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Thermodynamic stabilization of nanostructured alpha-Ni1−xCox(OH)2 for high efficiency batteries and devices

Paulo Roberto Martins、Sérgio H. Toma、Marcelo Nakamura 等 5 位作者2013-01-01RSC Advances

The exceptional stability of FTO electrodes modified with Ni1−xCox(OH)2 in the alpha polymorphic phase was assigned to Co(II) substitution in the Ni(II) reticule, decreasing the basal plane distances and the average grain size, as confirmed by careful analyses of their X-ray diffractograms and thermal behavior as a fu…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Influence of Neodymium Addition on the Microstructure, Mechanical and Thermal Properties of Mg-Si Alloys

K. K. Ajith Kumar、Abhilash Viswanath、U.T.S. Pillai 等 5 位作者2013-01-01Procedia Engineering

The present work aims to investigate the influence of neodymium addition on the microstructure, mechanical and thermal properties of Mg-Si alloys. Different proportions of (0.3, 0.6, 0.9 and 1.2 wt.%) Nd has been added to the hypo (Mg-1.15Si) and hypereutectic (Mg-6Si) alloys. The microstructural studies reveal that t…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Damage Evaluation of Reinforced Concrete Columns by Hypervelocity Impact

Toshiyuki Atou、Yousuke Sano、Masahide Katayama 等 4 位作者2013-01-01Procedia Engineering

To evaluate local damages of RC columns by the impacts of a high velocity projectile, impact experiments using a gun method were performed for the 1/10 scale RC columns as test specimens. Effects of an amount of main bar and spacing between hoops were examined. Also, scaling effects were evaluated by comparing with th…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Lamination and spherulite-like compaction of a hormone’s native amyloid-like nanofibrils: spectroscopic insights into key interactions

Wilmar van Grondelle、Sophie Lecomte、Carmen López‐Iglesias 等 7 位作者2013-01-01Faraday Discussions

The native hierarchical self-assembly process of natural somatostatin-14, a highly aromatic and charged peptide hormone involved in various inhibitory functions, was investigated mainly using vibrational spectroscopy (ATR-FTIR and Raman scattering) combined with electron microscopy. Generic kinetic features of amyloid…

Protein Structure and DynamicsLipid Membrane Structure and BehaviorSupramolecular Self-Assembly in Materials

Solid State Polymerization: Its action on thermal and rheological properties of PET/PC reactive blends

Luis Cláudio Mendes、Patrícia Soares da Costa Pereira2013-01-01Polímeros

The solid state polymerization (SSP) of PET/PC reactive extrusion blends -with and without cobalt catalyst -at different polymer ratios was studied. Thermal and rheological evaluations were performed. DSC results showed changes in the PET's T g , T ch , T m and X c . The melt flow rate (MFR) decreased for PET and the…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Exciton coupling in molecular salts of 2-(1,8-naphthalimido)ethanoic acid and cyclic amines: modulation of the solid-state luminescence

Simone D’Agostino、Fabrizia Grepioni、Dario Braga 等 8 位作者2013-01-01CrystEngComm

In this study we have purposely altered the solid state luminescence properties of 2-(1,8-naphthalimido)ethanoic acid (NEaH) (0) via molecular salts formation with cyclic amines such as 1,4-diazabicyclo[2.2.2]octane (DABCO), quinuclidine (ABCO), 3-quinuclidinol (OH-ABCO), and piperazine (PIP). All crystalline material…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchLuminescence and Fluorescent Materials

Preparation of magnetic rattle-type silica through a general and facile pre-shell–post-core process for simultaneous cancer imaging and therapy

Qiang Li、Xianwei Meng、Linlin Li 等 12 位作者2013-01-01Chemical Communications

Here we report a novel pre-shell-post-core method for the fabrication of monodispersed magnetic rattle-type silica (MRS) through an entrapment process, which could be used as a promising theranostic agent for simultaneous magnetic resonance imaging and drug delivery.

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesNanoplatforms for cancer theranostics

Kinetics of aggregations of F 2, F 3, X, and colloid centers in LiF/Si(111) films upon low-temperature annealing

Utkirjon Sharopov、Б.Г. Атабаев、R. Djabberganov 等 4 位作者2013-01-01Journal of Surface Investigation X-ray Synchrotron and Neutron Techniques

The temperature dependence of the generation kinetics of F centers and their aggregates in a LiF/Si(111) thin-film system after irradiation with low-energy (80-eV) electrons was studied by total current spectroscopy. It was shown that, in all cases, low-temperature annealing results in degradation of the formed center…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

NV centers in diamond. Part III: Quantum algorithms, scaling, and hybrid systems

A. V. Tsukanov2013-01-01Russian Microelectronics

In this part of the review, the currently implemented elementary quantum algorithms are considered and prospects of the development of the full-scale quantum computer based on NV centers in diamond are discussed. The NV-hybrid systems, which can operate as the communication elements between remote NV qubits, are analy…

Diamond and Carbon-based Materials ResearchLaser-Matter Interactions and ApplicationsAdvanced Fiber Laser Technologies

Final report on supplementary comparison EURAMET.EM-S32: Comparison of resistance standards at 1 TΩ and 100 TΩ

B. Jeckelmann、Jan H. N. van der Beek、Pier Paolo Capra 等 23 位作者2013-01-01Metrologia

Resistance standards with values in the TΩ range play an important role in electrical instrumentation. The calibration of such standards is, thus, a service offered by many metrology institutes. The techniques used to measure very high resistance values differ quite substantially from the calibration techniques applie…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesAdvanced Electrical Measurement Techniques

Compositional characterisation of metallurgical grade silicon and porous silicon nanosponge particles

Edward G. Chadwick、Naga Vishnu Vardhan Mogili、Colm O’Dwyer 等 8 位作者2013-01-01RSC Advances

