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3-D TiO 2 nanoparticle/ITO nanowire nanocomposite antenna for efficient charge collection in solid state dye-sensitized solar cells

Gill Sang Han、Sangwook Lee、Jun Hong Noh 等 9 位作者2014-01-01Nanoscale

TiO2 nanoparticle (NP)/ITO nanowire (NW) nanocomposites for use as photoelectrode materials were fabricated to improve the charge collection efficiency in solid state dye sensitized solar cells (ss-DSSCs). The average current density for ss-DSSCs containing TiO2 NP/ITO NW arrays was 7.2 mA cm(-2) that was 98% higher t…

TiO2 Photocatalysis and Solar CellsZnO doping and propertiesGas Sensing Nanomaterials and Sensors

Formation and photovoltaic performance of few-layered graphene-decorated TiO 2 nanocrystals used in dye-sensitized solar cells

Yueli Liu、Yuqing Cheng、Wei Shu 等 8 位作者2014-01-01Nanoscale

Few-layer graphene/TiO2 nanocrystal composites are successfully in situ synthesized at a low temperature of 400 °C using C28H16Br2 as the precursor. Raman mapping images show that the TiO2 nanocrystals are very uniformly dispersed in the composite films, and the in situ coating during the thermal decomposition process…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

A highly selective fluorescent probe for cadmium ions in aqueous solution and living cells

Qiaoling Liu、Lixia Feng、Caixia Yuan 等 8 位作者2014-01-01Chemical Communications

An organic salt based on double 1,3,4-oxadiazole derivatives as fluorophores and BAPTA as a receptor has been designed for detection of Cd(2+). The fluorescent probe exhibits high selectivity for Cd(2+) and a low detection limit of 20 nM in aqueous solution, making it useful for Cd(2+) imaging in living MCF-7 cells.

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Towards the elucidation of the high oxygen electroreduction activity of Pt x Y: surface science and electrochemical studies of Y/Pt(111)

T. P. Johansson、Elisabeth Therese Ulrikkeholm、P. Hernández-Fernández 等 7 位作者2014-01-01Physical Chemistry Chemical Physics

We have prepared an yttrium modified Pt(111) single crystal under ultra-high vacuum conditions, simulating a bulk alloy. A Pt overlayer is formed upon annealing the crystal above 800 K. The annealed structure binds CO weaker than Pt(111), with a pronounced peak at 295 K in the temperature programmed desorption of CO.…

Advanced Chemical Physics StudiesElectrocatalysts for Energy ConversionHydrogen Storage and Materials

OBTAINING NANOCELLULOSE FROM GREEN COCONUT FIBERS AND INCORPORATION IN BIODEGRADABLE FILMS OF STARCH PLASTICIZED WITH GLYCEROL

Bruna Aparecida Souza Machado、João H. O. Reis、Jania B. da Silva 等 7 位作者2014-01-01Química Nova

Composites strengthened with nanocellulose have been developed with the aim of improving mechanical, barrier, and thermal properties of materials. This improvement is primarily due to the nanometric size and the high crystallinity of the incorporated cellulose. Cassava starch films plasticized with glycerol and incorp…

Advanced Cellulose Research StudiesCoastal Management and Development

Factors Affecting the Performance of Single-Chamber Soil Microbial Fuel Cells for Power Generation

Deng、Huan、Wu 等 14 位作者2014-01-01Acta Scientiarum Naturalium Universitatis Sunyatseni

作为燃料来源用土壤有机物影响单个房间的微生物引起的燃料房间(MFC ) 的发电的因素有有限信息。我们检验了土壤和水深度的效果,并且有阳极的土壤 MFC 的表演上的温度在覆盖的水里在充满的土壤和阴极正在被嵌入。结果证明有覆盖的深土壤和 3 厘米浇的 5 厘米的 MFC 展出了 562 mV 和 0.72 mW m2 的功率密度的最高开的电路电压。欧姆的电阻与更多的土壤和水增加了。当阳极的与更多的水增加了时,阴极的极化电阻与更多的土壤增加了。在 30 d 操作期间,房间电压断然与温度相关并且与 500 外部负担到达了 162 mV 的最大值。在操作以后,从土壤和阳极的细菌的 16S rRNA 基因被定序。在土壤的细菌比那些遵守细菌主要…

Supercapacitor Materials and FabricationMicrobial Fuel Cells and Bioremediation

Giant photogalvanic effect in noncentrosymmetric plasmonic nanoparticles

Sergei V. Zhukovsky、Viktoriia E. Babicheva、Andrey B. Evlyukhin 等 6 位作者2014-01-01Institutional Repository of Leibniz Universität Hannover (Leibniz Universität Hannover)

Photoelectric properties of noncentrosymmetric, similarly oriented metallic nanoparticles embedded in a homogeneous semiconductor matrix are theoretically studied. Because of the asymmetric shape of the nanoparticle boundary, photoelectron emission acquires a preferred direction, resulting in a photocurrent flow in th…

Gold and Silver Nanoparticles Synthesis and ApplicationsMetamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon Research

Evolution of Dissolution Media Over the Last Twenty Years

Jennifer Dressman2014-01-01Dissolution Technologies

Twenty years ago, dissolution media were used almost exclusively for quality control purposes in the pharmaceutical industry. The most common dissolution tests were for oral dosage forms, and these were approached according to the release mechanism— immediate release (IR), enteric-coated (EC) tablets, and controlled-r…

Drug Solubulity and Delivery SystemsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Water induced zinc oxide thin film formation and its transistor performance

Jingjing Chang、Kok Leong Chang、Chunyan Chi 等 5 位作者2014-01-01Journal of Materials Chemistry C

This study reports the effect of water on the formation of a zinc oxide (ZnO) thin film and the performance of ZnO thin film transistors (TFTs).

