Materials Literature
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Summary In soils in general, the cation exchange capacity is an important factor in soil fertility because it determines both cation retention and selectivity, and in turn controls most of the other soil properties. The main goal of this paper was to estimate the cation exchange capacity (CEC) and the contribution of…
We study the kinetics of domain growth of fluid mixtures quenched from a disordered to a lamellar phase. At low viscosities, in two dimensions, when hydrodynamic modes become important, dynamical scaling is verified in the form C ( k , t ) ∼ L α f [( k − k M ) L ], where C is the structure factor with maximum at k M a…
We study a system of colloidal spheres with induced magnetic dipoles confined in two-dimensional (2D) hard-wall channels using Brownian dynamics simulations. The external magnetic field is directed normal to the 2D plane and therefore the colloids interact with a purely repulsive r(-3) potential. The effects of confin…
Wautersia eutropha H16 (formerly Ralstonia eutropha) mobilizes intracellularly accumulated poly(3-hydroxybutyrate) (PHB) with intracellular poly(3-hydroxybutyrate) depolymerases. In this study, a novel intracellular 3-hydroxybutyrate-oligomer hydrolase (PhaZc) gene was cloned and overexpressed in Escherichia coli. The…
Riesenspins: Die Strukturen der gemischtvalenten {MnIII20−xMnIIx}-Käfigkomplexe (x=2–6) entsprechen einem Fragment des kubisch-dichtgepackten Gitters (siehe Bild; Mn große Kugeln, O kleine Kugeln). Magnetismusuntersuchungen ergaben für den Käfig mit x=2 bei schwachem Feld einen Grundzustandsspin S von 19±1, der bei st…
The orientation dependence of the free induction decay (FID) of 1H NMR water signal in ex vivo bovine digital flexor tendon at the native level of hydration is reported. Residual dipolar coupling due to the overall tissue anisotropy produces a 6:1 change in the signal intensity as an angle between the long axis of a s…
Abstract Novel polycarbonates, with pendant functional groups, based on 1,4:3,6‐dianhydrohexitols and L ‐tartaric acid derivatives were synthesized. Solution polycondensations of 1,4:3,6‐dianhydro‐bis‐ O ‐( p ‐nitrophenoxycarbonyl)hexitols and 2,3‐di‐ O ‐methyl‐ L ‐threitol or 2,3‐ O ‐isopropylidene‐ L ‐threitol affor…
Abstract For Abstract see ChemInform Abstract in Full Text.
The fundamental temperature-dependent parameters of a thermoelectric module (TEM), such as Seebeck coefficient, electrical resistance, thermal conductance, and figure-of-merit are necessary, among other factors, for conception of models for this type of devices. This paper presents a new methodology to experimentally…
Surface-enhanced Raman scattering spectra of chemical and biological agent simulants, such as dimethyl methylphonate, pinacolyl methylphosphonate, diethyl phosphoramidate, 2-chloroethyl ethylsulfide, bacillus globigii, erwinia herbicola, and bacillus thuringiensis were obtained from silver-oxide film-deposited substra…
The field acceleration factor (/spl gamma/) for the E-model of time-dependent dielectric breakdown (TDDB) in various Cu interconnect structures has been studied. The /spl gamma/ for pSiCN structures is larger than that of pSiN structures and independent of the kind of interlayer dielectric material or other processes…
Materials exhibiting low-field magnetoelectric and magnetodielectric (MD) effects are necessary for utilization of these effects in multifunctional devices. Since large magnetic fields (H) or electric fields (E) are required to produce any significant effect in existing single-phase magnetoelectrics, recent efforts ha…
The synthesis of silica, silver bromide, and composite nanospheres made in the presence of block copolypeptide vesicles is reported. Hollow silica nanospheres of controllable size can be made with Lys:Phe 1:1 block copolypeptides, whereas at higher block ratios, uniform silica nanospheres are formed that are not hollo…
Refinement of the structural model of silk I (the structure of Bombyx mori silk fibroin before spinning in the solid state) proposed previously was performed on the basis of a detailed analysis of the 13 C solid-state NMR data using two-dimensional (2D) spin-diffusion NMR and REDOR of stable isotope-labeled (AG) 15, c…
The mononuclear diamagnetic compound {Fe(bztpen)[N(CN)2]}(PF6)CH3OH (1) (bztpen = N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethylenediamine) has been synthesized and its crystal structure studied. Complex 1 can be considered to be the formal precursor of two new dinuclear, dicyanamide-bridged iron(II) complexes with the g…
Crystalline ZnO nanowires were grown on sapphire and silicon substrates using pulsed-laser deposition. The optical properties of nanowire nanolasers, including their absolute light emission intensity and external and internal quantum efficiencies were experimentally determined. The external differential quantum effici…
We study shape and buckling transitions of particle-laden sessile and pendant droplets that are forced to shrink in size. Monodisperse polystyrene particles were placed at the interface between water and decane at conditions that are known to produce hexagonal, crystalline arrangements on flat interfaces. As the volum…
Currently, nanowire-based circuits are being considered as candidates for future high-speed electronics. Signal propagation in metallic carbon nanotubes has been analyzed using the Luttinger liquid theory to develop a transmission-line model showing features that can not be obtained from conventional transmission-line…
It is demonstrated both theoretically and experimentally that the spin chirality associated with a noncoplanar spin configuration produces a magneto-optical effect. Numerical study of the two-band Hubbard model on a triangle cluster shows that the optical Hall conductivity $σ_{xy}(ω)$ is proportional to the spin chira…
Epitaxial trilayer structures consisting of two antifferomagnetic charge/orbital order insulators Pr0.5Ca0.5MnO3 (PCMO) and La0.5Ca0.5MnO3 (LCMO) are grown on (001)-oriented SrTiO3 and LaAlO3 substrates. In this trilayer series, a thin film of LCMO with various thicknesses is sandwiched between the two fixed thickness…