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From strong to fragile glass- forming systems: A temperature modulated differential scanning calorimetry investigation

Laurent Carpentier、Sylvain Desprez、Marc Descamps2003-09-01Phase Transitions

The capacity of temperature modulated differential scanning calorimetry (TMDSC) technique to determine dynamical parameters is tested on several glass-formers of different fragility. We show that both the fragility index m and the stretching exponent β deduced from TMDSC are consistent with results from other spectros…

Material Dynamics and PropertiesGlass properties and applicationsTheoretical and Computational Physics

Bulk SmCo/sub 5/α-Fe composite by plasma pressure consolidation

Q. Zeng、Y. Zhang、M.J. Bonder 等 5 位作者2003-09-01IEEE Transactions on Magnetics

Plasma pressure consolidation (PPC) was used to synthesize exchange coupled composite magnets. The magnets were processed from a mixture of micrometer-size, anisotropic magnetically hard SmCo/sub 5/ and nanometer size magnetically soft Fe particles. High density magnets were obtained by PPC at a temperature as low as…

Magnetic properties of thin filmsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Feed-forward continuous and complete polarization control with a plzt rotatable-variable waveplate and inline polarimeter

Katsuhiko Hirabayashi、C. Amano2003-09-01Journal of Lightwave Technology

A Pb/sub 1-x/Lax(Zr/sub y/Ti/sub z/)/sub 1-x/4/O3(PLZT) electrooptic ceramic variable-rotatable waveplate and a compact inline polarimeter have been used to develop a fast feed-forward-controlled module for the continuous and complete conversion of polarization. This requires the control of only two parameters: the di…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesMagneto-Optical Properties and Applications

Diversity of epilithic diatoms in high mountain lakes under the stress of acidification (Tatra Mts, Poland)

Barbara Kawecka、Joanna Galas2003-09-01Annales de Limnologie - International Journal of Limnology

Using the epilithic diatoms as indicators of environmental conditions, 10 lakes in the High Tatra Mountains were characterised with regard to their stage of acidification. The diatom communities were diverse; 210 taxa were found, including 27 species of north and alpine preference. On the basis of cluster analysis, tw…

Marine and coastal ecosystemsAquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae Research

Water as Solvent in Polyimide Synthesis: Thermoset and Thermoplastic Examples

John Chiefari、Buu Dao、Andrew M. Groth 等 4 位作者2003-09-01High Performance Polymers

A combination of increasingly stringent environmental legislation and economic competition is driving industrial processes further and further towards the three “E”s of chemical manufacture: economy, efficiency and environmental impact. In this paper, we present a novel aqueous method for the synthesis of polyimides.…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersMicrowave-Assisted Synthesis and Applications

Unexpected Formation of a Weak Metal−Metal Bond: Synthesis, Electronic Properties, and Second-Order NLO Responses of Push−Pull Late−Early Heteronuclear Bimetallic Complexes with W(CO)3(1,10-phenanthroline) Acting as a Donor Ligand

Maddalena Pizzotti、Renato Ugo、Claudia Dragonetti 等 6 位作者2003-09-01Organometallics

In attempts to bridge the complex [W(CO) 3 (phen)(pyz)] (phen = 1,10-phenanthroline; pyz = pyrazine) to acceptor centers, either soft centers such as cis -M(CO) 2 Cl (M = Rh(I), Ir(I)) and fac- M(CO) 3 Cl 2 (M = Ru(II), Os(II)) or hard centers such as BF 3, the pyrazine ligand is lost, while the fragment W(CO) 3 (phen…

Metal complexes synthesis and propertiesMagnetism in coordination complexesNonlinear Optical Materials Research

Bipolar conduction and drain-induced barrier thinning in carbon nanotube FETs

Jason Clifford、D.L. John、D.L. Pulfrey2003-09-01IEEE Transactions on Nanotechnology