ZnO doping and propertiesThin-Film Transistor TechnologiesTransition Metal Oxide Nanomaterials

Decoupled ion conduction in poly(2-acrylamido-2-methyl-1-propane-sulfonic acid) homopolymers

Siti Aminah Mohd Noor、Jiazeng Sun、Douglas R. MacFarlane 等 6 位作者2014-01-01Journal of Materials Chemistry A

A family of novel sulfonate based homopolymers has been prepared by partially replacing sodium cations with different types of ionic liquid ammonium counter-cations, leading to an increased degree of decoupling of the conductivity from the glass transition of the ionomers.

Advanced Battery Materials and TechnologiesIonic liquids properties and applicationsConducting polymers and applications

Surface-charge accumulation effects on open-circuit voltage in organic solar cells based on photoinduced impedance analysis

Huidong Zang、Yu‐Che Hsiao、Bin Hu2014-01-01Physical Chemistry Chemical Physics

The accumulation of dissociated charge carriers plays an important role in reducing the loss occurring in organic solar cells. We find from light-assisted capacitance measurements that the charge accumulation inevitably occurred at the electrode and photovoltaic layer interface for bulk-heterojunction ITO/PEDOT:PSS/P3…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsNanowire Synthesis and Applications

Novel Testing to Study the Performance of Intumescent Coatings under Non-Standard Heating Regimes

A. Elliott、Alistair Temple、Cristián Maluk 等 4 位作者2014-01-01Fire Safety Science

Intumescent coatings (also called reactive coatings) are widely used to protect structural steel from fire. These thin coatings swell on heating to form a highly insulating char, protecting steel members and preventing them from reaching critical temperatures that could cause them to fail. As is the case for most stru…

Fire dynamics and safety researchFlame retardant materials and propertiesFire effects on concrete materials

In situ fabrication of Cu 2 ZnSnS 4 nanoflake thin films on both rigid and flexible substrates

Xuezhen Zhai、Huimin Jia、Yange Zhang 等 10 位作者2014-01-01CrystEngComm

Pure CZTS thin film is formed directly at a temperature of 250 °C, the lowest temperature of any current fabrication system, on both flexible stainless steel and rigid FTO substrates.

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Straight-forward synthesis of ringed particles

Jérôme Roche、Gabriel Loget、Dodzi Zigah 等 8 位作者2014-01-01Chemical Science

Particles with sophisticated surface patterns have many potential applications ranging from information coding to catalysis and optics. However controlled patterning of particles often requires rather complicated lithographic or template based approaches. Here we report a straightforward chemical synthesis of complex…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing TechnologiesNanofabrication and Lithography Techniques

Two-point halogen bonding between 3,6-dihalopyromellitic diimides

Dennis Cao、Michael Hong、Anthea K. Blackburn 等 6 位作者2014-01-01Chemical Science

The syntheses of several 3,6-dihalopyromellitic diimides have been achieved. Two-point intermolecular halogen–oxygen interactions—reminiscent of carboxylic acid dimers—are observed in the solid-state superstructures of (i) these molecules and (ii) their charge-transfer complexes with electron-rich naphthalenes.

Crystallography and molecular interactionsOrganic and Molecular Conductors ResearchStructural and Chemical Analysis of Organic and Inorganic Compounds

Fire Toxicity Assessment: Comparison of Asphyxiant Yields from Laboratory and Large Scale Flaming Fires

Anna A. Stec、T. Richard Hull、David Purser 等 4 位作者2014-01-01Fire Safety Science

In a fire, normally non-hazardous thermoplastic materials can produce lethal concentrations of toxic effluents in the smoke. The toxic product yields of the asphyxiants carbon monoxide (CO) and hydrogen cyanide (HCN) from developed fires are typically 10 times greater than those generated in small-scale laboratory fir…

Fire dynamics and safety researchFlame retardant materials and propertiesCombustion and Detonation Processes

Catalysis and molecular magnetism of dinuclear iron(iii) complexes with N-(2-pyridylmethyl)-iminodiethanol/-ate

Jong Won Shin、Jeong Mi Bae、Cheal Kim 等 4 位作者2014-01-01Dalton Transactions

The reaction of N-(2-pyridylmethyl)iminodiethanol (H2pmide) and Fe(NO3)3·9H2O in MeOH led to the formation of a dimeric iron(III) complex, [(Hpmide)Fe(NO3)]2(NO3)2·2CH3OH (1). Its anion-exchanged form, [(pmide)Fe(N3)]2 (2), was prepared by the reaction of 1and NaN3 in MeOH, during which the Hpmide ligand of 1 was also…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Photovoltaic enhancement of Si micro- and nanostructure solar cells via ultrafast laser texturing

Falah A.-H. Mutlak2014-01-01TURKISH JOURNAL OF PHYSICS

The purpose of the present study was to achieve laser-microtextured Si structures, the material used as silicon wafers, with a thickness of 330 mu m for a fast laser texturing technique, in order to produce micro-/nanosurface textures by means of a UV femtosecond laser. A textured silicon surface was prepared that has…

Laser Material Processing TechniquesSilicon Nanostructures and PhotoluminescenceAdvanced Surface Polishing Techniques