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Synthesis and characterization of polypyrrole nanofibers with different dopants

Shubhra Goel、Nasreen Mazumdar、Alka Gupta2009-04-15Polymers for Advanced Technologies

Abstract Nanostructures of polypyrrole (PPy) were synthesized in the presence of different dopants including hydrochloric acid (HCl), ferric chloride (FeCl 3 ), p ‐toluene sulfonic acid ( p ‐TSA), camphor sulfonic acid (CSA), and polystyrene sulfonic acid (PSSA), using a simple interfacial oxidative polymerization met…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Key Role of the Cation Interstitial Structure in the Radiation Resistance of Pyrochlores

Alain Chartier、Gilles Catillon、Jean-Paul Crocombette2009-04-15Physical Review Letters

The annealing of the B cation interstitial is shown to drive the thermokinetic of the response to irradiations of A(2)B(2)O(7) pyrochlores. Molecular dynamics simulations evidenced that the annealing of interstitials created by irradiations depends upon the nature of B. As the coordination number of B decreases, the d…

Geological and Geochemical AnalysisAdvanced Condensed Matter PhysicsNuclear materials and radiation effects

Gd 2 O 3 : Eu 3 + particles prepared by glycine-nitrate combustion: Phase, concentration, annealing, and luminescence studies

R. S. Ningthoujam、Rakesh Shukla、R.K. Vatsa 等 6 位作者2009-04-15Journal of Applied Physics

Eu 3 + doped Gd2O3 particles have been prepared by glycine-nitrate combustion route. Eu–O charge transfer peak shifts to higher wavelength from 260 to 273 nm with increasing Eu3+ concentration, whereas the linewidth at half maximum intensity varies with Eu3+ concentrations and annealing temperatures as well. Lifetime…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Intense red light emission of Eu^3+-doped LiGd(PO_3)_4 for mercury-free lamps and plasma display panels application

Bing Han、H. Liang、Haiyong Ni 等 7 位作者2009-04-15Optics Express

In order to obtain a suitable red phosphor for mercury-free lamps and plasma display panels (PDPs), samples of trivalent europium-activated polyphosphate LiGd(PO(3))(4):Eu(3+) (LGP:Eu(3+)) were prepared by a solid-state reaction technique at high temperature. The vacuum ultraviolet (VUV)-visible spectroscopic properti…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Metal-MACiE: a database of metals involved in biological catalysis

Claudia Andreini、Ivano Bertini、Gabriele Cavallaro 等 5 位作者2009-04-15Bioinformatics

SUMMARY: Metal-MACiE is a new publicly available web-based database, held in MySQL, which aims to organize the available information on the properties and the roles of metals in the context of the catalytic mechanisms of metalloenzymes. Metal-MACiE, which currently covers 75% of metal-dependent enzyme commission (EC)…

Enzyme Catalysis and ImmobilizationEnzyme Structure and FunctionMetal-Catalyzed Oxygenation Mechanisms

Mechatronic Design of a Shape Memory Alloy Actuator for Automotive Tumble Flaps: A Case Study

A. Bellini、M. Colli、Eugenio Dragoni2009-04-15IEEE Transactions on Industrial Electronics

The continuous advance in mechatronics has long attracted researchers toward the development of new highly integrated actuators for automotive applications where reduced space and low weight are common constraints. In this context, Shape Memory Alloys (SMAs) offer many peculiar characteristics that make this technolog…

Shape Memory Alloy TransformationsTopology Optimization in EngineeringStructural Engineering and Vibration Analysis

Protective effects of neohesperidin and poncirin isolated from the fruits of Poncirus trifoliata on potential gastric disease

Je‐Hyuk Lee、Seungho Lee、Yeong Shik Kim 等 4 位作者2009-04-15Phytotherapy Research

The effects of Poncirus trifoliata (P. trifoliata) (Ponciri Fructus, PF) extract and its constituents such as neohesperidin and poncirin on gastritis in rats and human gastric cancer cells were investigated. The PF 70% ethanol extracts (1 g) showed approximately 11.38% of acid-neutralizing capacities and cytotoxicity…

Helicobacter pylori-related gastroenterology studiesNatural product bioactivities and synthesisPhytochemistry and Bioactive Compounds

Helical spin structure ofMn1−yFeySiunder a magnetic field: Small angle neutron diffraction study

S. V. Grigoriev、Vadim Dyadkin、E. V. Moskvin 等 7 位作者2009-04-15Physical Review B

The magnetic structure of the noncentrosymmetric cubic magnets with Dzyaloshinskii-Moriya interaction ${\text{Mn}}_{1\ensuremath{-}y}{\text{Fe}}_{y}\text{Si}$ with $y=0.0,0.06,0.08,0.10$ has been studied by means of the small angle neutron diffraction and magnetization measurements. The compounds order in the spin hel…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsMagnetic Properties of Alloys

Thermosensitive Micelles Based on Folate‐Conjugated Poly(N‐vinylcaprolactam)‐block‐Poly(ethylene glycol) for Tumor‐Targeted Drug Delivery

M. Prabaharan、Jamison Grailer、Douglas A. Steeber 等 4 位作者2009-04-15Macromolecular Bioscience

Thermosensitive PNVCL-b-PEG block copolymer coupled with folic acid was prepared as an anti-cancer drug carrier. This polymer self-assembled into stable micelles in aqueous solutions at above 33 degrees C. At 37 degrees C, the release profile of PNVCL-b-PEG-FA micelles showed a slower and more controlled release of th…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched Polymers

A physics-based model of electrical conduction decrease with time in amorphous Ge2Sb2Te5

Mattia Boniardi、Andrea Redaelli、A. Pirovano 等 6 位作者2009-04-15Journal of Applied Physics