The drain current-voltage (I-V) characteristics of Schottky-barrier carbon nanotube field-effect transistors (FETs) are computed via a self-consistent solution to the two-dimensional potential profile, the electron and hole charges in the nanotube, and the electron and hole currents. These out-of-equilibrium results a…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvancements in Semiconductor Devices and Circuit Design

A new vector model of magnetic hysteresis based on a novel class of play hysterons

M. d’Aquino、C. Serpico、C. Visone 等 4 位作者2003-09-01IEEE Transactions on Magnetics

The scalar Preisach model of hysteresis is extended to the isotropic vector case by introducing a new type of elementary vector Play operators. The new isotropic vector hysteresis model can reproduce with reasonable accuracy the qualitative behavior of magnetic vector hysteresis in isotropic materials and is rather fa…

Force Microscopy Techniques and ApplicationsMagnetic Properties and ApplicationsPiezoelectric Actuators and Control

Role of Covalent and Noncovalent Interactions in the Formation of Films from Unheated Whey Protein Solutions Following pH Adjustment

Gregory B. Quinn、Frank J. Monahan、Dolores O’Riordan 等 5 位作者2003-09-01Journal of Food Science

ABSTRACT: Films were formed from heated whey protein isolate (WPI) solutions (heated [H] films) and from unheated WPI solutions following adjustment to pH 11, with subsequent readjustment to pH 7 (unheated, readjusted [UR] films) or without readjustment to pH 7 (unheated, unadjusted films [UU] films). UU and UR films…

Advanced Sensor and Energy Harvesting MaterialsNanocomposite Films for Food PackagingPolymer Surface Interaction Studies

Remarks about preisach function approximation using lorentzian function and its identification for nonoriented steels

B. Azzerboni、E. Cardelli、Giovanni Finocchio 等 4 位作者2003-09-01IEEE Transactions on Magnetics

In this paper, we will discuss the use of the Lorentzian function as a possible candidate for the accurate approximation of the Preisach function in the modeling of scalar hysteresis for nonoriented grain steels. In particular we discuss here the identification procedure of the parameters of the function from measured…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMagnetic Properties and Applications

Novel Chromophore‐Functionalized Poly[2‐(trifluoromethyl) adamantyl acrylate‐methyl vinyl urethane]s with High Poling Stabilities of the Nonlinear Optical Effect

David Briers、Guy Koeckelberghs、Isabel Picard 等 6 位作者2003-09-01Macromolecular Rapid Communications

Abstract Nonlinear optical vinyl polymers with high glass transition temperature ( T g ) were prepared by the functionalization of a fluorinated acrylate‐methyl vinyl isocyanate copolymer. A modified pathway to obtain a thiophene bridged chromophore was worked out. Poled films of the polymers show a fairly high and st…

Porphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Influence of the mechanical and metallurgical state of an Al-Mg alloy on the surface integrity in ultraprecision machining

Renato Goulart Jasinevicius、Gabriela Pessoa Campos、Luciana Montanari 等 8 位作者2003-09-01Journal of the Brazilian Society of Mechanical Sciences and Engineering

This work presents the experimental results of the facing turning of an Al-Mg alloy. This aluminium alloy was mechanically and metallurgically modified, by means of cold rolling reduction and refining grain size previous to machining. The samples were cut and compared with samples in the as-received form, machined und…

Advanced machining processes and optimizationMaterial Selection and PropertiesEngineering Technology and Methodologies

Formation of β‐Silicon Nitride Crystals from (Si,Al,Mg,Y)(O,N) Liquid: I, Phase, Composition, and Shape Evolutions

Lingling Wang、T. Y. Tien、I‐Wei Chen2003-09-01Journal of the American Ceramic Society

Precipitation, growth, and coarsening of Si 3 N 4 crystals in (Si,Al,Mg,Y)(O,N) liquids at 1680°C has been studied. The initial nucleation of β‐Si 3 N 4 occurs mostly on α‐Si 3 N 4 because of the very high supersaturation of the liquid. After a brief period of growth, the crystals then undergo accelerated coarsening,…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced Surface Polishing Techniques

