Materials Literature
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It is shown that the superconformal filling (SCF) efficiency ($ε_{SCF}$) of nano-scale cavities can be rationalized in terms of relevant physical and geometric parameters. Based on extensive numerical simulations and using the dynamic scaling theory of interface growth, it is concluded that the relevant quantity for t…
Large-area nickel antidot arrays with a density up to 1010/cm2 have been fabricated by depositing nickel onto anodic aluminum oxide membranes that contain lattices of nanopores. Electron microscopy images show a high degree of order of the antidot arrays. Various sizes and shapes of the antidots were observed with inc…
The NaNO2 nanocomposite ferroelectric material in porous glass was studied by neutron diffraction. For the first time, the details of the crystal structure including positions and anisotropic thermal parameters were determined for the solid material, embedded in a porous matrix, in ferro- and paraelectric phases. It i…
A coarse-grained bead spring model of short polymer chains is studied by constant pressure molecular dynamics (MD) simulations. Due to two competing length scales for the length of effective bonds and the energetically preferred distance between nonbonded beads, one observes a glass transition when dense melts are coo…
Palladium nanoparticles covered with liquid-crystal molecules were prepared by UV irradiation of an alcohol solution of palladium(II) acetate in the presence of liquid-crystal molecules. The prepared Pd nanoparticles have an average diameter of 2.5 nm. A twisted nematic (TN) liquid-crystal device (LCD) was fabricated…
Multiwalled carbon nanotubes (MWNT) reinforced epoxy composite thin films were prepared by a microfabrication process and their elastic modulus was determined using a shaft-loaded blister test and linear and nonlinear elasticity models. Compared to net resin thin films, a 20% increase in elastic modulus was seen when…
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Crystallization from oriented hexagonal-packed cylinder (hex) and gyroid (gyr) melt phases in an asymmetric poly(ethylene oxide)- b -poly(isoprene) diblock copolymer is investigated by small-angle X-ray scattering with simultaneous rheology. Crystallization from a shear-oriented hex phase leads to crystalline lamellar…
The bond dissociation energies of CuNO(+), Cu(NO)(2)(+), and CuAr(+) are determined by means of guided ion beam mass spectrometry and quantum chemical calculations. From the experiment, the values D(0)(Cu(+)-NO) = 1.13 +/- 0.05, D(0)(ONCu(+)-NO) = 1.12 +/- 0.06, D(0)(Cu(+)-Ar) = 0.50 +/- 0.07, and D(0)(Cu(+)-Xe) = 1.0…
The compounds RbLnSe(2) (Ln = La, Ce, Pr, Nd, Sm, Gd, Tb, Ho, Er, Lu) have been synthesized by means of the reactive flux method at 1173 K. These isostructural compounds, which have the alpha-NaFeO(2) structure type, crystallize with three formula units in space group D(3d)(5)-R(-)3m of the trigonal system in cells at…
In an initial attempt to understand the structural organization of Bombyx mori silk fibroin stored in the silk gland using several solid-state NMR techniques, we recently reported the conformation of the crystalline form of silk I (The unprocessed conformation of the silk fibroin before spinning in the solid state) as…
We study the time evolution of damage in a fiber bundle model in which the range of interaction of fibers varies through an adjustable stress transfer function recently introduced. We find that the lifetime of the material exhibits a crossover from mean field to short range behavior as in the static case. Numerical ca…
We have developed a multistep route to the formation of covalently linked adducts of single-wall carbon nanotubes (SWNT) and deoxyribonucleic acid (DNA) oligonucleotides. X-ray photoelectron spectroscopy was used to characterize the initial chemical modification to form amine-terminated SWNTs, which were then covalent…
Poly( p -phenylene benzobisoxazole) (PBO) has been synthesized in the presence of single-wall carbon nanotubes (SWNTs) in poly(phosphoric acid) (PPA) using typical PBO polymerization conditions. PBO and PBO/SWNT lyotropic liquid crystalline solutions in PPA have been spun into fibers using dry-jet wet spinning. The te…
The progressive replacement of Rh with Ni modulates the electronic as well as chemical properties of body-centered [Rh14−xNix(CO)9(μ-CO)16]n− clusters (x=0, n=4; x=1, n=5 (shown here); x=2, n=4; x=5, n=2, 3) and prompts multivalence. The complexes obtained are isostructural, but not isoelectronic.
Extremely high carrier mobilities at room temperature are predicted in quasi-one-dimensional organic crystals at certain conditions that lead to the interference of two electron-phonon interaction mechanisms. The relaxation time as a function of carrier energy takes the form of a Lorentzian, which may be very sharp, i…
The synthesis, characterization, and molecular structures of the first air-stable, hexacoordinated high spin Fe(II) porphyrins (1) with axial alcohols are reported (1 = Fe(II) meso-tetrakis(o-dichlorophenyl)-beta-octanitroporphyrin). The structure of 1 with two axial waters is also presented. The very different confor…
We studied the evolution of defect lines (oily streaks) in cholesteric liquid crystals. In contrast to nematic liquid crystals, there were no interactions between the defect lines in cholesteric liquid crystals. We observed experimentally that individual open defect segments shrank with time with a linear relation, an…
Single crystals of Sr[C(2)(COO)(2)] were formed at the phase boundary of an aqueous silica gel that contained acetylenedicarboxylic acid and an aqueous solution of SrCl(2). The crystal structure (I4(1)/amd, Z=4) shows a diamond-like topology, with the strontium ions in an eightfold co-ordination by the oxygen atoms of…
Ordered silicas with high loadings of pendant methyl groups were synthesized via cocondensation of tetraethyl orthosilicate and triethoxymethylsilane under basic conditions in the presence of cetyltrimethylammonium surfactant. The resulting materials were characterized using X-ray diffraction (XRD), transmission elect…