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Monodispersed and Well‐Crystallized Zinc Oxide Nanoparticles Fabricated by Microemulsion Method

Masashi Inoguchi、Keigo Suzuki、Keisuke Kageyama 等 5 位作者2008-11-18Journal of the American Ceramic Society

Monodispersed and spherically shaped zinc oxide (ZnO) nanoparticles with particle sizes of <5 nm were successfully fabricated by the microemulsion (ME) method. In this process, ZnO nanoparticles were formed at room temperature by the hydrolysis reaction of zinc diethoxide in the small water droplets in reverse mice…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Effect of functionalization on the self-assembling propensity of β-sheet forming peptides

Francesca Taraballi、Marcello Campione、A. Sassella 等 7 位作者2008-11-18Soft Matter

The mechanism underlying self-assembly of short peptides has not been fully understood despite the fact that a few decades have passed since their serendipitous discovery. RADA16-I (AcN-RADARADARADARADA-CONH2), representative of a class of self-assembling peptides with alternate hydrophobic and hydrophilic residues, s…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Partially Acetylated Chitosan Oligo- and Polymers Induce an Oxidative Burst in Suspension Cultured Cells of the Gymnosperm Araucaria angustifolia

André Luis Wendt dos Santos、Nour Eddine El Gueddari、Stéphane Trombotto 等 4 位作者2008-11-18Biomacromolecules

Suspension-cultured cells were used to analyze the activation of defense responses in the conifer A. angustifolia , using as an elicitor purified chitosan polymers of different degrees of acetylation (DA 1-69%), chitin oligomers of different degrees of polymerization (DP 3-6), and chitosan oligomer of different DA (0-…

Plant tissue culture and regenerationNanocomposite Films for Food PackagingPolysaccharides and Plant Cell Walls

Effect of fiber/matrix chemical modification on the mechanical properties and water absorption of extruded flax/polypropylene composite

Ahmed Elsabbagh、Leif Steuernagel、Gerhard Ziegmann2008-11-18Journal of Applied Polymer Science

Abstract Compound of flax/polypropylene (PP) is characterized concerning the mechanical properties of stiffness, strength, and impact in addition to the water absorption behavior. Manufacturing takes place by twin‐screw extruder. The extruder screw layout is modified through different kneading elements to get high fib…

Natural Fiber Reinforced CompositesElectromagnetic wave absorption materialsTribology and Wear Analysis

Coexistence of superconductivity and antiferromagnetic ordering in the layered superconductor SmFePO

Yoichi Kamihara、Hidenori Hiramatsu、Masahiro Hirano 等 9 位作者2008-11-18Physical Review B

Superconductivity and magnetic transition in SmFePO were examined by electric, magnetic, $^{57}\text{F}\text{e}$ M\"ossbauer, and $^{149}\text{S}\text{m}$ nuclear resonant forward-scattering (NRFS) measurements. Zero resistivity and negative magnetic susceptibility were observed in an undoped SmFePO, indicating superc…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Synthesis and Characterization of Tetrathiafulvalene-Substituted Di- and Tetraethynylethenes with p-Nitrophenyl Acceptors

Asbjørn Sune Andersson、L. Kerndrup、Anders Ø. Madsen 等 7 位作者2008-11-18The Journal of Organic Chemistry

Novel di- and tetraethynylethene (DEE and TEE) compounds functionalized with tetrathiafulvalene (TTF) donor groups and p-nitrophenyl acceptor groups were synthesized by palladium-catalyzed cross-coupling reactions under various conditions. The molecules are strong chromophores and were investigated for their optical p…

Magnetism in coordination complexesNonlinear Optical Materials ResearchOrganic and Molecular Conductors Research

Study of Supramolecular Side-Chain Copolymers Containing Light-Emitting H-Acceptors and Electron-Transporting Dendritic H-Donors

