Materials Literature
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We present a comparative study of the coupled-tetrahedra quantum spin systems Cu2Te2O5X2, X=Cl, Br (Cu-2252(X)) and the newly synthesized Cu4Te5O12Cl4 (Cu-45124(Cl)) based on ab initio Density Functional Theory calculations. The magnetic behavior of Cu-45124(Cl) with a phase transition to an ordered state at a lower c…
We theoretically study transport properties of a two-dimensional electron system on a hydrogen-passivated Si(111) surface in the field-effect-transistor (FET) configuration. We calculate the density and temperature dependent mobility and resistivity for the recently fabricated Si(111)-vacuum FET by using a semiclassic…
Incoherent surface scattering yields a statistical description of the surface, due to the ensemble averaging over many independently sampled volumes. Depending on the state of the surface and direction of the scattering vector relative to the surface normal, the height distribution is discrete, continuous, or a combin…
In the framework of the generalized mean field theory, conditions for arising the ferromagnetic state in a two-dimensional diluted magnetic semiconductor and the features of that state are defined. RKKY-interaction of magnetic impurities is supposed. The spatial disorder of their arrangement and temperature alteration…
The equilibrium texture of nematic shells is studied as a function of their thickness. For ultrathin shells the ground state has four short 1/2 disclination lines but, as the thickness of the film increases, a three-dimensional escaped configuration composed of two pairs of half-hedgehogs becomes energetically favorab…
WO3 thin layers with nanometer-scale periodicity were prepared by evaporation-induced self-assembly (EISA) using a novel amphiphilic block-copolymer template (poly(ethylene-co-butylene)-block-poly(ethylene oxide)). The evolution of the mesoporous ordered network and the crystallinity of the framework were monitored by…
Using an effective low-energy Hamiltonian derived from the first-principles electronic structure calculations for the narrow $t_{2g}$ bands of YTiO$_3$, LaTiO$_3$, YVO$_3$, and LaVO$_3$, we evaluate the contributions of the correlation energy ($E_C$) to the stability of different magnetic structures, which can be real…
Mercury-Sensitized Photo-Assisted Chemical Vapor Deposition (Hg-Photo-CVD) technique opens new possibilities for reducing thin film growth temperature and producing novel semiconductor materials suitable for the future generation of high efficiency thin film solar cells onto low cost flexible plastic substrates. This…
Temperature-dependent infrared reflectivity spectra of SrFe$_{4}$Sb$_{12}$ has been measured. A renormalized Drude peak with a heavy effective mass and a pronounced pseudogap of 10 meV develops in the optical conductivity spectra at low temperatures. As the temperature decreases below 100 K, the effective mass ($m^{*}…
Mercury-Sensitized Photo-Assisted Chemical Vapor Deposition (Hg-Photo-CVD) technique opens new possibilities for reducing thin film growth temperature and producing novel semiconductor materials suitable for the future generation of high efficiency thin film solar cells onto low cost flexible plastic substrates. This…
We report on the design, fabrication, and implementation of ultrasensitive micromechanical oscillators. Our ultrathin single-crystal silicon cantilevers with integrated magnetic structures are the first of their kind: They are fabricated using a novel high-yield process in which magnetic film patterning and deposition…
We examine the application of short-circuit electrical boundary conditions in density-functional theory calculations of ferroelectric thin films. Modeling $\mathrm{Pb}\mathrm{Ti}{\mathrm{O}}_{3}$ films with metallic electrodes, we demonstrate that under periodic boundary conditions of supercells, short-circuit conditi…
Biodegradable hollow capsules encapsulating proteins were prepared via layer-by-layer assembly of chitosan and dextran sulfate on protein-entrapping mesoporous silica particles and the subsequent removal of the silica. The enzymatic degradation of the capsules in the presence of chitosanase was explored by scanning el…
The 1H NMR study of supramolecular gels formed by two organogelators derived from valine is described. The analysis of the variation of chemical shift values and relaxation times in the gel samples reveals that in these systems only discrete species are observed by 1H NMR. The reduced T2 values and negative NOEs that…
Simple and effective biocompatible materials that mimic the natural extracellular matrix (ECM) were developed for a variety of uses in regenerative medicine. These synthetic ECMs (sECMs) were designed to recapitulate the minimal composition required to obtain functional ECMs. The sECM components are crosslinkable in s…
Abstract Electrospun polypropylene fiber webs and laminates were developed using melt‐electrospinning, to explore an alternative way of manufacturing protective clothing materials for agricultural workers. Electrospun polypropylene webs were fabricated in two levels of thickness. To examine the effect of lamination on…
Alloy nanocrystals provide an additional degree of freedom in selecting desirable properties for nanoscale engineering because their physical and optical properties depend on both size and composition. We report the pyrolytic synthesis of homogeneously alloyed CdS(x)Se(1-x) nanocrystals in all proportions. The nanocry…
This paper presents an experimental study on employing a pellet form of catalyst in photo-reduction of carbon dioxide with water. Water was first absorbed into titania pellets. Highly purified carbon dioxide gas was then discharged into a reactor containing the wet pellets, which were then illuminated continuously for…
We report the neutral-ionic transformation of ${\mathrm{N}}_{2}∕{\mathrm{O}}_{2}$ mixtures above $5\phantom{\rule{0.3em}{0ex}}\mathrm{GPa}$ at $300\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. The reaction is photoinduced with a Nd:YAG laser irradiation. The ionic compounds are characterized by Raman and infrared spectrosco…
Magnetic anisotropy field of (110) Fe∕Co superlattices was found to be as high as 1T, with an in-plane easy axis. First principles calculations within the local spin density approximation show good agreement with the measurement. Lowering the symmetry by creating artificial superlattice structures leads to a significa…