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Thin film metal hydrides for hydrogen storage applications

Andrea Baldi、B. Dam2010-12-06Journal of Materials Chemistry

Thin film technology is a powerful exploratory technique in the search for advanced hydrogen-storage systems. Thin films of metal hydrides allow one to perform high-throughput screening of large materials libraries, discover new metastable phases inaccessible by bulk preparation methods, and model the finite-size effe…

Hydrogen Storage and MaterialsMXene and MAX Phase MaterialsAmmonia Synthesis and Nitrogen Reduction

Reduced charge recombination in a co-sensitized quantum dot solar cell with two different sizes of CdSequantum dot

J. Chen、Wei Lei、Wei Deng2010-12-06Nanoscale

An efficient photoelectrode is fabricated by sequentially assembling 2.5 nm and 3.5 nm CdSe quantum dots (QDs) onto a TiO2 film. As revealed by UV-vis absorption spectroscopy, two sizes of CdSe QD can be effectively adsorbed on the TiO2 film. With a broader light absorption range and better coverage of CdSe QDs on the…

TiO2 Photocatalysis and Solar CellsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Seismic response attenuation of structures using shape memory alloy dampers

Y. M. Parulekar、G. R. Reddy、K.K. Vaze 等 7 位作者2010-12-06Structural Control and Health Monitoring

Smart materials such as shape memory alloys (SMAs) are recently being used in earthquake engineering applications to control the response of structures. In this paper, a shape-memory alloy damper device made up of austenite wires (e.g. Nickel Titanium wires) is used as a passive energy absorber. NiTi wires are very at…

Seismic Performance and AnalysisShape Memory Alloy TransformationsMasonry and Concrete Structural Analysis

Luminescent quantum-dot-sized conjugated polymernanoparticles—nanoparticle formation in a miniemulsion system

Zeina Hashim、Philip D. Howes、Mark Green2010-12-06Journal of Materials Chemistry

The synthesis of semiconducting polymer nanospheres (SPNs) by miniemulsion methods has been reported previously,1,2 however the resulting materials have typically been significantly larger than quantum dots, the nanomaterial of choice for cell imaging. In the current work, we aimed to obtain quantum-dot-sized poly(eth…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesConducting polymers and applications

Effects of Composition, Orientation and Temperature on the O2 Permeability of Model Polymer/Clay Nanocomposites

Erik Dunkerley、Daniel F. Schmidt2010-12-06Macromolecules

Studies of the barrier properties of polymer/layered silicate nanocomposites have traditionally focused on systems with low organoclay contents, with very little work comparing theory and experiment over broad composition ranges. As a result, in spite of many reports of promising enhancements in barrier properties, th…

Corrosion Behavior and InhibitionPolymer Nanocomposites and PropertiesConducting polymers and applications

Ballistic thermal rectification in asymmetric three-terminal graphene nanojunctions

Tao Ouyang、Yuanping Chen、Yuee Xie 等 7 位作者2010-12-06Physical Review B

Graphene nanojunctions (GNJs) are important components of future nanodevices and nanocircuits. Using the nonequilibrium Green's function method, we investigate the phononic properties of three-terminal GNJs (TGNJs). The results show that the heat flux runs preferentially along the direction from narrow to wide termina…

Graphene research and applicationsThermal properties of materialsThermal Radiation and Cooling Technologies

Thermally, photochemically and electrically switchable reflection colors from self-organized chiral bent-core liquid crystals

Manoj Mathews、Rafael S. Zola、Deng‐Ke Yang 等 4 位作者2010-12-06Journal of Materials Chemistry

We report the synthesis and characterization of two new chiral 1,3-phenylene based five ring bent-core mesogens that combine the unique electro-optic characteristics of banana-shaped molecules with chiroptic properties. Azobenzene moiety incorporated as a linking unit in one of the rigid arms renders trans–cis isomeri…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry

Flame retardancy working mechanism of methyl‐DOPO and MPPP in flexible polyurethane foam

Alexander König、Edwin Kroke2010-12-06Fire and Materials

SUMMARY The chemical nature of flexible polyurethane (flex PU) foams, the low density, the high air permeability and the open cell structure cause this material to be highly flammable. The new phosphorus flame‐retardant (FR) methyl‐DOPO (9, 10‐dihydro‐9‐oxa‐methylphosphaphenanthrene‐10‐oxide) is known to show an excel…

Toxic Organic Pollutants ImpactFire dynamics and safety researchFlame retardant materials and properties

Imaging ellipsometry of graphene

Ulrich Wurstbauer、Christian Röling、Ursula Wurstbauer 等 7 位作者2010-12-06University of Regensburg Publication Server (University of Regensburg)

Imaging ellipsometry studies of graphene on SiO2/Si and crystalline GaAs are presented. We demonstrate that imaging ellipsometry is a powerful tool to detect and characterize graphene on any flat substrate. Variable angle spectroscopic ellipsometry is used to explore the dispersion of the optical constants of graphene…

Graphene research and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Research

Enzymatic Cross-Linking of a Nanofibrous Peptide Hydrogel

Erica L. Bakota、Lorenzo Aulisa、Kerstin M. Galler 等 4 位作者2010-12-06Biomacromolecules

The rheological properties of the environment in which a cell lives play a key role in how the cells will respond to that environment and may modify cell proliferation, morphology and differentiation. Effective means of modifying these properties are needed, particularly for peptide hydrogels which are generally relat…

