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Substrate-Dependent Aggregation and Energy Transfer in Langmuir−Blodgett Films of 5-(4-N-Octadecylpyridyl)-10,15,20-tri-p-tolylporphyrin Studied by Ultraviolet−Visible and Fluorescence Spectroscopies

Zhijun Zhang、A. L. Verma、Kenichi Nakashima 等 6 位作者1997-10-01Langmuir

Substrate-dependent energy transfer and aggregation in Langmuir−Blodgett (LB) films of 5-(4- N -octadecylpyridyl)-10,15,20-tri- p -tolylporphyrin (porphyrin 338a) have been investigated by ultraviolet−visible (UV−vis) and fluorescence spectroscopies. It has been found that the porphyrin molecules form different kinds…

Photosynthetic Processes and MechanismsLipid Membrane Structure and BehaviorPorphyrin and Phthalocyanine Chemistry

Ultrahigh-sensitive AlGaAs-GaAs punchthrough heterojunction phototransistor

Han Dejun、Guohui Li、Feng Yan 等 4 位作者1997-10-01IEEE Photonics Technology Letters

An avalanche enhanced AlGaAs-GaAs punchthrough heterojunction phototransistor with an improved guard-ring emitter structure has been proposed. It has demonstrated a record high sensitivity of 5790 A/W and optical conversion gain of 10810 at 400-nW incident optical power level. Its novel guard-ring emitter structure ca…

Semiconductor Quantum Structures and DevicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Crosslinking characterization of a polyimide: AFR700B

John D. Russell、J. L. Kardos1997-10-01Polymer Composites

Abstract Crosslinking in AFR700B polyimide was studied using several techniques. Crosslinking could not be detected using Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC). Swelling in n‐methyl pyrrolidone (NMP) showed network formation occurs at cure temperatures ≥325°C (617°F…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Synthese und XPS‐Analyse von nano‐skaligen Metall/Metalloxid‐Kompositen mit Germanium, Zinn und Blei als metallische Komponente

Michael Veith、S. Kneip、A. Jungmann 等 4 位作者1997-10-01Zeitschrift für anorganische und allgemeine Chemie

Abstract tert‐Butanolate von Germanium(II), Zinn(II) und Blei(II) der Formel {M[OC(CH 3 ) 3 ] 2 } n (M  Ge, n = 2; M  Sn, n = 2; M  Pb, n = 3) sowie die entsprechenden Heterometallalkoxide M′M 2 [O‐C(CH 3 ) 3 ] 6 (M  Ge, M′  Sr, Ba; M  Sn, M′  Ca, Sr, Ba; M  Pb, M′  Ca, Ba) wurden in einem CVD‐Prozeß (Chemic…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisSilicone and Siloxane Chemistry

Plasma-ion-assisted deposition: a powerful technology for the production of optical coatings

Alfons Zoeller、Rainer Goetzelmann、Harro Hagedorn 等 5 位作者1997-10-01Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Plasma-IAD with the APS (advanced plasma source) has been introduced into the market in 1992. Up to now this technique is used worldwide in almost 100 coating systems. A large number of different layer systems has been investigated in R&D and applied in production. For ophthalmic applications plasma-IAD with the APS i…

Metal and Thin Film MechanicsOptical Coatings and GratingsSurface Roughness and Optical Measurements

Poly[poly(isobornyl methacrylate-co-methyl methacrylate) (poly(IBMA-co-MMA))-b-polybutadiene-b-poly(IBMA-co-MMA)] Copolymers: Synthesis, Morphology, and Properties

Jie Yu、Philippe Dúbois、R. Jérôme1997-10-01Macromolecules

Anionic random and block copolymerization of isobornyl methacrylate (IBMA) and methyl methacrylate (MMA) has been studied in THF at −78 °C by using (1,1-diphenyl-3,3-dimethylbutyl)lithium (DDBLi) as initiator in the presence of LiCl. The random copolymerization of MMA and IBMA has also been carried out at 0 °C, all th…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and Properties

Application of the Horner-Wadsworth-Emmons Reaction to the Functionalization of Dendrimers: Synthesis of Amino Acid Terminated Dendrimers

Delphine Prévôté、Sylvie Le Roy-Gourvennec、Anne‐Marie Caminade 等 5 位作者1997-10-01Synthesis