Corrosion of aluminium in perchloric acid in presence of various inorganic additives

N. Khalil、F. M. Mahgoub、B.A. Abd-El-Nabey 等 4 位作者2003-09-01Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

The corrosion of aluminium in 1M HClO4 at 40° C has been investigated using the potentiodynamic polarisation technique. The effect of various inorganic additives has been investigated. It was found that NO3-, NO2- and SCN- anions exhibit an inhibiting action on acid corrosion of aluminium by reducing the general corro…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Diamond nanofabrication and characterization for biosensing application

M. Tachiki、Yu Kaibara、Yu Sumikawa 等 8 位作者2003-09-01physica status solidi (a)

Surface potential of the H-terminated and locally oxidized diamond surfaces is investigated by Kelvin probe force microscope. Potential of H-terminated diamond surface is observed to be ∼0.1 V higher than that of oxidized diamond surface. Surface potential difference is attributed to the surface charge induced by the…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Radiolabeling of avidin with very high specific activity for internal radiation therapy of intraperitoneally disseminated tumors.

Marcelo Mamede、Tsuneo Saga、Hisataka Kobayashi 等 8 位作者2003-09-01PubMed

PURPOSE: For the effective internal radiation therapy of i.p. disseminated tumors, we developed avidin (Av)-dendrimer-chelate complex, which can be labeled with indium-111, emitting Auger and conversion electrons, with very high specific activity, and we studied its internalization, biodistribution, and therapeutic ef…

Radiopharmaceutical Chemistry and ApplicationsDendrimers and Hyperbranched PolymersCancer Research and Treatment

Relationship between microstructure and corrosion resistance in Zn–Al alloy coated galvanised steels

Jon Elvins、J. A. Spittle、David Worsley2003-09-01Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

The effect of cooling rate on the coating microstructure and corrosion resistance of Zn - 4.5 wt-%Al alloy galvanising coatings applied to 0.7 mm gauge strip steel substrates is presented. Increasing the cooling rate by the use of a high powered air cooler does not significantly alter the volume fraction of primary zi…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsConcrete Corrosion and Durability

Formation of Lead Zirconate Titanate Powders by Spray Pyrolysis

W. Nimmo、Naseef J. Ali、Rik Brydson 等 7 位作者2003-09-01Journal of the American Ceramic Society

Twin‐fluid atomization spray pyrolysis (SP) has been investigated for the production of lead zirconate titanate (PZT) powders, using aqueous solutions of lead acetate and zirconium and titanium alkoxide precursor reagents. The particle size distribution of the PZT powder showed a d 50 value of 0.3 μm, but with a small…

Ferroelectric and Piezoelectric MaterialsThermal and Kinetic AnalysisNuclear materials and radiation effects

Experimental evaluation of the preisach distribution for magnetic recording media

P. Postolache、M. Cerchez、Laurenţiu Stoleriu 等 4 位作者2003-09-01IEEE Transactions on Magnetics

In this paper, a nonparametric identification algorithm of the Preisach distribution from the first-order reversal curve diagram is discussed. The method presented is important because no assumption is made on the shape of the Preisach distribution. The sensitivity and the limits of the method are also analyzed.

Magnetic Properties and ApplicationsTree-ring climate responsesGeomagnetism and Paleomagnetism Studies

Crystallographic Studies on Ascaris suum NAD-Malic Enzyme Bound to Reduced Cofactor and Identification of an Effector Site

G S Rao、David E. Coleman、William E. Karsten 等 5 位作者2003-09-01Journal of Biological Chemistry

The crystal structure of the mitochondrial NAD-malic enzyme from Ascaris suum, in a quaternary complex with NADH, tartronate, and magnesium has been determined to 2.0-A resolution. The structure closely resembles the previously determined structure of the same enzyme in binary complex with NAD. However, a significant…

Mass Spectrometry Techniques and ApplicationsEnzyme Structure and FunctionBiochemical and Molecular Research