Materials Literature
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Abstract This paper presents a review of the principle and technologies in reactive extrusion and their application in starch modification and preparation of starch derivatives, such as starch graft copolymers, glycosides, cationic starch, or oxidized starch. The applications of reactive extrusion in producing other b…
First-principles simulations have been performed for [001]-ordered Mn/Ge and Mn/GaAs "digital alloys", focusing on the effects of i) a larger band-gap and ii) a different semiconducting host on the electronic structure of the magnetic semiconductors of interest. Our results for the exchange constants in Mn/Ge, evaluat…
The scattering determinant for the scattering of waves from several obstacles is considered in the case of elastic solids with voids. The multi-scattering determinant displays contributions from periodic ray-splitting orbits. A discussion of the weights of such orbits is presented.
Traumatic injury to the central nervous system (CNS) triggers cell death and deafferentation, which may activate a cascade of cellular and network disturbances. These events often result in the formation of irregularly shaped lesions comprised of necrotic tissue and/or a fluid-filled cavity. Tissue engineering represe…
We herein present the preparation, crystal structure, magnetic properties, and theoretical study of new heterobimetallic chains of formula {[Fe(III)(bpym)(CN4)]2M(II)(H2O)2}.6H2O [bpym = 2,2'-bipyrimidine; M = Zn (2), Co (3), Cu (4), and Mn (5)] which are obtained by using the building block PPh4[Fe(bpym)(CN)4].H2O (1…
A hydrothermal carbonization route has been designed for the syntheses of uniform core−shell Te@carbon-rich composite nanocables with ultrathin and ultralong Te nanowires as the core component and carbonaceous matter with remarkable reactivity as the shell, using ultralong Te nanowires of several nanometers in diamete…
Polyaniline (PANI)/Au composite hollow spheres were successfully synthesized using polystyrene/sulfonated polystyrene core/shell gel particle templates. The PANI shell thickness and the number of Au nanoparticles decorating the PANI could be controlled effectively by adjusting the experimental conditions. The morpholo…
A method for homogenizing heterogeneous catalyst is described. The method is based on growing polyaminoamido (PAMAM) dendrons on silica-coated magnetic nanoparticles. After the dendronizing process, the silica-coated magnetic nanoparticles are more stable and more soluble in organic solvents. The dendronized particles…
Nanoparticles (1-100 nm) comprise the latest technological advances designed to do everything from absorb environmental toxins to deliver drugs to a target organ. Recently, however, they have come under scrutiny for the potential to cause environmental damage. Because compounds in this miniature size range have chemic…
A near-field electrospinning (NFES) process has been developed to deposit solid nanofibers in a direct, continuous, and controllable manner. A tungsten electrode with tip diameter of 25 microm is used to construct nanofibers of 50-500 nm line width on silicon-based collectors while the liquid polymer solution is suppl…
Abstract Two different test apparatuses are used at BAM to evaluate the safety of oxygen components: First, the “promoted ignition combustion test” according to ASTM G 124 [1] and to EIGA IGC Doc 13/02/E [2], and second, the new “metallic disk ignition test” that has not been standardized yet. The standard test method…
Abstract It is shown that the heat conductivity of carbon fiber (CF)‐reinforced aromatic polyamide on the basis of phenylone can be described within the framework of a fractal model. Depending on the dimension of filler fibers network (system), such description can be obtained by the application of two limiting cases:…
Accurate measurements of the temperature dependence of spontaneous polarization and dielectric constant in the vicinity of the phase transition from the paraelectric to the ferroelectric phase in ${\mathrm{SrTi}}^{18}{\mathrm{O}}_{3}$ were performed. Dielectric constant and soft mode frequency can be well described [M…
Lead zirconium titanate (PZT) ceramic specimens were prepared by liquid phase sintering with excess PbO. By the addition of a small amount of MgO, the grain shape was changed from spherical to angular. When SiO 2 was further added, twin was induced in a few grains, which grew abnormally during heat treatment. Through…
Using a novel combustion method, Eu‐doped Eu:yttrium aluminum garnet (YAG) and Eu:YSAG powders, and transparent Eu:YSAG ceramics were fabricated. The optical properties of these transparent ceramics have been measured, and a reduced peak splitting of Eu 3+ for 5 D 0 → 7 F 1 and 5 D 0 → 7 F 2 was observed when 10 at.%…
We measured the temperature dependence of dielectric constant and striction for spinel MnT 2 O 4 (T = V, Cr, Mn) under magnetic field. We found critical changes of the dielectric constant and striction with ferrimagnetic ordering as well as applied magnetic field in MnV 2 O 4 and Mn 3 O 4 , which have orbital degree o…
Abstract The clay is treated with a reducing agent and an acid so as to obtain a clay containing various metal components with a variable‐valence state. Then, the clay is coprecipitated with natural rubber (NR) latex to prepare a vulcanized NR/clay composite. The degradation process of the NR/clay composite under hot…
The average concentration of N -methylmorpholine- N -oxide (NMMO) in the running Lyocell filament was measured in the coagulation process by which the precipitation kinetics of cellulose in the Lyocell process was studied. It was found that there are two diffusion regimes in the coagulation process of cellulose in the…
The {1 1 1} twins frequently observed in pressureless‐sintered BaTiO 3 ceramics have been analyzed by the X‐ray diffractometry, scanning and transmission electron microscopy. Both the single twins and double lamellar twins are growth (or annealing) twins. The twins lying in the {1 1 1} mirror planes, which is not one…
We have synthesized A-D-A-type linear chain chromophores based on oligo(phenylene vinylene) as an electron donor (D) and several electron/energy acceptors (A), which are linked by an alkyl spacer with various lengths and are processed for a helical encapsulation with amylose. Photoinduced electron/energy transfers (eT…