Po-Jen Yang、Chung-Wen Wu、Duryodhan Sahu 等 4 位作者2008-11-18Macromolecules

A novel light-emitting hydrogen-bonded (H-) acceptor PBB (M1) containing three conjugated aromatic rings, including one pyridyl terminus and two lateral methoxyl groups (on the middle ring), was successfully synthesized via Horner−Wadsworth−Emmons (HWE) olefination and Sonogashira coupling reaction. Moreover, differen…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Structural, dynamic, and electronic properties of liquid tin: An ab initio molecular dynamics study

Lázaro Calderín、D. J. González、L. González 等 4 位作者2008-11-18The Journal of Chemical Physics

We report on a study of several structural, dynamic, and electronic properties of liquid Sn at a thermodynamic state close to the triple point (573 K) and another one at a higher temperature (1273 K). This study has been performed by ab initio molecular dynamics simulations using 205 atoms and around 20 ps of simulati…

Material Dynamics and PropertiesGlass properties and applicationsThermodynamic and Structural Properties of Metals and Alloys

Self‐Assembly and Metallization of Resorcinarene Microtubes in Water

Yan Sun、Chao‐Guo Yan、Yong Yao 等 5 位作者2008-11-18Advanced Functional Materials

Abstract Amphiphilic resorcinarene‐based multiwalled microtubes, millimetres in diameter and centimetres in length, are generated in water. The thickness of the tube wall approaches 300 nm. Their self‐assembly properties are investigated using transmission electron microscopy, scanning electron microscopy, atomic‐forc…

Supramolecular Chemistry and ComplexesSupramolecular Self-Assembly in MaterialsAdvanced Materials and Mechanics

Constructing explicit magnetic analogies for the dynamics of glass forming liquids

Jacob D. Stevenson、Aleksandra M. Walczak、Randall W. Hall 等 4 位作者2008-11-18The Journal of Chemical Physics

By defining a spatially varying replica overlap parameter for a supercooled liquid referenced to an ensemble of fiducial liquid state configurations, we explicitly construct a constrained replica free energy functional that maps directly onto an Ising Hamiltonian with both random fields and random interactions whose s…

Material Dynamics and PropertiesTheoretical and Computational PhysicsComplex Systems and Time Series Analysis

Inhibition and Promotion of Copper Corrosion by CTAB in a Microreactor System

Caroline Mukiri Murira、Christian Punckt、Hannes C. Schniepp 等 5 位作者2008-11-18Langmuir

We report on an optical microscopy technique for the analysis of corrosion kinetics of metal thin films in microreactor systems and use it to study the role of cetyltrimethylammonium bromide surfactant as a corrosion inhibitor in a copper-gold galvanic coplanar microsystem. A minimum in the dissolution rate of copper…

Corrosion Behavior and InhibitionElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Dynamic admittance of carbon nanotube-based molecular electronic devices and their equivalent electric circuit

ChiYung Yam、Yan Mo、Fan Wang 等 9 位作者2008-11-18Nanotechnology

We use first-principles quantum mechanics to simulate the transient electrical response through carbon nanotube-based conductors under time-dependent bias voltages. The dynamic admittance and time-dependent charge distribution are reported and analyzed. We find that the electrical response of these two-terminal molecu…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresMechanical and Optical Resonators

Cocrystallization Phenomenon between the H and D Species of Isotactic Polypropylene Blends As Revealed by Thermal and Infrared Spectroscopic Analyses for a Series of D/H Blend Samples

Kummetha Raghunatha Reddy、Kohji Tashiro、Takashi Sakurai 等 4 位作者2008-11-18Macromolecules

Cocrystallization phenomenon between the hydrogenous (H) and deuterated (D) species of a series of isotactic polypropylene blends with various D/H contents has been established for the first time on the basis of the detailed analysis of thermal and infrared spectral data for both α1 and α2 crystalline forms, where the…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Ultrafast Exciton Dephasing in Semiconducting Single-Walled Carbon Nanotubes

Ying‐Zhong Ma、Matt W. Graham、Graham R. Fleming 等 5 位作者2008-11-18Physical Review Letters

Femtosecond two-pulse degenerate four-wave mixing spectroscopy was applied to study the exciton dephasing in a broad range of excitation intensities and lattice temperatures. We find that both exciton-exciton and exciton-phonon scattering have profound effects on the dephasing process. The dominant phonon mode involve…

Carbon Nanotubes in CompositesSilicon Nanostructures and PhotoluminescenceMechanical and Optical Resonators

Temperature stability of proteins essential for the intracellular survival of Mycobacterium tuberculosis

Nathan A. Lack、Akane Kawamura、Elizabeth Fullam 等 9 位作者2008-11-18Biochemical Journal

In Mycobacterium tuberculosis, the genes hsaD (2-hydroxy-6-oxo-6-phenylhexa-2,4-dienoic acid hydrolase) and nat (arylamine N-acetyltransferase) are essential for survival inside of host macrophages. These genes act as an operon and have been suggested to be involved in cholesterol metabolism. However, the role of NAT…

Pharmacogenetics and Drug MetabolismEnzyme Structure and FunctionSteroid Chemistry and Biochemistry

Absorption Enhancement and Conformational Control of Peptides by Small Silver Clusters

Thibault Tabarin、Alexander Kulesza、Rodolphe Antoine 等 7 位作者2008-11-18Physical Review Letters

We explored experimentally and theoretically the optical properties of isolated silver trimer-dipeptide bioconjugates. The metallic moiety induces a strong enhancement of the optical absorption of the peptide. We also show that its binding to a peptide can reduce the conformational flexibility and induce transitions b…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresNanocluster Synthesis and Applications

Influence of electric fields on spin waves in simple ferromagnets: Role of the flexoelectric interaction

D. L. Mills、I. E. Dzyaloshinskiǐ2008-11-18Physical Review B

We discuss the influence of electric fields on spin waves in simple ferromagnets produced by the flexoelectric interaction. Such terms produce a frequency shift that is linear in both the applied electric field and the wave vector of the spin waves. Above a certain critical electrical field, ferromagnetism is unstable…

Physics of Superconductivity and MagnetismMultiferroics and related materialsNonlocal and gradient elasticity in micro/nano structures

Colloidal Ordering on a 2D Quasicrystalline Substrate

Michael Schmiedeberg、Holger Stark2008-11-18Physical Review Letters

By using Monte Carlo simulations, we study the complex phase behavior of charged-stabilized colloidal particles in a two-dimensional substrate potential with quasicrystalline decagonal symmetry. In the regime where the strengths of the substrate and colloidal pair potential are comparable, we identify a novel and unex…

Material Dynamics and PropertiesTheoretical and Computational PhysicsQuasicrystal Structures and Properties

Structural Instabilities in Lamellar Diblock Copolymer Thin Films During Solvent Vapor Uptake

Christine M. Papadakis、Zhenyu Di、Dorthe Posselt 等 4 位作者2008-11-18Langmuir

We have studied the structural rearrangements in a lamellae-forming poly(styrene-b-butadiene) film during exposure to toluene vapor. Real-time, in situ grazing-incidence small-angle X-ray scattering allowed us to identify distinct kinetic regimes: First, the lamellae swell linearly, and the blocks stretch uniaxially.…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Preparation of chitosan–polyethylene glycol coated cotton membranes for wound dressings: preparation and characterization

Bhuvanesh Gupta、Abha Arora、Shalini Saxena 等 4 位作者2008-11-18Polymers for Advanced Technologies

Abstract Cotton fabric was coated with chitosan (CS) and polyethylene glycol (PEG) followed by freeze‐drying. The influence of PEG on the physical characteristics and the surface morphology was investigated. The scanning electron microscopy of the coated fabric revealed a porous structure. The porosity of the material…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesMicroplastics and Plastic Pollution