All articles of this category The Horner-Wadsworth-Emmons reaction of the first, third and fourth generation of aldehyde terminated dendrimers 1-[Gn] ( n =1: 6 CHO, n =3:24 CHO, n =4:48 CHO groups, respectively) with phosphonates unsubstituted at the carbon α to the phosphoryl group 2a-i affords in moderate yield dend…

Chemical Synthesis and AnalysisDendrimers and Hyperbranched PolymersOrganophosphorus compounds synthesis

In Situ Optical Interferometric Studies of the Growth and Dissolution Behavior of Paracetamol (Acetaminophen) Crystals. 3. Influence of Growth in the Presence of p-Acetoxyacetanilide

Boris Y. Shekunov、David Grant、R.J. Latham 等 4 位作者1997-10-01The Journal of Physical Chemistry B

The influence of p -acetoxyacetanilide (PAA) as an additive in the surrounding paracetamol solution was investigated during growth and dissolution of paracetamol crystals. The different crystal faces of paracetamol, {110}, {201̄}, and {001}, exhibited two different mechanisms of interaction with the additive. Accordin…

Crystallography and molecular interactionsSolidification and crystal growth phenomenaCrystallization and Solubility Studies

Diagnosis of precipitate formation in pulsed-laser deposition ofYBa2Cu3O7−δby means ofin situlaser-light scattering andex situatomic force microscopy

Naoki Kanda、M. Kawasaki、Toshikazu Kitajima 等 4 位作者1997-10-01Physical review. B, Condensed matter

We have developed a technique using laser-light scattering for monitoring and controlling precipitate formation during pulsed-laser deposition of ${\mathrm{YBa}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\delta}}}$ (YBCO) films. By laser ablating a stoichiometric YBCO target under o…

Physics of Superconductivity and MagnetismZnO doping and propertiesElectronic and Structural Properties of Oxides

Meso‐Tetraphenylporphyrin Dimer Derivative as a Potential Photosensitizer in Photodynamic Therapy

M. Amparo F. Faustino、Maria G. P. M. S. Neves、M. Graça H. Vicente 等 7 位作者1997-10-01Photochemistry and Photobiology

Studies on the synthesis, preliminary in vivo biological activity, singlet oxygen and fluorescence yields of a dimeric porphyrin (D1) are described. The pharmacokinetic behavior and photodynamic properties of the dimer D1 were examined in Balb/c mice bearing an MS-2 fibrosarcoma. Compound D1 shows a high selectivity f…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Recent case histories of food product ‐metal container interactions using scanning electron microscopy‐x‐ray microanalysis

James E. Charbonneau1997-10-01Scanning

Scanning electron microscopy (SEM) and x-ray microanalysis (EDS) were used to investigate stress corrosion cracking (SCC) in plain tinplate food cans, product discoloration, filiform corrosion, pitting/perforation corrosion, and loss of coating adhesion in enameled food cans. Intergranular SCC of uncoated tinplate occ…

Corrosion Behavior and InhibitionCultural Heritage Materials Analysis

Electrochemical and Spectroelectrochemical Properties of SnO2 and SnO2 / Mo Transparent Electrodes with High Ion‐Storage Capacity

Urša Opara Krašovec、Boris Orel、Stanko Hočevar 等 4 位作者1997-10-01Journal of The Electrochemical Society

Thin solid SnO 2 and SnO 2 / Mo (10%, 2:1 and 1:1) films with an ion‐storage capacity of 20 to 30 mC/cm 2 and weakly expressed cathodic electrochromism were deposited using the dip‐coating technique. The films were deposited from peroxo sols prepared by reacting SnCl 2 ⋅ 2 H 2 O and a metallic molybdenum precursor wit…

Gas Sensing Nanomaterials and SensorsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Polymer-Stabilized Ferroelectric Liquid Crystal Devices with Grayscale Memory

Hideo Fujikake、Kuniharu Takizawa、Hiroshi Kikuchi 等 6 位作者1997-10-01Japanese Journal of Applied Physics

A novel grayscale-memory ferroelectric liquid crystal device with polymer dispersion has been studied. The ferroelectric liquid crystal molecules are stabilized by a low-concentration doped polymer, which induces an enormous number of small liquid crystal domains with different threshold voltages for bistable switchin…