Porous silicon is generally achieved through electro-chemical etching or chemical etching of bulk silicon in hydrofluoric acid based solutions. The work presented here explores the effect of a chemical etching process on a metallurgical grade silicon powder. It is found that the metallurgical grade silicon particles c…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

The Role of Replacing CdO by Fe<sub>2</sub>O<sub>3</sub> on the Fast Neutron Removal Cross Sections in Cd-Boro Phosphate Glass Shield

H. A. Sallam、Heba A. Saudy2013-01-01World Journal of Condensed Matter Physics

This work deals with the application of [MERCSF-N] computer program in calculating the macroscopic effective removal cross-section of fast neutrons, ΣR (cm-1), for two different boro phosphate glass systems: (0.5 - x) CdO-x Fe2O3-0.4 P2O5-0.1 B2O3 and (0.5 - x) B2O3-x Fe2O3-0.1 CdO-0.4 P2O5 (with 0.05 ≤ x ≤ 0.5 by mol…

Glass properties and applicationsRadiation Shielding Materials AnalysisNuclear materials and radiation effects

Anionic surfactant templated chiral nanospheres and their enantioselective adsorption

Bin Di、Lifei Cheng、Qiuling Jiang 等 5 位作者2013-01-01New Journal of Chemistry

Monodispersed chiral mesoporous spheres of nanometer size with high specific area and good thermal stability were synthesized using the chiral anionic surfactant (N-palmitoyl-L-phenylalanine) as a template according to the co-structure directing agent (CSDA) method. The resulting mesoporous nanospheres were characteri…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisSupramolecular Self-Assembly in Materials

Chemical modification of graphene with a thermotropic liquid crystalline polymer and its reinforcement effect in the polymer matrix

Ying Jing、Hui Tang、Guijun Yu 等 4 位作者2013-01-01Polymer Chemistry

In our work, graphene oxide (GO) was covalently functionalized with propargyl alcohol to obtain alkyne terminated graphene oxide. These alkyne groups on graphene oxide sheets further reacted with a kind of azido-functionalized liquid crystalline polymer via click chemistry, which was found to be a facile and effective…

Graphene research and applicationsAdvanced Sensor and Energy Harvesting MaterialsGraphene and Nanomaterials Applications

Regioselective oxidative coupling of 2,6-dimethylphenol to tetramethyldiphenoquinone using polyamine dendrimer-encapsulated Cu catalysts

Zen Maeno、Motohiro Okao、Takato Mitsudome 等 6 位作者2013-01-01RSC Advances

The polyamine dendrimer-encapsulated Cu complexes are capable of regioselectively catalyzing the oxidative coupling reaction of 2,6-dimethylphenol to tetramethyldiphenoquinone in high yield. The polyamine dendrimer nanovoids encapsulate Cu ions in such a manner that adjacent Cu centers are able to serve as active spec…

Metal-Organic Frameworks: Synthesis and ApplicationsDendrimers and Hyperbranched PolymersNanomaterials for catalytic reactions

Lanthanide-containing peroxoisopolytungstate with tetrahedral WO42− template core, [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14−

Lanying Song、Dongdi Zhang、Pengtao Ma 等 6 位作者2013-01-01CrystEngComm

Two lanthanide-containing peroxoisopolyanions [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14− (Ln = LaIII; PrIII), have been synthesized by reaction of Na2WO4 and lanthanide (Ln) ions in the presence of peroxide. These represent the first two examples of peroxo-containing Ln-stabilized polyanions (LSPs), and have the highest number…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Improvement of Boron Carbide Mechanical Properties in B<sub>4</sub>C-TiB<sub>2 </sub>and B<sub>4</sub>C-ZrB<sub>2</sub> Systems

Zviad Kovziridze、Z. Mestvirishvili、G. Tabatadze 等 6 位作者2013-01-01Journal of Electronics Cooling and Thermal Control

Experimental works have been conducted the objective of which was to improve mechanical properties of boron carbide by introduction of doping elements into the system. Titanium and Zirconium were selected as doping elements, which were introduced into the system in the form of TiB2 and ZrB2. Four types of boron carbid…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchAdvanced materials and composites

Energy transfer in Ce, Nd, and Yb co-doped YAG phosphors

Lulu Wang Lulu Wang、Changtai Xia Changtai Xia、Peng Xu 等 6 位作者2013-01-01Chinese Optics Letters

YAG-Ce, Nd, and Yb phosphors with a triple-doped system are prepared by conventional solid-state reaction method. The fluorescence emission and excitation spectra are measured and analyzed. The influences of Yb 3+ doping concentration on the emission of Yb 3+ and Nd 3+ in YAG-Ce, Nd, and Yb are studied. The fluorescen…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesAmmonia Synthesis and Nitrogen Reduction

Combustion and material characterization of porous silicon nanoenergetics

Nicholas W. Piekiel、Wayne A. Churaman、Christopher J. Morris 等 4 位作者2013-01-01OpenAlex

Certain porous silicon (PS) structures have demonstrated energetic characteristics when mixed with an appropriate oxidizer [1-4]. However, limited studies on the effect of PS structure on its combustion have been performed. This work investigates how various material properties of PS films; surface area, porosity and…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Photocontrolled template-directed synthesis of complementary double helices assisted by amidinium–carboxylate salt bridge formation

Junki Tanabe、Daisuke Taura、Hidekazu Yamada 等 5 位作者2013-01-01Chemical Science

The template-directed imine-bond forming reactions between chiral amidines or achiral carboxylic acids monomers bearing a formyl or an amino group at one end were remarkably accelerated 34- or 10-fold in chloroform in the presence of the corresponding optically inactive carboxylic acid dimer or optically active amidin…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry