spacers exposed to fast oscillating impulse. A photomultiplier and a current probe are employed for the investigation of discharge development. The results show that the back discharge plays an important role in the initiation…
Environmental transmission electron microscopy (ETEM) is opening an important window for in situ studies of interaction of water with oxides. Studies of MgO smoke nanocrystals under partial pressures of water ranging from 10 mTorr to 10 Torr found their {100} neutral surfaces to be extremely resistant to dissociative…
Visible quantum cutting through downconversion is observed for the Gd3+–Eu3+ couple in KLiGdF5:Eu3+ (KLGF:Eu3+). In this Gd3+-based fluoride, visible quantum cutting, the emission of two photons of visible light per absorbed photon, occurs upon vacuum ultraviolet excitation of Gd3+ at the GJ6 level via two-step energy…
We describe the synthesis and characterization of a series of model nematic liquid crystals with transverse dipole moments used to study the flexoelectric effect in guest−host mixtures with commercial liquid crystal host. The flexoelectric coefficicent of the mixtures, containing only 10% by weight of the dopant, are…
Automatic qualitative analysis for peak identification is a standard feature of virtually all modern computer-aided analysis software for energy dispersive X-ray spectrometry with electron excitation. Testing of recently installed systems from four different manufacturers has revealed the occasional occurrence of misi…
Systematic studies of resistivity, thermoelectric power, and thermal conductivity have been performed on polycrystalline bilayered manganites ${\mathrm{LaSr}}_{2}{\mathrm{Mn}}_{2\ensuremath{-}x}{\mathrm{Co}}_{x}{\mathrm{O}}_{7}\phantom{\rule{0.2em}{0ex}}(0\ensuremath{\leqslant}x\ensuremath{\leqslant}0.2)$. As $x\ensur…
A series of nondegenerate pump-probe measurements were carried out on a DNA-wrapped single-walled carbon nanotube (SWNT) sample that is enriched with the (6,5) species. The pump pulse excites SWNTs at $\ensuremath{\sim}1.567\phantom{\rule{0.3em}{0ex}}\mathrm{eV}$, which corresponds to an energy of two $D$-band phonons…
In a poled ferroelectric ceramic, the probability of crystallographic poles oriented in any given specimen direction is the multiple of both the initial crystallographic texture and the domain switching fraction. In this paper, the non-180° domain switching fraction is shown to be dependent on the initial crystallogra…
Pressureless sintering of ultrafine zirconium diboride ZrB2 produced by self-propagating high temperature synthesis (SHS) was carried out over a temperature range of 1573 to 1873 K using a nickel additive. The additive improved densification behaviour and a maximum densification of 88% was achieved at 1873 K. The XRD…