Liquid Crystal Research AdvancementsPhotorefractive and Nonlinear OpticsPhase-change materials and chalcogenides

Mechanical Behavior at 20° and 1200°C of Nicalon‐Silicon‐Carbide‐Fiber‐Reinforced Alumina‐Matrix Composites

Jose Antonio Celemaín、J.Y. Pastor、Javier LLorca 等 4 位作者1997-10-01Journal of the American Ceramic Society

Tensile and fracture tests were conducted at 20° and 1200°C on a ceramic‐matrix composite that was composed of an alumina (Al 2 O 3 ) matrix that was bidirectionally reinforced with 37 vol% silicon carbide (SiC) Nicalon fibers. The composite presented nonlinear behavior at both temperatures; however, the strength and…

Advanced ceramic materials synthesisInnovative concrete reinforcement materialsAluminum Alloys Composites Properties

Kinetic studies of the inhibitory effects of propeptides subtilisin BPN' and Carlsberg to bacterial serine proteases

Hongbo Huang、Wen‐Chin Chen、Chun-Ying Wu 等 7 位作者1997-10-01Protein Engineering Design and Selection

The propeptides of bacterial subtilisin BPN' and Carlsberg were synthesized to investigate their inhibitory function on the enzymes. Kinetically, pro-BPN' inhibits the proteolytic activities of subtilisin BPN' and Carlsberg separately in a slow binding mode. Pro-Carlsberg behaves as a typical rapid equilibrium competi…

Enzyme Structure and FunctionEnzyme Production and CharacterizationBiochemical and Structural Characterization

A PROCEDURE TO SELECT THE BEST MATERIAL COMBINATIONS AND OPTIMALLY DESIGN HYBRID COMPOSITE PLATES FOR MINIMUM WEIGHT AND COST

Martin Walker、T. Reiss、Sarp Adali1997-10-01Engineering Optimization

The optimal layup with least weight or cost for a symmetrically laminated plate subject to a buckling load is determined using a hybrid composite construction. A hybrid construction provides further tailoring capabilities and can meet the weight, cost and strength constraints while a non-hybrid construction may fail t…

Material Properties and Applications

Magnetism of Nanometer-Scale Graphite with Edge or Topological Defects

Koichi Kusakabe、Katsunori Wakabayashi、Masatsura Igami 等 5 位作者1997-10-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

Magnetic structure is studied for several π-networks of graphite-like structures with edge and/or topological defects using the tight-binding model (the Hückel model). Zigzag-edged graphite have edge states, which form a partly flat band at the Fermi energy. Short range repulsion (the Hubbard U) is enough to induce hu…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Salt-Controlled Lamellar Spacing in Ionically End-Capped Symmetric Diblock Copolymers

Volker Schädler、Ulrich Wiesner1997-10-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTSalt-Controlled Lamellar Spacing in Ionically End-Capped Symmetric Diblock CopolymersVolker Schädler and Ulrich WiesnerView Author Information Max-Planck-Institut für Polymerforschung, Postfach 3148, D-55021 Mainz, Germany Cite this…

Theoretical and Computational PhysicsBlock Copolymer Self-AssemblyNanopore and Nanochannel Transport Studies

Polymers under mechanical stress: Deformation of the nanostructure of isotactic polypropylene revealed by scanning force microscopy

Gilles Castelein、G. Coulon、C. G’Sell1997-10-01Polymer Engineering and Science

Abstract Scanning force microscopy (SFM) was used to study the lamellar morphology of α and β spherulites in bulk intruded isotactic polypropylene (iPP) samples deformed under shear stress. The iPP specimens were sheared at a constant shear rate at room temperature. Just beyond yielding, at a shear strain level of 0.5…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Crystallization of Syndiotactic Polystyrene in β-Form. 3. Energetic Analysis of the Incorporation Mechanism of Stacking Faults into the Crystal

Masatoshi Tosaka、Noritaka Hamada、Masaki Tsuji 等 4 位作者1997-10-01Macromolecules

Crystallization-temperature ( T c ) dependence of the probability of the presence of stacking faults, p, in the solution-grown β-form single crystal of syndiotactic polystyrene (s-PS) was analyzed on the basis of the growth theory of the polymer crystal. By comparing the experimentally obtained T c dependence of p wit…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties