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Syntheses and characterization of 5-substituted hydantoins and thiazolines—implications for crystal engineering of hydrogen bonded assemblies. Crystal structures † of 5-(2-pyridylmethylene)hydantoin, 5-(2-pyridylmethylene)-2-thiohydantoin, 5-(2-pyridylmethylene)thiazolidine-2,4-dione, 5-(2-pyridylmethylene)rhodanine and 5-(2-pyridylmethylene)pseudothiohydantoin †

Mubarik M. Chowdhry、D. Michael P. Mingos、Andrew J. P. White 等 4 位作者2000-01-01Journal of the Chemical Society Perkin Transactions 1

A series of six potentially bidentate ligands composed of 5-membered heterocyclic rings with methylenepyridyl substituents are described. These molecules are potentially bifunctional, acting as bidentate ligands to metal centres whilst retaining on their periphery a range of groups capable of forming triple hydrogen b…

Metal complexes synthesis and propertiesCrystal structures of chemical compoundsMagnetism in coordination complexes

Property optimization in nitrile rubber composites via hybrid filler systems

Nihan Nugay、Burak Erman2000-01-01Journal of Applied Polymer Science

Nitrile rubber–PVC composites having carbon black and mica fillers in different compositions as hybrid reinforcements were studied. The effect of the silane treatment of mica, the degree of replacement, and the molecular architecture of nitrile rubbers on static-dynamic mechanical, swelling, and curing behavior of the…

Polymer crystallization and propertiesStructural Behavior of Reinforced ConcretePolymer Nanocomposites and Properties

Adaptive mesh generation for full-vectorial guided-mode and beam-propagation solutions

Yasuhidé Tsuji、M. Koshiba2000-01-01IEEE Journal of Selected Topics in Quantum Electronics

A simple and efficient adaptive mesh generation algorithm is proposed for the full-wave finite-element analysis of optical waveguides using edge/nodal hybrid elements. We employ a local weight defined by a difference between the fundamental and the higher order element solutions. This method can be used for both the g…

Electromagnetic Simulation and Numerical MethodsAdvanced Antenna and Metasurface TechnologiesOptical Coatings and Gratings

The influence of electrodes and conditioning on space charge accumulation in XLPE

R.J. Fleming、M. Henriksen、Joachim Holbøll2000-01-01IEEE Transactions on Dielectrics and Electrical Insulation

The accumulation of space charge in planar crosslinked polyethylene (XLPE) samples under dc electric fields at room temperature was investigated using the pulsed electroacoustic (PEA) method. Three different organic semiconductor (semicon) materials containing carbon black at concentrations /spl sim/30 %wt, and vacuum…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Infrared spectroscopy of enzyme reaction intermediates

Christopher W. Wharton2000-01-01Natural Product Reports

Abbreviations: ATP’ase, adenosine triphosphatase; IR, infrared; MRSA, methicillin-resistant Staphylococcus aureus; PBP, penicillin binding protein; pM, pH meter reading TIM, triosephosphate isomerase.

Mass Spectrometry Techniques and ApplicationsEnzyme Structure and FunctionSpectroscopy Techniques in Biomedical and Chemical Research

Vibrational spectroscopy and EXAFS study of Ti(OC2H5)4 and alcohol exchange in Ti(iso-OC3H7)4

Kim S. Finnie、Vittorio Luca、Paul D. Moran 等 5 位作者2000-01-01Journal of Materials Chemistry

The vibrational spectrum of tetraethylorthotitanate (TET) has been assigned by using vibrational and structural data from the series Ti(OEt)yCl4 − y (y = 1 to 4), to distinguish between bands due to bridging and terminally coordinated ethoxide. EXAFS studies of the series showed an increase in association with increas…

Metal complexes synthesis and propertiesMagnetism in coordination complexesThermal and Kinetic Analysis

Instruments based on shape-memory alloy properties for minimal access surgery, interventional radiology and flexible endoscopy

T. G. Frank、Wei Xu、A. Cuschieri2000-01-01Minimally Invasive Therapy & Allied Technologies

Instrumental manipulations during minimal access surgery (MAS) are limited by the four degrees of freedom (d.o.f.) possible when long instruments are introduced into the peritoneal cavity through access ports. This is in sharp contrast to an equivalent instrument held in the hand by the surgeon during open conventiona…

Shape Memory Alloy Transformations

Thermal, mechanical, and morphological properties of phenolic resin/silica hybrid ceramers

Ji-Fu Lin、C. C. M.、F. Y. Wang 等 5 位作者2000-01-01Journal of Polymer Science Part B Polymer Physics

Phenolic resin/silica hybrid ceramers were prepared through sol–gel technology. Differential scanning calorimetry and thermogravimetric analysis methods were utilized to study the thermal properties of the fabricated hybrid ceramers. The results showed that the heat resistance of the ceramers was slightly higher than…

Synthesis and properties of polymersSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Large diamonds grown at high pressure conditions

H. Kanda2000-01-01Brazilian Journal of Physics

A technique has been established to grow large diamonds up to 2 cm. The crystals are bulky polyhedron with yellow, blue, green or brown color as well as colorless, which depend on impurities. The impurities incorporated into the diamond are limited, i.e. nitrogen, boron, nickel, cobalt, silicon and phosphorus.

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Efficient photodecarboxylation of aroyl-substituted phenylacetic acids in aqueous solution: a general photochemical reaction

Musheng Xu、Peter Wan2000-01-01Chemical Communications

Photolysis (254–350 nm) of a variety of aroyl-substituted phenylacetic acids and p-acetylphenylacetic acid in aqueous solution at pH > pKa resulted in efficient photodecarboxylation (Φ = 0.2–0.7), to give in most cases a single product arising via the corresponding arylmethyl carbanion, indicating that photodecarboxyl…

Radical Photochemical ReactionsPhotochromic and Fluorescence ChemistryOxidative Organic Chemistry Reactions

Flame retardancy of some ethylene-vinyl acetate copolymer-based formulations

Joseph Zilberman、T. Richard Hull、Dennis Price 等 5 位作者2000-01-01Fire and Materials

The combustion behaviour and thermal decomposition of ethylene–vinyl acetate copolymer (EVA) (26 wt% vinyl acetate content) formulations containing alumina trihydrate, ammonium polyphosphate, melamine, pentaerythritol and their co-mixtures, were studied using cone calorimetry and thermogravimetric analysis. Formulatio…

Fire dynamics and safety researchFlame retardant materials and propertiesSynthesis and properties of polymers

Rheological and thermal properties of binary blends of polypropylene and poly(ethylene-CO-1-octene)

Ana L�cia N. Da Silva、Marisa Cristina Guimarães Rocha、Fernanda M. B. Coutinho 等 5 位作者2000-01-01Journal of Applied Polymer Science

Dynamic viscoelastic properties of binary blends consisting of an isotactic polypropylene (i-PP) and ethylene-1-octene copolymer (PEE) were investigated to reveal the relation between miscibility in the molten state and the morphology in the solid state. In this study, PEE with 24 wt % of 1-octene was employed. The PE…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Foaming and Composites

Microchannel Surface Area Enhancement Using Porous Thin Films

Kenneth D. Harris、Michael J. Brett、T. Smy 等 4 位作者2000-01-01Journal of The Electrochemical Society

Microchannels having highly enhanced surface area have been fabricated by a thin‐film deposition technique known as glancing angle deposition. Porosimetry and simulation of the microstructures was used to estimate the surface area enhancement of the new microchannels. Two distinct types of microchannels have been crea…

Metal and Thin Film MechanicsAdvancements in Photolithography TechniquesOptical Coatings and Gratings

Synthesis and functionalities of poly(N-vinylalkylamide). XII. Synthesis and thermosensitive property of poly(vinylamine) copolymer prepared from poly(N-vinylformamide-co-N-vinylisobutyramide)

Kazuya Yamamoto、Takeshi Serizawa、Yoichiro Muraoka 等 4 位作者2000-01-01Journal of Polymer Science Part A Polymer Chemistry

The differences in the polymerization abilities of N-vinylformamide (NVF) and N-vinylisobutyramide (NVIBA) and the synthesis of their copolymers were studied. The polymerization abilities were fairly good and quite similar to those of N-vinyl- acetamide (NVA), a monomer in the same class as N-vinylalkylamides. Since t…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Complex char formation in flame-retarded fibre-intumescent combinations ? IV. Mass loss and thermal barrier properties

Baljinder K. Kandola、A. Richard Horrocks2000-01-01Fire and Materials

Previously reported fibre/intumescent composite textile systems are leading to the development of a range of high performance thermal barrier fabrics. These systems comprise nonwoven cores of flame retardant cellulose/regenerated cellulose throughout which fibre-interactive intumescent chemicals (melamine and phosphat…

Electromagnetic wave absorption materialsFire dynamics and safety researchFlame retardant materials and properties

Aluminium-containing mesoporous silica films as nano-vessels for organic photochemical reactions

Makoto Ogawa、Kazuyuki Kuroda、Junichi Mori2000-01-01Chemical Communications

The adsorption of a cationic azobenzene derivative into both siliceous and aluminium containing mesoporous silica films has been investigated; photoisomerization was found to occur in the temperature range 80–300 K and the mesoporous aluminium containing silica films were proved to be useful reaction media to immobili…

Advanced Photocatalysis TechniquesMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Effect of Long-Term Irradiation on the Fracture Properties of Zr-2.5Nb Pressure Tubes

R.R. Hosbons、PH Davies、M. Griffiths 等 5 位作者2000-01-01OpenAlex

Results from fracture toughness and tensile and delayed hydride cracking (DHC) tests on Zr-2.5Nb pressure tubes removed from CANDU power reactors in the 1970s and 80s for surveillance showed considerable scatter. At that time, the cause of the scatter was unknown and prediction of fracture toughness to the end of the…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Scanning electron microscopic studies of wool/intumescent char formation

Philip Davies、A. Richard Horrocks、Mohsen Miraftab2000-01-01Polymer International

Thermal analytical studies of synthesized mixtures of powdered wool, wool/flame retardant viscose blended fibre/intumescent combinations and intumescent-coated fabrics have shown previously that while enhanced volatilization occurs during char formation below 400 °C, the chars formed show higher-than-expected oxidativ…

Skin Protection and AgingFlame retardant materials and propertiesDyeing and Modifying Textile Fibers

Ferro-, ferri- and antiferro-electric behaviour in a bent-shaped mesogen

Avtar S. Matharu、Chrissie Grover、L. Komitov 等 4 位作者2000-01-01Journal of Materials Chemistry

The synthesis of a novel bent-shaped, four-ring thiophene-based chiral liquid crystalline ester derived from 5-(4-n-decyloxyphenyl)thiophene-2-carboxylic acid and (S)-1-methylheptyl 4′-hydroxybiphenyl-4-carboxylate is reported, i.e., (S)-4′-(1-methylheptyloxycarbonyl)biphenyl-4-yl 5-(4-n-decyloxyphenyl)thiophene-2-car…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchMolecular spectroscopy and chirality

Corrosion Mechanism of Nickel in Hot, Concentrated H[sub 2]SO[sub 4]

J.R. Kish、M. B. Ives、J.R. Rodda2000-01-01Journal of The Electrochemical Society

Electrochemical techniques, complemented by weight change and ex situ X‐ray spectroscopic measurements, were employed to characterize the corrosion of nickel in concentrated solutions. By use of a rotating cylinder electrode, it was found that corrosion is a mass‐transport controlled process with the convective diffus…

Electrocatalysts for Energy ConversionCorrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metals