Glycosylation and Glycoproteins ResearchConnective tissue disorders researchSupramolecular Self-Assembly in Materials

Metal−Metal-Interaction-Facilitated Coordination Polymer as a Sensing Ensemble: A Case Study for Cysteine Sensing

Jiang‐Shan Shen、Donghua Li、Mingbo Zhang 等 6 位作者2010-12-06Langmuir

A detailed investigation of the absorption and CD signals of Ag(I)-cysteine (Cys) aqueous solutions at buffered or varying pH has allowed us to suggest that coordination polymers are formed upon mixing Ag(I) and Cys bearing a Ag(I)-Cys repeat unit. The formation of the coordination polymers are shown to be facilitated…

Metal complexes synthesis and propertiesMolecular Sensors and Ion DetectionNanocluster Synthesis and Applications

Diameter-modulated nanowires as candidates for high thermoelectric energy conversion efficiency

Xanthippi Zianni2010-12-06Applied Physics Letters

High optimal thermoelectric efficiencies are theoretically demonstrated in ballistic nanowires with diameter modulation. The physics underlying the good thermoelectric performance of diameter-modulated nanowires is the strong energy dependence of their transmission coefficients. It is shown that the thermoelectric eff…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Fabrication of magnetic cryptomelane-type manganese oxide nanowires for water treatment

Tong Zhang、Xiwang Zhang、Jiawei Ng 等 6 位作者2010-12-06Chemical Communications

Superparamagnetic Fe(3)O(4) nanoparticles were successfully grafted onto the manganese oxide OMS-2 nanowires, and the synthesized material exhibits excellent magnetic separation and adsorption properties.

ZnO doping and propertiesCopper-based nanomaterials and applicationsCharacterization and Applications of Magnetic Nanoparticles

Sonochemical Synthesis of Magnetic Janus Nanoparticles

Boon Mian Teo、Su Kyung Suh、T. Alan Hatton 等 5 位作者2010-12-06Langmuir

The sonochemical synthesis of nanosized surface-dissymmetrical (Janus) particles is described. The Janus particles were composed of silica and polystyrene, with the polystyrene portion loaded with nanosized magnetite particles. It is shown that the Janus particles can be used to form kinetically stable oil-in-water em…

Iron oxide chemistry and applicationsPickering emulsions and particle stabilizationElectrohydrodynamics and Fluid Dynamics

Magnetoconductance Oscillations and Evidence for Fractional Quantum Hall States in Suspended Bilayer and Trilayer Graphene

Wenzhong Bao、Zeng Zhao、Hang Zhang 等 9 位作者2010-12-06Physical Review Letters

We report pronounced magnetoconductance oscillations observed on suspended bilayer and trilayer graphene devices with mobilities up to $270\text{ }000\text{ }\text{ }{\mathrm{cm}}^{2}/\mathrm{V}\text{ }\mathrm{s}$. For bilayer devices, we observe conductance minima at all integer filling factors $\ensuremath{\nu}$ bet…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Solution-processable, high-T g , ambipolar polyimide electrochromics bearing pyrenylamine units

Yi‐Chun Kung、Sheng‐Huei Hsiao2010-12-06Journal of Materials Chemistry

Two new pyrenylamine-based polyimides were prepared from the polycondensation reaction of N,N-di(4-aminophenyl)-1-aminopyrene with pyromellitic dianhydride (PMDA) or 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTDA). The polyimide derived from PMDA is soluble in hot N-methyl-2-pyrrolidone and can be solution-cast…

Conducting polymers and applicationsTransition Metal Oxide NanomaterialsSynthesis and properties of polymers

Modulating the electronic structures of graphene by controllable hydrogenation

Zhiqiang Luo、Jingzhi Shang、Sanhua Lim 等 8 位作者2010-12-06Applied Physics Letters

The evolution of electronic structures of hydrogenated graphene with different amount of hydrogen (H) coverage was investigated by ultraviolet photoemission spectroscopy and optical absorption spectroscopy. Raman spectroscopy and x-ray photoelectron spectroscopy were used to monitor and evaluate the H coverage. At low…

Advancements in Battery MaterialsGraphene research and applicationsBoron and Carbon Nanomaterials Research

Electronic transport in disordered bilayer and trilayer graphene

Shengjun Yuan、Hans De Raedt、M. I. Katsnelson2010-12-06Physical Review B

We present a detailed numerical study of the electronic transport properties of bilayer and trilayer graphene within a framework of single-electron tight-binding model. Various types of disorder are considered, such as resonant (hydrogen) impurities, vacancies, short- or long-range Gaussian random potentials, and Gaus…

Graphene research and applicationsQuantum and electron transport phenomenaThermal properties of materials

Surface polar phonon dominated electron transport in graphene

X. Li、E. A. Barry、J. M. Zavada 等 5 位作者2010-12-06Applied Physics Letters

The effects of surface polar phonons on the electronic transport properties of monolayer graphene are studied by using a Monte Carlo simulation. Specifically, the low-field electron mobility and saturation velocity are examined for different substrates (SiC, SiO2, and HfO2) in comparison to the intrinsic case. While t…

Graphene research and applicationsThermal properties of materialsAdvanced Physical and Chemical Molecular Interactions