Materials Literature
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Titanium porphyrin hydrazido complexes (TTP)Ti = NNR2 (TTP = meso-tetra-p-tolylporphyrinato dianion; R = Me (1), Ph (2)) were synthesized by treatment of (TTP)TiCl2 with 1,1-disubstituted hydrazines H2NNR2 (R = Me, Ph) in the presence of piperdine. The nucleophilic character of the hydrazido moiety was demonstrated in…
Thin films of poly(vinylcinnamate) and poly(7-methacryloyloxycoumarin) have been exposed to linearly polarized UV light. The resulting anisotropic films have been characterized by using UV, conventional and polarization modulation FTIR spectroscopies. In particular, several internal vibrational modes have been used as…
Reaction of trialkylaluminum Al2R6 (R = Me, Et) with 2,2′-methylenebis(6-tert-butyl-4-methylphenol) (mbmpH2) gives the dimeric mono(alkyl) complex [Al(mbmp)R]2 with bridging oxygen atoms. Reaction of [Al(mbmp)R]2 with one equiv. of 2-propanol results in the formation of the dimeric isopropoxide [Al(mbmp)(μ-OiPr)]2. Si…
Aqueous solutions of the calcium and sodium salts of dipicolinic acid (DPA) were shown to have weak fluorescence when excited at wavelengths near 300 nm, but no fluorescence was observed from DPA alone. Upon UV irradiation at 254 nm the fluorescence of all three forms increases dramatically. The emission spectrum of c…
The core structure of a screw dislocation in the diamond lattice has been calculated with the Stillinger-Weber potential for the interatomic interaction. The non-dissociated screw dislocation positioned at the centre of a unit hexagon normal to the dislocation line is a stable configuration A. A perfect screw centred…
A Landau expansion of the elastic energy in the strains is used to study two-dimensional structures in tetragonal-orthorhombic ferroelastics with constraints. Local energy minima are found with respect to the components of the displacement and so the strains satisfy the compatibility relation; this interdependence of…
The photoelectric characteristics (independent of ferroelectric polarization) of metal-ferroelectric-metal thin film structures upon exposure to radiation in different ranges of mercury arc lamp spectrum are studied for the Pb(Zr 0.5 2Ti 0.48 )O 3 ( PZT ) ferroelectrics. The PZT films on platinized silicon substrates…
Hydrogen permeation and corrosion inhibition characteristics of isomers of phenylenediamine, toluidine, and nitroaniline were studied on mild steel in 1M HCl. The Tafel extrapolation method was used to determine the inhibition efficiency, while the Devanathan–Stachurski technique was used to determine the hydrogen per…
The microstructure of strained epitaxial La0.7Sr0.3MnO3 (LSMO) films on a LaAlO3(001) substrate has been investigated by means of electron diffraction and high-resolution electron microscopy in cross-section and plan view. Fourier transforms of the high-resolution images allow us to deduce the local lattice parameters…
The plasma polymerization of the perfluoroallyl benzene monomer [(C6F5)CF2CF=CF2] was carried out under pulsed discharge conditions. Progressive changes in the composition of the plasma generated polymers were observed with sequential changes in the duty cycle of the pulsed discharge, as other reaction variables remai…
Abstract Thermal effects in dynamic hydrogen storage by adsorption at room temperature and high pressure are studied theoretically and experimentally. The system of adsorbate–adsorbent used was hydrogen in granular activated carbon. The theoretical analysis was based on heat‐ and mass‐transfer modeling in a packed‐bed…
A nickel catalytic probe was used to determine the density of neutral oxygen atoms in a glass tube. The O source was a low pressure weakly ionized inductively coupled rf oxygen plasma. The recombination coefficient for polycrystalline nickel (purity 99.8 at. %) was determined experimentally by use of a nickel tube wit…
Abstract The rheological properties of conventional polyethylene terephthalate (PET) resins are not particularly suitable for low density extrusion foaming with physical blowing agents; as a result, chemically modified resins through chain extension/branching reactions are often used. Such resins have overall higher m…
Abstract Grease‐resistant paper has been produced by coating paper with isolated soy protein (ISP). Tensile strength (TS) of ISP‐coated paper is 28–30 MPa (between the TS of paper and of ISP film). TS of the ISP‐coated paper (2.3 kg/ream) was highest (36.0 MPa) among other ISP‐coated papers, but elongation (E) of the…
Thin film material of oriented multiwall carbon nanotubes was obtained by noncatalytical chemical vapor deposition in a glow-discharge plasma. The film phase composition, surface morphology, and structural features were studied by Raman and electron microscopy techniques. Low-voltage electron field emission of thin fi…
The lamellar organization of melt-crystallized β-isotactic polypropylene was studied by atomic force microscopy (AFM) after permanganic etching. Hedritic objects grown at a high crystallization temperature (140–143 °C) were investigated. Essential features of the hedritic development were revealed by the characteristi…
Abstract Acid variable charge subsoils exhibit a positive charge, which retards the passage of anions through the soil profile. The objective was to study the NO − 3 adsorption isotherms and the effect of changing the subsoil positive charge on NO − 3 and Cl − retention, estimate NO − 3 and Cl − retardation in differe…
Type II and III fibrillar collagens were localized by immunogold electron microscopy in resin sections of human femoral articular cartilage taken from the upper radial zone in specimens from patients with osteoarthritis. Tissue samples stabilized by high-pressure cryofixation were processed by freeze-substitution, eit…
Summary Soils derived from loess are extensive in Europe and are well suited for forestry. They are suspected to be poor acid buffers, however. We have estimated the weathering stage and acid neutralizing capacity of acid soils under forest in a toposequence on loess in the Belgian silt belt. The soils vary distinctly…
Rutherford backscattering spectroscopy was used to investigate the persistence of cation-diffusion- limited oxidation in three, low-Fe 2+ -bearing MgO-Al 2 O 3 -SiO 2 glasses (base glass compositions along the enstatite-cordierite-liquid cotectic; total Fe levels of 0.04, 0.19, and 0.54 at%). The glasses were reacted…