The time-stability of the electrical characteristics of chalcogenide materials is one of the most important issues for their use in nonvolatile solid state memory applications. In particular the electrical conduction of the glassy phase evolves with time due to two different physical phenomena: the crystallization and…

Liquid Crystal Research AdvancementsPhase-change materials and chalcogenidesAdvanced Optical Imaging Technologies

Upper bound to the thermal conductivity of carbon nanotube pellets

Yann Chalopin、Sébastian Volz、Natalio Mingo2009-04-15Journal of Applied Physics

Using atomistic Green’s function calculations, we find that the phonon thermal conductivity of pellets composed of ∼μm long carbon nanotubes has an upper bound of a few W/m K. This is in striking contrast with the extremely high thermal conductivity of individual nanotubes (∼3000 W/m K). We show that, at room temperat…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Subwavelength internal imaging by means of a wire medium

Yan Zhao、Pavel A. Belov、Yang Hao2009-04-15Journal of Optics A Pure and Applied Optics

Evanescent wave amplification is observed, for the first time to our knowledge, inside a half-wavelength-thick wire medium slab used for subwavelength imaging. The wire medium is analyzed using both a spatially dispersive finite-difference time-domain (FDTD) method and a full-wave commercial electromagnetic simulator…

Metamaterials and Metasurfaces ApplicationsTerahertz technology and applicationsMicrowave Imaging and Scattering Analysis

Synthesis of ultrathin carbon films by direct current filtered cathodic vacuum arc

H.-S. Zhang、K. Komvopoulos2009-04-15Journal of Applied Physics

Filtered cathodic vacuum arc was used to synthesize ultrathin carbon films on silicon substrates. The depth profiles, near-surface chemical composition, fractions of tetrahedral (sp3) and trigonal (sp2) carbon atom hybridizations, roughness, and hardness of the carbon films were determined from Monte Carlo (T-DYN) sim…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Investigation of Vortex Spun Yarn Properties in Comparison with Conventional Ring and Open-end Rotor Spun Yarns

Nazan Erdumlu、Bülent Özipek、A. Selda Oztuna 等 4 位作者2009-04-15Textile Research Journal

In this study, the properties of ring, rotor, and vortex spun yarns produced in different counts from cotton, viscose rayon, and 50/50 cotton-modal blended fibers were investigated. Yarn samples were converted into knitted fabrics in a single jersey circular knitting machine and dyed with reactive dyestuff to determin…

Textile materials and evaluationsAdvanced Materials and MechanicsStructural Analysis and Optimization

Protonated Nanoparticle Surface Governing Ligand Tethering and Cellular Targeting

Abhilash Vincent、K. Suresh Babu、Eric Heckert 等 11 位作者2009-04-15ACS Nano

Nanoparticles have shown tremendous potential for effective drug delivery due to their tiny size and cell membrane penetration capabilities. Cellular targeting with nanoparticles is often achieved by surface modifications followed by ligand conjugation. However, the efficiency of the nanoparticles reaching the target…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesAdvanced Nanomaterials in Catalysis

Peptide‐Coated Silver Nanoparticles: Synthesis, Surface Chemistry, and pH‐Triggered, Reversible Assembly into Particle Assemblies

Philipp Graf、Alexandre Mantion、Annette Foelske 等 7 位作者2009-04-15Chemistry - A European Journal

Abstract The degree of aggregation of silver nanoparticles can be controlled via a pH sensitive peptide coating (see figure). As the peptide not only controls the colloidal properties, but also influences the crystal structure of the individual nanoparticles, peptide/silver particle hybrid materials can be viewed as f…

Quantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Novel Biomimetic Surface Based on a Self-Organized Metal−Polymer Hybrid Structure

Daisuke Ishii、Hiroshi Yabu、Masatsugu Shimomura2009-04-15Chemistry of Materials

Biomimetic hybrid metal-dome−polymer-spike surfaces having controllable water droplet adhesion on superhydrophobic surfaces are prepared by self-organization, electroless plating, and simple peeling. The hybrid surface is characterized by affinity-driven water droplet adhesion that is easily controlled by hydrophilic…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Topological description of the Stone-Wales defect formation energy in carbon nanotubes and graphene

Elif Ertekin、D. C. Chrzan、Murray S. Daw2009-04-15Physical Review B

We develop a topological continuum framework to compute the formation energies of Stone-Wales defects in graphene and carbon nanotubes. Our approach makes no a priori assumptions about the analytical form of the dislocation strain fields while explicitly accounting for boundary conditions and defect-defect interaction…

Carbon Nanotubes in CompositesGraphene research and applicationsTopological Materials and Phenomena

Lanthanide(III)-Doped Magnetite Nanoparticles

Channa R. De Silva、Steve Smith、In‐Bo Shim 等 7 位作者2009-04-15Journal of the American Chemical Society

Nearly monodisperse lanthanide-doped magnetite nanoparticles were obtained by thermally decomposing a mixture of Fe(acac)(3) and Ln(acac)(3) (acac = acetylacetonate; Ln = Sm, Eu, Gd) in the presence of passivating surfactants. Magnetic studies revealed room-temperature ferromagnetic behaviors of these doped nanopartic…

Magnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Combined Surface Plasmon and Classical Waveguiding through Metamaterial Fiber Design

Elliot J. Smith、Zhaowei Liu、Yongfeng Mei 等 4 位作者2009-04-15Nano Letters

A metamaterial integration for fiber optics, leading to a dual effect of surface plasmon and classical waveguiding, is presented along with experimental potentiality. We theoretically propose a metamaterial fiber in which, depending on the wavelength (from ultraviolet to infrared) and the particular metamaterial compo…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications