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A Comparative Study on Mechanical Properties of Al 7075 Alloy Processed by Rolling at Cryogenic Temperature and Room Temperature

S.K. Panigrahi、R. Jayaganthan2008-06-17Materials science forum

The mechanical properties and microstructural characteristics of a precipitation hardenable Al 7075 alloy subjected to rolling at liquid nitrogen temperature and room temperature are reported in this present work. The Al 7075 alloy was severely rolled at cryogenic temperature and room temperature and its mechanical pr…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetal Alloys Wear and Properties

Pressure-induced changes in the magnetic and magnetocaloric properties ofRMn2Ge2(R=Sm,Gd)

Pramod Kumar、К. Г. Суреш、A. K. Nigam 等 6 位作者2008-06-17Physical Review B

We have studied the variation of magnetic and magnetocaloric properties of polycrystalline compounds ${\text{SmMn}}_{2}{\text{Ge}}_{2}$ and ${\text{GdMn}}_{2}{\text{Ge}}_{2}$ as a function of applied hydrostatic pressure. The magnetic transition temperatures are found to change considerably with pressure. The temperat…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsInorganic Chemistry and Materials

Synthesis and Characterization of the 4,4′-Bipyridyl Dianion and Radical Monoanion. A Structural Study

M.S. Denning、M. Irwin、José M. Goicoechea2008-06-17Inorganic Chemistry

The reaction of ethylenediamine solutions of 4,4'-bipyridine with varying stoichiometric amounts of sodium resulted in the isolation of the 4,4'-bipyridyl radical anion (44bipy(*-)) and the unprecedented 4,4'-bipyridyl dianion (44bipy(2-)). The radical was characterized by single-crystal X-ray diffraction in Na(44bipy…

Magnetism in coordination complexesRadical Photochemical ReactionsPolyoxometalates: Synthesis and Applications

Microstructural Characterizations of Cu Processed by ECAP from 4 to 24 Passes

Chongxiang Huang、Hua Yang、Shi Ding Wu 等 4 位作者2008-06-17Materials science forum

The microstructures of pure Cu processed by equal channel angular pressing (ECAP) from 4 to 24 passes were investigated. It was found that the microstructures of Cu samples with a small number of ECAP passes (4-8) were not inhomogeneous and the fraction of high-angle grain boundary (HAGB) was low (25~43%). While for t…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesMetallurgy and Material Forming

Martensitic Transformations and Functional Stability in Ultra-Fine Grained NiTi Shape Memory Alloys

Juri Burow、Egor Prokofiev、Christoph Somsen 等 6 位作者2008-06-17Materials science forum

Martensitic transformations in NiTi shape memory alloys (SMAs) strongly depend on the microstructure. In the present work, we investigate how martensitic transformations are affected by various types of ultra-fine grained (UFG) microstructures resulting from various processing routes. NiTi SMAs with UFG microstructure…

Shape Memory Alloy Transformations

Atomic Force Microscopy Characterization and Interpretation of Thin‐Film Poly(butylene adipate) Spherulites with Ring Bands

Andreas Frömsdorf、Eamor M. Woo、Li‐Ting Lee 等 5 位作者2008-06-17Macromolecular Rapid Communications

Abstract Atomic force microscopy characterization has been conducted to reveal the morphological difference between single‐ring bands in poly(butylene adipate) (PBA). Furthermore, morphological features of the ring‐less Maltese‐cross spherulites are compared to the ring‐band spherulites. Periodic changes in height see…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Surface-wave instabilities, period doubling, and an approximate universal boundary of bubble stability at the upper threshold of sonoluminescence

Joachim Holzfuss2008-06-17Physical Review E

Numerical results are presented for hydrodynamic instabilities surrounding the parameter space of sonoluminescing bubbles. The Rayleigh-Taylor instability is shown to limit bubble oscillations only in a small region near a border at small radii in noisy environments. Also, two different noise-induced instabilities by…

Ocean Waves and Remote SensingUnderwater Acoustics ResearchUltrasound and Cavitation Phenomena

Tailor‐made hybrid nanostructure of poly(ethyl acrylate)/clay by surface‐initiated atom transfer radical polymerization

Haimanti Datta、Anil K. Bhowmick、Nikhil K. Singha2008-06-17Journal of Polymer Science Part A Polymer Chemistry

Abstract Hybrid nanoarchitecture of tailor‐made Poly(ethyl acrylate)/clay was prepared by surface‐initiated atom transfer radical polymerization (SI‐ATRP), by tethering ATRP initiator on active hydroxyl group, present in surface as well as in the organic modifier of the clay used. Extensive exfoliation was facilitated…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer Surface Interaction Studies

Perovskite Nanoparticles and Nanowires: Microwave–Hydrothermal Synthesis and Structural Characterization by High‐Resolution Transmission Electron Microscopy

Xinhua Zhu、Junyi Wang、Zhenghai Zhang 等 7 位作者2008-06-17Journal of the American Ceramic Society

Perovskite pure BaTiO 3 (BT) nanoparticles with spherical morphology and PX‐phase PbTiO 3 (PT) nanowires with acicular morphology, were synthesized by microwave–hydrothermal process, and their atomic‐scale microstructures were characterized by electron microscopy. Both X‐ray diffraction (XRD) and selected area electro…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Selective Hydrogenation of Benzene to Cyclohexene on a Ru/Al2O3/Cordierite Monolithic Catalyst: Effect of Mass Transfer on the Catalytic Performance

Yujun Zhao、Jin Zhou、Jianguo Zhang 等 5 位作者2008-06-17Industrial & Engineering Chemistry Research

A Ru/Al 2 O 3 /cordierite monolithic catalyst was prepared, characterized, and examined in selective hydrogenation of benzene to cyclohexene in a monolithic fixed-bed reactor with an aqueous solution of ZnSO 4 . The Carberry number and Wheeler−Weisz group were calculated to analyze the effects of external and internal…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Structures and Surface Energies of (100) and Octopolar (111) Faces of Halite (NaCl): an Ab initio Quantum-Mechanical and Thermodynamical Study

Marco Bruno、Dino Aquilano、Linda Pastero 等 4 位作者2008-06-17Crystal Growth & Design

The structures of the (100), octopolar (111) Na-terminated [(111) Na ], and (111) Cl-terminated [(111) Cl ] surfaces of halite (NaCl) were determined by means of ab initio quantum mechanical calculations (density functional theory, DFT). The (111) surfaces show higher surface relaxation with respect to the (100) surfa…

Advanced Chemical Physics StudiesAdvanced Thermoelectric Materials and DevicesThermal and Kinetic Analysis

Permeation mechanisms of pulsed microwave plasma deposited silicon oxide films for food packaging applications

Michael Deilmann、Mirko Grabowski、Sebastian Theiß 等 5 位作者2008-06-17Journal of Physics D Applied Physics

Silicon oxide barrier layers are deposited on polyethylene terephthalate as permeation barriers for food packaging applications by means of a low pressure microwave plasma. Hexamethyldisiloxane (HMDSO) and oxygen are used as process gases to deposit SiO x coatings via pulsed low pressure plasmas. The layer composition…

Electromagnetic wave absorption materialsCopper Interconnects and ReliabilitySilicone and Siloxane Chemistry

Controlled Deposition of Silver Indium Sulfide Ternary Semiconductor Thin Films by Chemical Bath Deposition

Li-Hau Lin、Ching-Chen Wu、Chia‐Hung Lai 等 4 位作者2008-06-17Chemistry of Materials

An aqueous method for the deposition of silver indium sulfide ternary semiconductor thin films is presented. According to grazing-incidence X-ray diffraction studies, a single phase of AgInS 2 with orthorhombic structure or a single phase of AgIn 5 S 8 with cubic spinel structure can be selectively grown on 3-mercapto…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Synthesis and Characterization of Tetraanthroporphyrins

Hiroko Yamada、Daiki Kuzuhara、Tetsuro Takahashi 等 8 位作者2008-06-17Organic Letters

Linearly pi-expanded novel tetraanthroporphyrins with and without aromatic rings at the meso-positions were prepared quantitatively for the first time from the corresponding precursors by a retro-Diels-Alder reaction.

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Probing the Electronic Structure and Chemical Bonding of Gold Oxides and Sulfides in AuOn− and AuSn− (n = 1, 2)

Hua‐Jin Zhai、Christian Bürgel、Vlasta Bonačić‐Koutecký 等 4 位作者2008-06-17Journal of the American Chemical Society

The Au-O and Au-S interactions are essential in nanogold catalysis and nanotechnology, for which monogold oxide and sulfide clusters serve as the simplest molecular models. We report a combined photoelectron spectroscopy and ab initio study on AuO (-) and AuO 2 (-) and their valent isoelectronic AuS (-) and AuS 2 (-)…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Template Growth of ZnO Nanorods and Microrods with Controllable Densities

Xiaodong Yan、Zhengwei Li、Ruiqun Chen 等 4 位作者2008-06-17Crystal Growth & Design

ZnO nanorod/microrod arrays with controllable surface distribution densities were successfully synthesized on glass substrates via a low-temperature template-assisted aqueous solution growth method. The influences of the pH of the solution on the formation and continuing growth of ZnO crystals were studied. It was fou…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesGas Sensing Nanomaterials and Sensors

Silica Nanoparticles with Continuously Tunable Sizes: Synthesis and Size Effects on Cellular Contrast Imaging

Yuhui Jin、Samuel Lohstreter、David T. Pierce 等 7 位作者2008-06-17Chemistry of Materials

Controlling the size of silica nanoparticles (NPs) on a continuously variable scale was achieved by systematically varying the organic solvent(s) used in water-in-oil microemulsion synthesis. A number of individual as well as binary solvent mixtures were investigated for tuning silica NP size. The results demonstrated…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniques

Reemergent Metal-Insulator Transitions in Manganites Exposed with Spatial Confinement

Thomas Z. Ward、Siyuan Liang、Kenji Fuchigami 等 7 位作者2008-06-17Physical Review Letters

The metal-insulator transition is characterized as a single peak in the temperature-dependent resistivity measurements; exceptions to this have never been seen in any single crystal material system. We show that by reducing a single crystal manganite thin film to a wire with a width comparable to the mesoscopic phase-…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Structural and angular dependence of coercivity and magnetic remanence of electrochemical ferromagnetic nanowires

A. Ghaddar、F. Gloaguen、J. Gieraltowski2008-06-17arXiv

A novel method for controlling nanowire magnetic properties and growth from filling time profile is presented. The wires are grown with an electrodeposition method ("Template synthesis") with a wide selection of pore diameters. We show that stray-fields presence in ferromagnetic nanowires are entirely dependent on the…

Materials Sciencecond-mat.other

Dual-band planar electric metamaterial in the terahertz regime

Yuan Yu、Chris Bingham、Talmage Tyler 等 9 位作者2008-06-17Optics Express

We present the design, fabrication, and measurement of a dual-band planar metamaterial with two distinct electric resonances at 1.0 and 1.2 THz, as a step towards the development of frequency agile or broadband THz materials and devices. A method of defining the effective thickness of the metamaterial layer is introdu…

Metamaterials and Metasurfaces ApplicationsTerahertz technology and applicationsAdvanced Antenna and Metasurface Technologies