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Photodegradation and photostabilization of europium compounds in polyvinyl chloride

I. V. Kalinovskaya、А. Г. Мирочник、В. Е. Карасев2008-12-01Russian Journal of Applied Chemistry

The photolysis kinetics was studied, and methods were suggested for photostabilization of complexes of europium with β-diketones and europium cinnamates and quinaldates in polyvinyl chloride.

Analytical chemistry methods developmentRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Ethylene glycol-modified cobalt and iron oxalates as precursors for the synthesis of oxides as extended microsized and nanosized objects

В. Н. Красильников、О. И. Гырдасова、Г. В. Базуев2008-12-01Russian Journal of Inorganic Chemistry

The reactions of ethylene glycol with iron and cobalt oxalates upon heating in air are reported. Heat treatment of mixtures of oxalate powders with ethylene glycol yields new compounds (solvates) via the replacement of the water molecules in the oxalate structure by ethylene glycol molecules: MC 2 O 4 · 2H 2 O + HOCH…

Iron oxide chemistry and applicationsnanoparticles nucleation surface interactionsThermal and Kinetic Analysis

Study of cyanoethylated alfa fiber reinforced composites by dynamic mechanical analysis

M. Ben Abderrahmane、Ridha Ben Cheikh2008-12-01Surface Engineering and Applied Electrochemistry

Cyanoethylation of long alfa fibers was studied, and these chemically modified fibers were used to manufacture alfa-polyester composites. The dynamic mechanical thermal properties of an unsaturated polyester resin (cured) and of composites of unmodified and chemically modified alfa-polyester were studied using a dynam…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesMaterial Properties and Applications

Monomer recovery from polycarbonate by methanolysis

Shwu-Jer Chiu、Chou-Tso Tsai、Yu-Kaung Chang2008-12-01e-Polymers

Abstract Depolymerization and monomer recovery from polycarbonate (PC) by methanolysis was investigated. Methanolysis with molar ratios of methanol to polycarbonate ranging from 12.5 to 50 was carried out from 170°C to 300°C for up to 30 min. Polycarbonate decomposed into two monomers, bisphenol A (BPA) and dimethyl c…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Electro‐optical cells using a cellulose derivative and cholesteric liquid crystals

Pedro L. Almeida、Sudarshan Kundu、J. L. Figueirinhas 等 4 位作者2008-12-01Liquid Crystals

A cellulose derivative/liquid crystal composite‐type electro‐optical cell using a commercial cholesteric liquid crystal (CLC) was investigated. The electro‐optical properties of the system were examined, i.e. the dependence on applied voltage of the reflected wavelength and the minimum and maximum transmissions. A thi…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsSemiconductor Lasers and Optical Devices

Leakage Current Patterns on High Voltage Insulators: Analysis on Frequency and Time-frequency Domains

H.I.S. Jayasundara、W.P.S. Sudarshani、M.A.R.M. Fernando2008-12-01OpenAlex

This paper presents analysis of leakage currents on high voltage insulators in frequency and time-frequency domains. Leakage currents were measured on five silicone rubber insulators under salt fog conditions and recorded over 1000 hours. Different types of leakage current patterns were identified and were grouped acc…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrical Fault Detection and Protection

Efficacy of solvent, alkali and pectinase on removal of non-cellulosics from cotton fibres

G Nalankilli、D. Saravanan、N Govindaraj 等 5 位作者2008-12-01OpenAlex

The physical properties of different varieties of cotton fibres of various origins have been studied after extraction using solvents and alkali scouring with reference to enzyme scouring process. Enzyme scoured samples show comparable results with that of solvent extracted and alkali scoured samples in terms of fibre…

Natural Fiber Reinforced CompositesDyeing and Modifying Textile FibersTextile materials and evaluations

Estimation of pore sizes in porous silicon by scanning electron microscopy and NMR cryoporometry

Alexey Khokhlov、Rustem Valiullin、Jörg Kärger 等 5 位作者2008-12-01Journal of Surface Investigation X-ray Synchrotron and Neutron Techniques

Certain possibilities of scanning electron microscopy and cryoporometry based on nuclear magnetic resonance (NMR) have been evaluated to determine pore sizes in porous silicon. The results obtained by these methods have been compared. NMR cryoporometry has been shown to be promising in the investigation of porous mate…

Carbon Nanotubes in CompositesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Thallium-rich murunskite from the Lovozero pluton, Kola Peninsula, and partitioning of alkali metals and thallium between sulfide minerals

Igor V. Pekov、Atali A. Agakhanov2008-12-01Geology of Ore Deposits

A new thallium-rich variety of murunskite has been found in the Palitra peralkaline pegmatite at Mount Kedykverpakhk, the Lovozero alkaline pluton, Kola Peninsula, Russia. This mineral occurs as a flattened dark bronze segregation (0.3 × 0.8 × 0.8 mm) overgrowing ussingite in a cavity. The chemical composition is as f…

Crystal Structures and PropertiesInorganic Chemistry and MaterialsThallium and Germanium Studies

Synthesis and characterization of some composites with bioactive properties on the basis of vinyl ester resins

