Materials Literature
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In nuclear borosilicate glasses, when molybdenum is in too high concentration and when it combines with other elements such as alkali and alkaline‐earth elements it may form crystalline molybdates, including sodium molybdate, Na 2 MoO 4 , during melt cooling. In a nuclear vitrification context, the origin of this phen…
A localized dielectric breakdown model with good universality is introduced to explain the pore initiation, separation and growth processes of nanoporous and nanotubular anodic metal oxides. It is suggested that the degree of localized dielectric breakdown, which is mainly determined by the dielectric strength and ene…
Nitrites dominate! Nitrites and nitrates are formed on the catalyst surface upon storage of NOx over a model Pt–Ba/Al2O3 NOx storage–reduction catalyst. Nitrites are formed through the oxidation of NO at the Pt–Ba interface (nitrite route), while nitrates are formed upon nitrite oxidation and/or NO2 adsorption followi…
Let it grow: The conjugated polymer poly(3,4-ethylenedioxythiophene) (PEDOT) was synthesized with heparin as the counterion to form a cell culture substrate. The surface of PEDOT:heparin in the neutral state associated biologically active growth factors. Electrochemical in situ oxidation of PEDOT during live cell cult…
We demonstrate how combinatorial atmospheric pressure chemical vapor deposition (cAPCVD) can be used as a synthetic tool for rapidly optimizing the functional properties of thin-films, by analyzing the self-cleaning properties of tungsten doped anatase as an example. By introducing reagents at separate points inside t…
The industrial importance of penetrable and/or impenetrable polymer systems is evident when one faces with a huge number of publications considering various aspects of diffusion phenomenon. Strong worldwide interest to realize more details about the fundamental of the process, generalize the governed laws to new findi…
Surface Fe ensembles, surface alloyed Fe atoms, and subsurface Fe species have been identified at Pt surfaces on the basis of studies in Fe–Pt(111) model systems and supported Pt–Fe nanoparticles (NPs). The surface Fe ensemble changes to ferrous oxide and forms a highly active and stable “FeO-on-Pt” structure in prefe…
Formyl groups at 6- and 2,6-positions initiated Knoevenagel reactions of the methyl groups at the 7, and 1,7-positions of 1,3,5,7-tetramethyl BODIPY dyes with aromatic aldehydes. Formation of vinyl bonds at the 7-, and 1,7-positions facilitates further Knoevenagel reactions of the methyl groups at the 3,5-positions. T…
Thickness is a very important parameter to control the microstructures, as well as physical properties in the multiferroic BiFeO 3 thin films. In this article, BiFeO 3 thin films with different thickness (from 210 to 830 nm) are fabricated by chemical solution deposition on the Pt/Ti/SiO 2 /Si (100) substrates to inve…
We present here an overview of the Fourier-transform scanning tunnelling spectroscopy technique (FT-STS). This technique allows one to probe the electronic properties of a two-dimensional system by analysing the standing waves formed in the vicinity of defects. We review both the experimental and theoretical aspects o…
The strength of siro-, solo-, compact-, and conventional ring-spun yarns has been examined with reference to yarn migration parameters, spinning-in-coefficient, number of broken fibers, and yarn hairiness. The measured results are presented in the forms of diagrams and tables. Results reveal that at various levels of…
We report the rational synthesis of one-dimensional SnO(2) nanowires (SnO(2)NWs) via a Sn-catalyzed vapor-liquid-solid (VLS) growth mechanism, in which Sn nanoparticles can direct the oriented growth of SnO(2)NWs at high temperature. I-V measurement of a field effect transistor made of individual SnO(2)NWs exhibits ty…
Ultrasmall FeCo-graphitic carbon shell nanocrystals (FeCo/GC) are promising multifunctional materials capable of highly efficient drug delivery in vitro and magnetic resonance imaging in vivo. In this work, we demonstrate the use of FeCo/GC for highly effective cancer therapy through combined drug delivery, tumor-sele…
The optical properties of alloyed Ag–Au 147-atom cuboctahedral nanoclusters are theoretically investigated as a function of composition and chemical ordering via a time-dependent density functional theory (TDDFT) approach. Compositions 37–63%, 46–54%, and 63–37%, in Ag–Au, and three types of chemical ordering, core–sh…
[FeL2][BF4]2·2H2O (L = 2,6-di{5-methylpyrazol-3-yl}pyridine) adopts a 1 : 1 high : low spin state population, and can be converted into different high-spin anhydrous phases by recrystallisation (phase 1AA) or by thermal dehydration (phase 1BB). Upon cooling in vacuo, the latter undergoes a thermal spin-state transitio…
Immobilized biomineralizing protein Mms6 templates the formation of uniform magnetite nanoparticles in situ when selectively patterned onto a surface. Magnetic force microscopy shows that the stable magnetite particles maintain their magnetic orientation at room temperature, and may be exchange coupled. This precision…
We investigate the electronic density redistribution of rotated bilayer graphene under a perpendicular electric field, showing that the layers are actually coupled even for large angles. This layer-layer coupling is evidenced by the charge transfer on these structures as a function of the external voltage. We find an…
The 2010 Nobel Prize in physics was awarded to Professors Andre Geim and Konstantin Novoselov for their ground-breaking experiments on graphene, a single atomic layer of carbon, and more generally, for their pioneering work in uncovering a new class of materials, namely two-dimensional atomic crystals. This paper give…
Context. The properties of hydrogenated amorphous carbon (a-C:H) dust are known to evolve in response to the local conditions.
Surface-initiated photoiniferter-mediated polymerization (SI-PIMP) offers great promise for many applications primarily due to it lacking the requirement of a toxic catalyst as well as not being limited to specific types of monomers. In this work, zwitterionic carboxybetaine (pCB) polymer thin films with uniform and c…