Dan Roşu、Constantin N. Caşcaval、Liliana Roşu2008-12-01e-Polymers

Abstract Vinyl ester resins are unsaturated polyesters, widely used as matrix for high performance composite materials. The paper presents the synthesis and characterization of some vinyl ester resin/hydroxyapatite bioactive compositions using an unsaturated copolyester based on turpentine oil as reactive diluent. The…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer composites and self-healing

Synchrotron X-ray powder diffraction data of atorvastatin

Selma Gutierrez Antônio、Fernanda Ribeiro Benini、Fábio Furlan Ferreira 等 5 位作者2008-12-01Powder Diffraction

X-ray powder diffraction data collected in transmission and high-throughput geometries were used to analyze form I of atorvastatin. The X-ray wavelength of the synchrotron radiation used in this study was determined to be λ =1.3771 Å. Form I of atorvastatin was found to be triclinic with space group P 1 and unit cell…

Crystallography and molecular interactionsCultural Heritage Materials AnalysisX-ray Diffraction in Crystallography

Piranha Treated Titanium Compared to Passivated Titanium as Characterized by XPS

Holly J. Martin、Kirk H. Schulz、Keisha B. Walters2008-12-01Surface Science Spectra

Titanium is commonly used as an implant material because of its strength, durability, density, and ability to passivated. Two titanium surfaces were compared, one produced by passivation following the ASTM F87 standard and one produced by treating coupons with piranha. The XPS spectra of the two treated titanium surfa…

Bone Tissue Engineering MaterialsAdvanced Surface Polishing TechniquesElectron and X-Ray Spectroscopy Techniques

Endothelial Cell Retention on a Viscoelastic Nanocomposite Vascular Conduit Is Improved by Exposure to Shear Stress Preconditioning Prior to Physiological Flow

Dina Vara、Geoffrey Punshon、Kevin M. Sales 等 6 位作者2008-12-01Artificial Organs

In this study, endothelial cell (EC)-seeded nanocomposite grafts were preconditioned with 1-2 dynes/cm(2) in vitro to establish whether low shear stress resulted in improved cell adherence prior to physiological shear stress (15 dynes/cm(2)). Alamar blue cell viability was assessed. Polymerase chain reaction was condu…

Electrospun Nanofibers in Biomedical ApplicationsCardiac and Coronary Surgery TechniquesTissue Engineering and Regenerative Medicine

Synthesis and RGD peptide modification of poly{(lactic acid)-co-[(glycolic acid )-alt-(L-lysine)]}

Qiongjiao Yan、Juan Li、Shipu Li 等 5 位作者2008-12-01e-Polymers

Abstract A new polymer poly{(lactic acid)- co -[(glycolic acid)- alt -(L-lysine)]} (poly[LA- co -(Glc- alt -Lys)]) was synthesized and modified with a cell adhesion peptide, Gly-Arg-Gly-Asp-Tyr (GRGDY, abbreviated as RGD). The process for preparing poly[LA- co -(Glc- alt -Lys)]/RGD involved four steps: Firstly, (3S)-3…

biodegradable polymer synthesis and propertiesClick Chemistry and ApplicationsBiopolymer Synthesis and Applications

Pressure-induced phase transformation in CdO: An ab initio constant-pressure study

Murat Durandurdu2008-12-01Europhysics Letters (EPL)

A constant-pressure ab initio technique is used to study the behavior of CdO at high pressures. A phase transformation from the NaCl-type structure to the CsCl-type structure via a rhombohedral intermediate state is successfully observed through the constant-pressure simulation. This phase change is also analyzed from…

Advanced Chemical Physics StudiesZnO doping and propertiesHigh-pressure geophysics and materials

Optically monitored wet‐chemical preparation of SEIRA active Au nanostructures

Dominik Enders、Tadaaki Nagao、Tomonobu Nakayama 等 4 位作者2008-12-01Surface and Interface Analysis

Abstract The growth process of spherical substrate‐bound Au nanoparticles (AuNP) was investigated with in situ visible (VIS) spectroscopy, in situ Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). In the VIS spectra, the redshift and broadening of the AuNP's surface plasmon resona…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanocluster Synthesis and Applications

Introduction to Cast Irons

George M. Goodrich2008-12-01ASM International eBooks

Abstract The term cast iron designates a group of materials that contain more than one constituent in their microstructure due to excess carbon that result in unique characteristics such as the fracture appearance and graphite morphology. This article discusses the classification of cast iron and the various metallurg…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Counting perfect colourings of plane regular tilings

Dirk Frettlöh2008-12-01Zeitschrift für Kristallographie

Abstract A first step in investigating colour symmetries of periodic and nonperiodic patterns is determining the number of colours which allow perfect colourings of the pattern under consideration. A perfect colouring is one where each symmetry of the uncoloured pattern induces a global permutation of the colours. Two…

Quasicrystal Structures and Properties

The effect of temperature on tacticity for bulk thermal polymerization of styrene

Farshid Ziaee、Mehdi Nekoomanesh、Hamid Salehi Mobarakeh 等 4 位作者2008-12-01e-Polymers

Abstract Three types of polystyrenes were prepared at different temperatures of 50, 150 and 250°C by bulk thermal polymerization of styrene below 20 percent of conversion. The assignment of all stereosequences at pentad level of quaternary aromatic carbon and hexad level of methylene carbon of the polystyrenes were do…

Zeolite Catalysis and SynthesisPolymer crystallization and propertiesNMR spectroscopy and applications